BI TP HIDROCACBON HAY V KH Cu 1. Hn hp X gm hirocacbon A v H2. un nng X vi xc tc Ni thu c kh Y duy nht. T khi hi ca Y so vi H2 gp 3 ln t khi hi ca X so vi H2.

t chy hon ton mt lng khc ca Y thu c 22 gam CO2 v 13,5 gam H2O. Xc nh cng thc cu to ca A: A. C3H4 B. C2H2 C. C3H6 D. C2H4 Cu 2. Thi 672 ml (ktc) hn hp kh A gm mt ankan, mt anken v mt ankin (u c s nguyn t cacbon trong phn t bng nhau) qua lng d dung dch AgNO3/NH3, th thy c 3,4 gam AgNO3 tham gia phn ng. Cng lng hn hp kh A nh trn lm mt mu va ht 200 ml dung dch Br2 0,15 M. Khi lng ankin trong A l: A. 0,39 gam B. 0,40 gam C. 0,26 gam D. 0,28 gam Cu 3: Trn mt th tch H2 vi mt th tch anken thu c hn hp X. T khi ca X so vi H2 l 7,5. Dn X i qua Ni nung nng thu c hn hp kh Y c t khi so vi H2 l 9,375. Phn trm khi lng ankan trong Y l A. 25%. B. 20%. C. 60%. D. 40%. Cu 4: t chy hon ton mt lng hn hp kh X gm mt ankan v mt anken cn dng va 0,7 mol O2 thu c 0,4 mol CO2. Cng thc ca ankan l A. C2H6. B. CH4. C. C4H10. D. C3H8. Cu 5: Hn hp kh X gm H2 v mt anken c t khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. S ng phn anken (k c ng phn hnh hc) tha mn l: A. 2 B. 3 C. 4. D. 5 Cu 6: Hn hp kh X gm xiclopropan, etan, propen, buta-1,3-ien c t khi so vi H2 l 18. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh gim m gam. Gi tr ca m l A. 4,3 B. 9,8 C. 2,7 D. 8,2 Cu 7: Thc hin phn ng tch 15,9 gam hn hp gm butan v pentan (c t l mol tng ng l 3 : 2) iu kin thch hp thu c hn hp X gm cc hirocacbon mch h v hiro c t khi so vi H2 bng 15. X phn ng ti a vi bao nhiu gam brom trong CCl4? A. 40,0 gam. B. 44,8 gam. C. 56,0 gam. D. 84,8 gam Cu 8: t chy hon ton hn hp A hai ankin X,Y. Hp th ton b sn phm chy vo 4,5 lt dd Ca(OH)2 0,02M thu c kt ta v khi lng dd tng 3,78gam so vi ban u. Cho dd Ba(OH)2 va vo dd thu thm kt ta. Tng kt ta hai ln l 18,85 gam. Bit rng s mol X bng 60% s mol ca hn hp A. Cc phn ng xy ra hon ton. Cng thc ca X,Y ln lt l A C4H6 v C2H2 B C2H2 v C3H4 C C2H2 v C4H6 D C3H4 v C2H2 Cu 9: Hn hp X gm axetilen, etilen v hidrocacbon A chy hon ton thu c CO2 v H2O theo t l mol 1:1. Dn X i qua bnh ng dung dch brom d thy khi lng bnh tng ln 0,82 gam, kh thot ra khi bnh em t chy hon ton thu c 1,32 gam CO2 v 0,72 gam H2O. % V ca A trong X l: A. 75 B. 50 C. 33,33 D. 25 Cu 10: Tin hnh nhit phn hn hp X gm butan v heptan (t l 1:2 v s mol) th thu c hn hp Y (Gi s ch xy ra phn ng cracking ankan vi hiu sut 100%). Xc nh khi lng phn t trung bnh ca Y A. MY =43 B. 32 MY 43 C. 25,8 MY 32 D. 25,8 MY 43 Cu 11. Hn hp X gm hiro, propen, propanal, ancol alylic. t 1 mol hn hp X thu c 40,32 lt CO2 (ktc). un X vi bt Ni mt thi gian thu c hn hp Y c t khi so vi X l 1,25. Nu ly 0,1 mol hn hp Y th tc dng va vi V lt dung dch Br2 