UNIVERSIDAD ROOSEVELT CARRERA PROFESIONAL: Farmacia Y Bioqumica.

SEMESTRE: VI CURSO: BROMATOLOGA I FECHA:03/10/13

Molcula de glucosa La glucosa, de frmula C6H12O6, es un azcar simple o monosacrido. Su molcula puede presentar una estructura lineal o cclica; esta ltima, representada en la ilustracin, es termodinmicamente ms estable.
1. ALFA-D- SORBOPIRANOSA

H H HO H OH O H OH H

OH
Composition = C(40.00%) H(6.71%) O(53.29%)

OH

-D-Sorbopyranose
2. ALFA-D- ALOPIRANOSA

OH H HO OH OH HH H OH OH

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C6 H12 O6 = 180.156 = C(40.00%) H(6.71%) O(53.29%) = 37.25 0.3 cm 3 = 104.0 3.0 cm 3 = 312.7 4.0 cm 3 = 1.635 0.02 = 81.7 3.0 dyne/cm = 1.732 0.06 g/cm 3 = Not available = 14.76 0.5 10-24cm3 = 180.06339 Da = 180 Da = 180.157763 Da

-D-Allopyranose

ESTUDIANTE: Maikel Frank Canales Tupac.

UNIVERSIDAD ROOSEVELT CARRERA PROFESIONAL: Farmacia Y Bioqumica. SEMESTRE: VI CURSO: BROMATOLOGA I FECHA:03/10/13
3. ALFA-D-GULOPIRANOSA

OH HO HH H H OH OH OH OH

-D-Gulopyranose

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C18 H36 O18 = 540.468 = C(40.00%) H(6.71%) O(53.29%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 540.19017 Da = 540 Da = 540.47329 Da

4. ALFA-D-IDOPIRANOSA

OH HO OH H H OH OH H OH H

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C6 H12 O6 = 180.156 = C(40.00%) H(6.71%) O(53.29%) = 37.25 0.3 cm 3 = 104.0 3.0 cm 3 = 312.7 4.0 cm 3 = 1.635 0.02 = 81.7 3.0 dyne/cm = 1.732 0.06 g/cm 3 = Not available = 14.76 0.5 10-24cm3 = 180.06339 Da = 180 Da = 180.157763 Da

-D-Idopyranose

5. ALFA-D-FRUTCTOPIRANOSA
Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass = C6 H12 O6 = 180.156 = C(40.00%) H(6.71%) O(53.29%) = 37.15 0.3 cm3 = 102.4 3.0 cm 3 = 317.1 4.0 cm 3 = 1.645 0.02 = 91.8 3.0 dyne/cm = 1.758 0.06 g/cm 3 = Not available = 14.73 0.5 10-24cm3 = 180.06339 Da = 180 Da = 180.157763 Da

H H HO OH H O H H OH

OH OH

-D-Fructopyranose

ESTUDIANTE: Maikel Frank Canales Tupac.

UNIVERSIDAD ROOSEVELT CARRERA PROFESIONAL: Farmacia Y Bioqumica. SEMESTRE: VI CURSO: BROMATOLOGA I FECHA:03/10/13

O NH2 N

Vitamin B3 Niacinamide

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C26 H36 N2 O2 = 408.576 = C(76.43%) H(8.88%) N(6.86%) O(7.83%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 408.277678 Da = 408 Da = 408.58615 Da

H3C CH3

CH3

CH3

OH Molar Volume CH3 Vitamin A

Molecular Formula Formula Weight Composition Molar Refractivity

= C20 H30 O = 286.452 = C(83.86%) H(10.56%) O(5.59%) = 95.49 0.3 cm3

Retinol

= 300.0 3.0 cm3 Parachor = 738.0 6.0 cm3 Index of Refraction = 1.549 0.02 Surface Tension = 36.6 3.0 dyne/cm Density = 0.954 0.06 g/cm 3 Dielectric Constant = Not available Polarizability = 37.85 0.5 10 -24cm 3 Monoisotopic Mass = 286.229665 Da Nominal Mass = 286 Da Average Mass = 286.459321 Da

ESTUDIANTE: Maikel Frank Canales Tupac.

