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Bowen 2005 Ans Key

Bowen 2005 Ans Key

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Bowen Sec Sch2005 Preliminary ExaminationsChemistry (5068)P1 Answers
1.B2.C3.D4.A5.A6.B7.C8.D9.A10.C11.C12.A13.B14.B15.C16.D17.A18.C19.D20.D21.C22.B23.A24.D25.B26.C27.A28.D29.C30.C31.B32.B33.B34.B35.D36.A37.C38.D39.B40.C
 
PRELIM EXAM 2005Paper 2CHEMISTRY 5068/2ANSWER KEYSECTION AQnNoPartSubpartAnswerMarksA1a
lithium oxide
1b
carbon monoxide
1c
sulphur trioxide
1d
aluminium oxide
1e
vanadium (V) oxide
1
Sulphur dioxide, carbon dioxide or sulphur trioxide
1A2a
Ionic bonding with cation and anioncorrectly shownStable octet clearly indicated
(Do not read further if ionic bonding is not indicated.)
11b
Covalent bonding clearly shownElectrons correctly shared between Cl andO
(Do not read further if covalent bonding isnot indicated.)
11c
SiO
2
- giant molecular structureP
4
O
6
– simple molecular structureMore energy needed to break the networkof bonds in SiO
2
than the bonds in P
4
O
6
111A3a
Burette or pipette
1b
It is a catalyst.
1c
A colourless solution of sodium chlorideand a black precipitate of manganese (IV)oxide
1
 
di
No of moles of NaClO
3
used =(20*0.1)/1000= 0.002Number of moles of O
2
expected =(0.002*3)/2= 0.003Volume of O
2
= 0.003*24
 
= 0.0 72 dm
3
11ii
O
2
is soluble in water.
1A4a
Fractional distillation of liquid air 
1b
Catalytic cracking of petroleum
1
c
There would be more collisions betweenthe particles.This would increase the speed of thereaction
11
d
NH
4
NO
3
: (28/80)*100(NH
4
)
2
SO
4
: (28/132)*100(NH
2
)
2
CO : (28/60)*100Urea has the most nitrogen per kilogram
11
ei
Addition polymerisationThere is a carbon to carbon double bond inthe monomer or it is unsaturated.
11
ii
Polyacrylonitrile
1
iii
Structural formula of polyacrylonitrile withC-C bonds
1A5
a
H – F bondIts bond energy is the highest.
11b
H
2
+ F
2
 
2HFEnthalpy change = 436 + 158 – 2(565)= - 536 kJmol
-1
(No marks if sign is not shown)
11

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