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Free radical halogenation.ppt

Free radical halogenation.ppt

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Published by Jonathan Franklin

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Published by: Jonathan Franklin on Dec 02, 2013
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Free Radical Chlorination
 
Experimental Evidence Helps to Determine Mechanism
Chlorination does not occur at room temperature in the dark.
The most effective wavelength of light is blue that is strongly absorbed by Cl
2
 gas.
The light-initiated reaction has a high quantum yield (many molecules of product are formed from each photon of light).
 
Free Radical Species are Constantly
Generated Throughout the Reaction
Propagation

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