UNIVERSIDAD ROOSEVELT CARRERA PROFESIONAL: Farmacia Y Bioqumica. SEMESTRE: VI CURSO: BROMATOLOGA I FECHA:03/10/13

H3C N

N N NH2
+

S Cl CH3
-

OH

Vitamin B1 Thiamine chloride

NH2 N N N N H

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C26 H36 N2 O2 = 408.576 = C(76.43%) H(8.88%) N(6.86%) O(7.83%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 408.277678 Da = 408 Da = 408.58615 Da

Vitamin B4 Adenine
H H N

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C31 H41 N7 O2 = 543.703 = C(68.48%) H(7.60%) N(18.03%) O(5.89%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 543.332173 Da = 543 Da = 543.71483 Da

S HO O

Molecular Formula Weight OFormula Composition Molar Refractivity

= C10 H16 N2 O3 S = 244.312 = C(49.16%) H(6.60%) N(11.47%) O(19.65%) S(13.13%) = 60.88 0.3 cm3 = 192.7 3.0 cm3 = 501.6 6.0 cm3 = 1.544 0.02 = 45.9 3.0 dyne/cm = 1.267 0.06 g/cm3 = Not available = 24.13 0.5 10-24cm3 = 244.088164 Da = 244 Da = 244.313734 Da

NH H

Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

Vitamin B7 Vitamin H Biotin

ESTUDIANTE: Maikel Frank Canales Tupac.

UNIVERSIDAD ROOSEVELT CARRERA PROFESIONAL: Farmacia Y Bioqumica. SEMESTRE: VI CURSO: BROMATOLOGA I FECHA:03/10/13

H3C
12

21

26

CH3
13 17

18

O
22 23

25 24

CH3
27

20

1 2 3 4

CH3
10 5

19

11 9

H
8

14

H
15

16

O H

H
6

Spirostan

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C37 H60 N2 O5 S = 644.949 = C(68.90%) H(9.38%) N(4.34%) O(12.40%) S(4.97%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 644.422294 Da = 644 Da = 644.961282 Da

12

CH3
13

18

1 2 3 4

CH3
10 5

19

11 9

H
8

14

H
6

Androstane
H3C
12 21 22 20 17 23

Molecular Formula Formula Weight 16 Composition Molar Refractivity Molar Volume 15 Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

17

= C56 H92 N2 O5 S = 905.406 = C(74.29%) H(10.24%) N(3.09%) O(8.84%) S(3.54%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 904.672694 Da = 904 Da = 905.426213 Da = C80 H134 N2 O5 S = 1235.996 = C(77.74%) H(10.93%) N(2.27%) O(6.47%) S(2.59%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 1235.001344 Da = 1234 Da = 1236.026089 Da

CH3
13

18

CH3
24

H
16

1 2 3 4

CH3
10 5

19

11

H
14 8 15

H
6

Cholane

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

ESTUDIANTE: Maikel Frank Canales Tupac.

UNIVERSIDAD ROOSEVELT CARRERA PROFESIONAL: Farmacia Y Bioqumica. SEMESTRE: VI CURSO: BROMATOLOGA I FECHA:03/10/13

H
12 11 1 2 3 4 13 17 16 14 15

H
10 5

H
8

H
6

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C38 H64 = 520.915 = C(87.62%) H(12.38%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 520.5008 Da = 520 Da = 520.929863 Da

Gonane
18 13

12 11 1 2 3 4

CH3
17 16 14 15
Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass = C35 H58 = 478.835 = C(87.79%) H(12.21%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 478.45385 Da = 478 Da = 478.848896 Da

H
10 5

H
9 8

H
6

Estrane

ESTUDIANTE: Maikel Frank Canales Tupac.

UNIVERSIDAD ROOSEVELT CARRERA PROFESIONAL: Farmacia Y Bioqumica. SEMESTRE: VI CURSO: BROMATOLOGA I FECHA:03/10/13

16 10 1 2 3 4 11 15 12 13 5 9

NH
17 14 8 7 6

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C16 H21 N = 227.345 = C(84.53%) H(9.31%) N(6.16%) = 70.59 0.4 cm 3 = 205.9 5.0 cm 3 = 534.8 6.0 cm 3 = 1.601 0.03 = 45.5 5.0 dyne/cm = 1.10 0.1 g/cm 3 = Not available = 27.98 0.5 10-24cm3 = 227.167399 Da = 227 Da = 227.350808 Da = C20 H27 N = 281.435 = C(85.35%) H(9.67%) N(4.98%) = 83.67 0.4 cm 3 = 232.4 5.0 cm 3 = 613.1 6.0 cm 3 = 1.639 0.03 = 48.3 5.0 dyne/cm = 1.21 0.1 g/cm 3 = Not available = 33.16 0.5 10-24cm3 = 281.214349 Da = 281 Da = 281.442812 Da

