Cc chuyn luyn thi H

Gio vin: Bi Quang Chnh

CC DNG BI TON V CHT BO

Loi 1 : Cch tnh mono i tri este trong cht bo Phng php
Dng 1: Tnh s loi Tri este Khi cho glixerol + n (n Z*) axit bo th s loi trieste to ra c tnh theo cng thc: Loi trieste Trieste cha 1 gc axit ging nhau Trieste cha 2 gc axit khc nhau Trieste cha 3 gc axit khc nhau Cng thc chung tng s trieste Vi n=1 s trieste = 1 Vi n=2 s trieste = 2 + 4.C22 Dng 2: Tnh s loi mono este, i - este Khi cho glixerol + n axit bo th s loi mono este v i este to ra c tnh theo cng thc: Loi este Mono este i este i este cha 1 loi gc axit i este cha 2 loi gc axit khc nhau Tng = 2n = 3.Cn2 (n 2) = 2n + 2n + 3.Cn2 = 2n Cng thc (s loi) Cng thc (s loi) =n = 4.Cn2 = 3.Cn3 = n + 4.Cn2 + 3.Cn3 (n 3) Vi n=3 s trieste = 3 + 4.C32 + 3.C33 Vi n4 s trieste = n + 4.Cn2 + 3.Cn3 Cng thc (s loi trieste)

Bi tp
Cu 1: Cho glixerol phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste c to ra ti a l bao nhiu? (S: 6) Cu 2: Cho glixerin tc dng vi hn hp 3 axit bo gm C17H35COOH, C17H31COOH, C17H33COOH th to ra bao nhiu loi cht bo? (S: 18) Cu 3: Cho glixerin tc dng vi hn hp 3 axit bo gm C17H35COOH, C17H31COOH, C17H33COOH th to ra bao nhiu sn phm este? (S: 39) Cu 4: Cho glixerol phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi mono i tri este v tng s este thu c l bao nhiu?

Loi 2 : Tnh ch s axit este x phng ha v ch s iot

Phng php 1. Ch s axit bo l s mg KOH cn thit trung ha ht lng axit bo t do c trong1 gam cht bo. hoc c th: Khi 2 Ca Nam - TP Vinh Cng thc tnh t hp

Cc chuyn luyn thi H 2.

Gio vin: Bi Quang Chnh

Ch s iot l s gam iot phn ng ht vi s lin kt C = C c trong 100 gam cht bo.

- Tnh s lin kt trong gc axit: CxHy th - Nu tnh trong 3 nhm (CxHyCOO)3 = 3. S mol iot = s . ncht bo

Ch s x phng l tng lng mg KOH cn trung ha ht axit t do v x phng ha ht lng este trong 1gam cht bo.

4.

Ch s este l s mg KOH cn thit x phng ha ht lng este c trong1 gam cht bo

Bi tp
Cu 1: trung ha lng axit bo t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH 0,1M. Ch s axit ca mu cht bo trn l bao nhiu? (S: 6) Cu 2: Khi x phng ha 1,26 gam mt cht bo cn 45ml dung dch KOH 0,1M. xc nh ch s x phng ca cht bo ? (S: 200) Cu 3: Tng s miligam KOH trung ha ht lng axit t do v x phng ha ht lng este trong 1 gam cht bo gi l ch s x phng ha cu cht bo. Tnh ch s x phng ha ca mi cht bo c ch s axit l 7 cha tristearoylglixerol cn ln mt lng axits stearic. (S: 189) Cu 4: Tnh ch s iot cht bo glixerin oleat? (S: 86,2)

Loi 3 : Bi ton v phn ng x phng ha cht bo Bi tp

Cu 1: Thy phn hon ton 444 gam mt lipit thu c 46 gam glixerol v hai loi axit bo. Xc nh 2 loi axit bo . (S: C17H33COOH v C17H35COOH) Cu 2: X phng ha hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l bao nhiu? (S: 17,8 gam) Cu 3: X phng ha hon ton 66 gam lipit cn dng 12 gam NaOH. Khi lng x phng thu c l bao nhiu? (S: 68,8 gam) Cu 4: X phng ha hon ton 8,6 gam cht bo bng 1,2 gam NaOH v thu c 0,92 gam glyxerol v cc axit bo. Khi lng phn t trung bnh ca axit bo l bao nhiu? (S: 274 vC) Cu 5 : Thy phn hon ton 8,06kg cht bo trung tnh cn va 1,2 kg NaOH. Khi lng glixerin v mui to thnh ln lt l bao nhiu? (S: 920gam, 8,34kg)

Khi 2 Ca Nam - TP Vinh

Cng thc tnh t hp