0,2M. Gi tr ca V l A. 0,20 lt B. 0,40 lt C. 0,30 lit D. 0,25lit Cu 12: Mt hn hp X gm 1 ankan A v 1 ankin B c cng s nguyn t cacbon. Trn X vi H2( va ) c hn hp Y. Khi cho Y qua Pt, xc tc th thu c kh Z c t khi i vi CO2 bng 1 (phn ng cng H2 hon ton). Bit rng Vx = 6,72 lt v VH2 = 4.48 lt. Cc th tch kh c o ktc. CTPT v s mol ca A, B trong hn hp X l A. C2H6,C2H2, 0,2 mol C2H6, 0,2 mol C2H2 B. C2H6,C2H2, 0,1 mol C2H6, 0,2 mol C2H2 C. C3H8,C3H4, 0,1 mol C3H8, 0,2 mol C3H4 D. C3H8,C3H4, 0,2 mol C3H8, 0,1 mol C3H4 Cu 13: Hn hp X gm ankin Y v H2 c t l mol l 1 : 2. Dn 13,44 lt hn hp X (ktc) qua Ni, nung

nng thu c hn hp Z c t khi so vi H2 l 11. Dn hn hp Z qua dung dch Br2 d, sau phn ng hon ton thy c 32 gam Br2 phn ng. Cng thc ca ankin Y l: A. C2H2. B. C4H6. C. C3H4. D. C5H8. Cu 14. Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X vo bnh kn c cha Ni xc tc, nung nng bnh mt thi thu c hn hp Y. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra hn hp kh c khi lng m gam. t chy hon ton hn hp Y thu c 44 gam CO2. Gi tr m l. A. 17,2gam B. 2,2gam C. 15,2gam D. 3,2gam Cu 15: Cho hn hp A gm C2H2 v H2 qua Ni nung nng thu c hn hp kh B ch gm cc hirdocacbon c MB = 28,5. Gi tr MA = ? A.11,67 B. 12,67 C.11. D. 12. Cu 16: Hn hp A gm 1 ankan X v 2 hidrocacbon Y,Z thuc 2 dy ng ng khc nhau. Hn hp B gm O2 v O3 c t khi so vi He l 72/7 . t chy 11,2 lit A cn va 784/15 lit B ktc v thu c CO2 v H2O c t l mol l 1:1. Nu cho 0,5 mol A qua dd Br2 d th cn li 5,6lit kh bay ra v dung dch tng 13,5 g. Cn nu dn 0,5 mol A qua dd AgNO3/NH3 th thu c 16,2g kt ta vng. T khi ca A so vi He v X l: A. 28 v C3H8 B. 28 v C4H10 C. 14 v C4H10 D. 14 v C3H8 Cu 17: Crackinh mt lng pentan thu c hn hp X gm C5H12, C5H10, C 5H8, C5H6, H2 . T khi ca X so vi hidro l 14,4. Nu cho 0,6 mol X qua dung dch brom d th s mol Brom phn ng l: A. 0,36 mol B. 0,45 mol. C. 0,6 mol. D. 0,8 mol. Cu 18: X l mt hircacbon mch h cha khng qu 3 lin kt bi trong phn t. Hn hp Y gm X v lng H2 gp i lng cn thit hir ha hon ton X. Cho hn hp Y qua Ni nung nng, sau phn ng thu c Z c t khi so vi hir l 31/3. t m gam Z cn va 13,44lit O2 (ktc). Hp th hon ton sn phm chy vo 400ml dd Ca(OH)2 0,5M v KOH 0.25M thu c khi lng kt ta l A 33,49g B 35,46g C 37,43g D 39,4g
p n cu 3: Ta c nAnken = nH2(v cng trn mt th tch) -> (1.X + 1.2)/2=7,5.2 -> X=28 Anken l C2H4 . C1: C2H4 + H2 -> C2H6 a mol ---> a --> a sau phn ng c : x -a mol C2H4 ,a mol C2H6 ,x-a mol H2 28(x-a) + 2(x-a) + 30a = 18,75 ( x-a + x-a + a) -> 30x = 37,5x - 18,75a -> 7,5x = 18,75a -> a = 0,4x -> %C2H6 = 0,4x.30 / (0,4x.30 + 0,6x .28 + 0,6x .2) = 40% . C2: nhn hp trc / nhn hp sau = Msau / Mtrc = 1,25 Chn nhn hp trc = 1 mol -> nhn hp sau = 0,8 n C2H6 = n H2p = 1 0,8 = 0,2 mol -> %?