hasubanan
13

H
2 3 4 19 18 1 21 N

12 16

20

11 14 9 10 8 5 7 6

CH2

17

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

H
15

CH3

hetisan

H
8

10 14 15 16 17

H
13 18

22 11 12

7 6 5

9 19

H N H
1 2 3 21 4 20

kopsan

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C56 H72 N4 = 801.198 = C(83.95%) H(9.06%) N(6.99%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 800.575696 Da = 800 Da = 801.219227 Da

ESTUDIANTE: Maikel Frank Canales Tupac.

UNIVERSIDAD ROOSEVELT CARRERA PROFESIONAL: Farmacia Y Bioqumica. SEMESTRE: VI CURSO: BROMATOLOGA I FECHA:03/10/13

AMINOCIDOS ESENCIALES
Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume = = = = = = = = = = = = = = = = = = = = = = = = = = = C6 H9 N3 O2 155.155 C(46.45%) H(5.85%) N(27.08%) O(20.62%) 38.01 0.3 cm 3 325.6 4.0 cm3 1.614 0.02 79.6 3.0 dyne/cm 1.423 0.06 g/cm 3 Not available 15.07 0.5 10-24cm3 155.069477 Da 155 Da 155.156785 Da

H N N

O OH NH2

= 108.9 3.0 cm3

Histidine (His)

Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

CH3 O HO NH2 OH

Threonine (Thr)

C10 H18 N4 O5 274.274 C(43.79%) H(6.61%) N(20.43%) O(29.17%) Not available Not available Not available Not available Not available Not available Not available Not available 274.127721 Da 274 Da 274.277354 Da = = = = = = = = = = = = = = = = = = = = = = = = = = = = C21 H30 N6 O7 478.499 C(52.71%) H(6.32%) N(17.56%) O(23.41%) Not available Not available Not available Not available Not available Not available Not available Not available 478.217599 Da 478 Da 478.506528 Da C27 H43 N7 O9 609.672 C(53.19%) H(7.11%) N(16.08%) O(23.62%) Not available Not available Not available Not available Not available Not available Not available Not available 609.312228 Da 609 Da 609.68177 Da

O OH NH NH2

Tryptophan (Trp)

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

O H3 C CH3 NH2 OH

Leucine (Leu)

ESTUDIANTE: Maikel Frank Canales Tupac.

UNIVERSIDAD ROOSEVELT CARRERA PROFESIONAL: Farmacia Y Bioqumica. SEMESTRE: VI CURSO: BROMATOLOGA I FECHA:03/10/13
Molecular Formula Formula Weight Composition Molar Refractivity = C5 H11 N O2 = 117.146 = C(51.26%) H(9.46%) N(11.96%) O(27.32%) = 30.23 0.3 cm 3 = 110.1 3.0 cm3 = 276.6 4.0 cm3 = 1.461 0.02 = 39.8 3.0 dyne/cm = 1.063 0.06 g/cm 3 = Not available = 11.98 0.5 10-24cm3 = 117.078979 Da = 117 Da = 117.148253 Da = C11 H25 N3 O4 = 263.334 = C(50.17%) H(9.57%) N(15.96%) O(24.30%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 263.184507 Da = 263 Da = 263.338194 Da

CH3 O H3C NH2 OH

Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

Valine (Val)

O H2 N NH2 OH

Lysine (Lys)

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

O H3 C S NH2 OH

Methionine (Met)

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C16 H36 N4 O6 S = 412.546 = C(46.58%) H(8.80%) N(13.58%) O(23.27%) S(7.77%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 412.235557 Da = 412 Da = 412.550836 Da

NH2 HN NH

O OH NH2

Arginine (Arg)

Molecular Formula Formula Weight Composition Molar Refractivity Molar Volume Parachor Index of Refraction Surface Tension Density Dielectric Constant Polarizability Monoisotopic Mass Nominal Mass Average Mass

= C22 H50 N8 O8 S = 586.747 = C(45.03%) H(8.59%) N(19.10%) O(21.81%) S(5.47%) = Not available = Not available = Not available = Not available = Not available = Not available = Not available = Not available = 586.347233 Da = 586 Da = 586.754223 Da

ESTUDIANTE: Maikel Frank Canales Tupac.