Professional Documents
Culture Documents
Air Bags
Impact trips a sensor that activates the reaction:
The gaseous product of the reaction occupies 450 times more space than does the solid reactant.
Pressure Defined
Gas molecules are in constant motion, colliding with each other and with the walls of their container. The sum of ALL these collisions is called pressure.
A Swarm of Particles
The air around us is a mixture of gases, tasteless, odorless and invisible We can feel its effects, and we depend on it every moment of our existence. Its a swarm of molecules not unlike a swarm of gnats
Pressure
Pressure is directly proportional to the number of gas molecules in the air; pressure can change.
Br2 can exist as a gas (A), liquid (B), or solid (C) if p & T are the right values.
A measure of the weight of the atmosphere pressing down upon us. Pressure = Force Area Measured using a barometer - A device that can weigh the atmosphere above us.
In left diagram, p inside can = p outside can. In right, air is removed (pinside < poutside) and can collapses.
A Mercury Barometer
When you drink through a straw, you create a lower p above liquid, and the atmosphere pushes the liquid up.
Differential manometers. (a) Both columns are at the same height because both sides are exposed to the atmosphere; (b) the stopcock on the left is closed, and the stopcock on the right is open to the atmosphere. The difference in heights is a direct measure of the difference in pressure between the flask on the left and the atmospheric pressure.
P1V1 = P2V2
Pressure increases with depth & decreases with Height Ascending to quickly increases volume of gas in lungs leading to ailment called bends.
or:
An Experiment to Study the Relationship between the Volume and the Amount of a Gas
Avogadros law
The volume of a gas confined in an insulated cylinder will remain the same when its Kelvin temperature is doubled if, at the same time, the pressure also is doubled.
P1 x V1 T1
P2 x V2 T2
Calculations
Change of Conditions: Problem - I A gas sample in the laboratory has a volume of 45.9 L at 25 oC and a pressure of 743 mm Hg. If the temperature is increased to 155 oC by pumping (compressing) the gas to a new volume of 3.10 ml what is the pressure?
Change of Conditions: Problem II A weather balloon is released at the surface of the earth. If the volume was 100 m3 at the surface ( temp = 25 oC, P = 1 atm ) what will its volume be at its peak altitude of 90,000 ft where the temperature is - 90 o C and the pressure is 15 mm Hg ?
P1 = 1.0 atm
P2 x V2 T2 V2 =
P1V1T2 T1P2 =
n2 = n1 x V2 V1
mass SF6 = 3.39 mol SF6 x 146.07 g SF6 / mol = 496 g SF6
T2 = T1 x ( V2 / V1) T2 = 192 K
o
Ideal Gases
An ideal gas --a hypothetical gas whose properties (P, V, and T) are completely described by the ideal gas equation (or ideal gas law) The ideal gas equation is:
PV= nRT
R = Ideal, Universal, or Molar gas constant R = 0.08206 L atm mol-1 K-1
Boyles, Charles & Avogadros Laws are all combined into a single statement called the Ideal Gas law. law
at Standard Temperature and Pressure, the molar volume = 22.4 L P = 1.00 atm (by definition) T = 0 oC = 273.15 K (by definition) n = 1.00 moles (by definition)
R=
(38.37 mol )(0.0821 L atm)(291.95 K) = 10.5108 atm 87.5 L (mol K) = 10.5 atm
P = 2.26 atm
The Earths carbon atoms travel a constant cycle through the atmosphere, from air to plants and animals and back to the air again.
Nitrogen
Tasteless, colorless, nonflammable, relatively inert Nitrogen compounds are a limiting factor in plant growth.
Oxygen
Oxygen reacts with glucose during respiration.
Carbon dioxide
Central to plant growth through photosynthesis
Stratosphere
Contains UV absorbing ozone. Ozone is a natural and necessary component of this section.