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ABSTRAK

Reaktor Fasa Cair adalah tempat berlangsungnya suatu reaksi kimia dimana dinyatakan sebagai pusat suatu proses kimia. Tujuan percobaan Reaktor Fasa Cair ini adalah untuk mengetahui dan mempelajari cara kerja dan performance reaktor fasa cair, dan menentukan persamaan kecepatan reaksi, orde reaksi, dan konstanta kecepatan reaksi reaktan. Selain itu juga dapat mengetahui hubungan konsentrasi reaktan dan laju reaksi terhadap perubahan waktu, serta mengetahui hubungan konversi reaktan dan laju alir terhadap perubahan waktu. Percobaan ini dilakukan dengan mereaksikan NaOH dan etil asetat, vA = vB = 645 ml/menit dengan variasi pengadukan = 125 rpm, 225 rpm, dan 325 rpm. Pengambilan sampel setiap 5 menit sebanyak 5% dari volume total, sampel lalu ditambahkan phenolphthalein, kemudian dititrasi dengan larutan HCl 0,1 M hingga warna merah rosa hilang dan pengambilan sampel dihentikan bila volume HCl telah konstan. Dari percobaan diperoleh persamaan kecepatan reaksi untuk pengadukan 125 rpm adalah -rA = 1,011 CA0,702 mol.ml-1.menit-1, untuk pengadukan 225 rpm adalah -rA = 1,125CA0,601 mol.ml1 .menit-1 dan pengadukan 325 rpm adalah -rA = 1,169 CA0,659 mol.ml-1.menit-1. Kata kunci : kecepatan reaksi, konstanta kecepatan reaksi, orde reaksi, pengadukan reaktor fasa cair

ABSTRACT

Liquid Phase Reactor is the venue for a chemical reaction which is expressed as a center of chemical processes . The purpose of the Liquid Phase Reactor experiment is to find out and learn how to work and liquid phase reactor performance, to determine the reaction rate equation, the reaction order and the reaction rate constants of the reactants. It also can determine the relationship of the concentration of the reactants and the reaction rate to changes in time, and to know the relationship and the conversion of the reactant flow rate to changes in time . This experiment was carried out by reacting NaOH and ethyl acetate , v A = vB = 645 ml / min with a variation speed of agitation = 125 rpm, 225 rpm, and 325 rpm. 5% (v/v) of total volume sample was taken every 5 minutes, then samples was added by phenolphthalein, then the samples was titrated with 0.1 M HCl until the red color disappeared red and sampling was stopped when the volume of HCl has been constant. From the obtained experimental equation for the reaction rate for 125 rpm is- rA = 1.011 CA0,702 mol.ml-1.menit-1, for 225 rpm is - rA = 1.125 CA0,601 mol.ml1 .menit-1 and for 325 rpm is - rA = 1.169 CA0,659 mol.ml-1.menit-1. Keywords : rate reaction , the reaction rate constants , reaction order , stirring liquid phase reactor

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