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SEL VOLTA
Potensial Sel
Example 1: What are the anodic, cathodic and overall reactions responsible for the potensial in the elecrochemical cell shown here? Write the shorthand notation for the electrochemical cell
Example 2: what is the potential of the electrochemical cell shown in example 1 (Eo Fe3+/Fe2+ = +0.771 V ; Eo AgCl/Ag = +0.2223 V
Example 3: what is the concentration of Fe3+ in an electrochemical cell similar to that shown in example 1 if concentration of HCl in the left-hand cell is 1.0 M, the concentration of FeCl2 in the right-hand cell is 0.0151 M and the measured potential is +0.546 V
Potentiometric Cells
84,2 mV
Elektroda Pembanding
Elektroda yang mempunyai harga potensial tetap dan konstan dan tidak dipengaruhi konsentrasi analit dalam larutan
Elektroda Kalomel
Besarnya potensial sel: jika digunakan KCl jenuh + 0.2440 V jika [KCl] 3.5 M maka E = +0.2500 V jika [KCl] 0.1 M maka E = +0.3356 V
Elektroda Ag/AgCl
Besarnya potensial: jika digunakan KCl jenuh E = 0.199 V jika digunakan KCl 3.5 M maka E = 0.205 V
Elektroda Indikator
Elektroda yang potensialnya bergantung pada konsentrasi zat yang sedang diselidiki
Logam yang dicelupkan kedalam larutan ionnya Contoh: logam tembaga yang dicelupkan ke dalam larutan ion Cu2+
Example 4:
Calculate the formation constant Kf for Ag(CN)2- if the cell:
SCE || Ag(CN)2- (7.50 x 10-3 M, CN- (0.0250
Elektroda Redoks
Elektroda logam inert dicelupkan ke dalam larutan yang mengandung ion yang dapat mengalami reaksi reduksi/oksidasi di permukaan elektroda tersebut. Elektroda ini tidak terlibat dalam reaksi tersebut. Contoh: Fe3+, Fe2+Pt
Elektroda Membran
Selektifitas Membran
[A]E dan [I]E adalah konsentrasi analit dan pengganggu yang memberikan nilai potensial sel yang sama
Elektroda Gelas
Batas MembranLarutan
ESI Kalsium
Aktivitas vs Konsentrasi
Jika tetap
DebeyeHuckel
log =
0,51Z x2
1 + 3,3
Analisis Kuantitatif
What is the concentration of Ca2+ in the water sample if its cell potential is found to be -0.084 V?
Quantitative Analysis
Contoh: The concentration of Ca2+ in a sample of sea water is determinedusing a Ca ion selective and a one point standard addition. A 10.00 mL sample is transferred to a 100 mL volumetric flask and diluted to volume. A 50.00 mL aliquot of sample is placed in a beaker with the Ca ion-selective electrode and a reference electrode, and the potential is measured as -0.05290 V. A 1.00 mL aliquot of a 5.00 x 10-2 M standard solution of Ca2+ is added, and a potential of -0.04417 V is measured. What is the concentration of Ca in the sample of sea water?
Titrasi Potensiometri
Elektroda kerja dan elektroda pembanding dicelupkan ke dalam larutan analit. Potensial sel diamati selama penambahan titran. Titik akhir ditentukan dari kurva titrasi
Titrasi Potensiometri