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Table Of Contents

1.1.1 State function versus path function
1.1.2 Intensive property versus extensive property
1.2.1 The first law of thermodynamics
1.2.2 The second law of thermodynamics
1.3 The fundamental equation of thermodynamics
1.4 The calculus of thermodynamics
1.5 Open systems
1.6 Legendre transforms and free energies
2.1 General phase behavior
2.2 Conditions for phase equilibrium
2.3 The Clapeyron equation
3.1.1 The fundamental equation of thermodynamics
3.1.2 Phase equilibria
3.1.3 Gibbs phase rule
3.2.1 Vapor-liquid equilibrium
3.2.2 Liquid-liquid equilibria
3.2.3 Vapor-liquid-liquid equilibria
4.2 Derivation of Raoult’s law
5.1 Definition
5.2 Relationship between total properties and partial molar properties
5.3 Properties changes on mixing
5.4 Graphical representation for binary systems
6.1 Deviations from Raoult’s law and the activity coefficient
6.2 Modified Raoult’s law
6.3 Empirical activity coefficient models
6.4 The Gibbs-Duhem equation
6.5 Azeotropic systems
7.1 Introduction
7.2 Liquid-liquid equilibrium
8.1 Introduction
8.2 Phase behavior
8.3 Conditions for equilibrium
9.1 Henry’s law
9.2 Activity coefficients
10.1 The principle of corresponding states
10.2 The van der Waals equation and cubic equations of state
10.3 Equations of state for mixtures
11.1 The residual Helmholtz free energy
11.2 Fugacity
11.3 Vapor-liquid equilibrium with a non-ideal vapor phase
12.1 Conditions for equilibrium
12.2 The phase rule for chemically reacting systems
12.3 Gas phase reactions
12.4 The standard Gibbs free energy of formation
12.5 The influence of temperature
12.6 Liquid phase reactions
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Chemical Thermodynamics

Chemical Thermodynamics

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Published by: amit_harry on Oct 03, 2013
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