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Synthetic Inorganic Chemistry Blanchard 5thed1937

Synthetic Inorganic Chemistry Blanchard 5thed1937

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Published by: rhozab on Oct 05, 2009
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SYNTHETICINORGANIC CHEMISTRY
A COURSE
OF
LABORATORY
AND
CLASSROOMSTUDY
FOR
FIRST YEAR COLLEGE STUDENTSBYARTHUR
A.
BLANCHARD,
Ph.D.
Professor
of
Inorganic Chemistry
ANDJOSEPH
W.
PHELAN,
S.B.
Late
Professor
of
Inorganic Chemistry
ANDARTHUR
R.
DAVIS,
Ph.D.
Assistant
Professor
of
Chemistry
at the
Massachusetts Institute
of
Technology
FIFTH EDITION
NEW YORKJOHN WILEY
&
SONS,
INC.
LONDON:
CHAPMAN & HALL,
LIMITED
1936
 
COPYRIGHT, 1908, 1910, 1916,
BY
ARTHUR A. BLANCHARD1908 Copyright renewed 19351910 Copyright renewed 1937
COPYRIGHT, 1922, 1930,
BY
A. A. BLANCHARD
AND
J. W. PHELAN
COPYBIQHT, 1936,
BY
ARTHUR A. BLANCHARD, ARTHUR R. DAVIS
AND
ROBERT K. PHELAN
All Rights
ReservedThis book or
any
part thereof must not
be
reproduced
in any form
withoutthe written permission
of
the
publisher.
Printed in U. S. A. 4-39Printing Composition Binding
F.
H.
GXSON
CO.
TECHNICAL COMPOSTON
CO.
STANHOPE BINDEBY
BOSTON BOSTON BOSTON
 
PREFACE TO FIFTH EDITIONSix years have elapsed since the appearance of the FourthEdition of this book. The general plan and purposes of the coursetherein outlined have continued to meet satisfactorily the problemof first-year college students in chemistry, yet the number ofimprovements and supplementary preparations and exercises thatthe present authors have accumulated and in part used hi piano-graph form has so increased that a new edition seems to be in order.A very considerable portion of the text has been wholly rewritten,and the entire text has been subjected to a revision and rearrange-ment. Specific new exercises and discussions which have beenintroduced include such topics as the determinations of vapordensity and molecular weight, the standardization of acids andthe titration of acids and bases, Faraday's law, and the use of thepH scale of hydrogen-ion concentration. Several new prepara-tions have been introduced, and a few of the old ones have beendiscontinued. A complete list of apparatus and chemicals re-quired in the course has been added to the Appendix.The purpose of this, as well as of the former editions, may beindicated by a brief statement of the manner in which it is usedwith the large freshman class at the Massachusetts Institute ofTechnology. The entire year's work for both laboratory andclass room is outlined in this book. Each year a list of experi-ments and preparations is made out and posted. All studentsare supposed to perform these exercises (thirty laboratory periodsof three hours each in the course), and the class room exercises(sixty hours) are built around the methods and principles of thiswork. The lectures in chemistry (sixty hours) follow approxi-mately the order in which the elements are taken up in the book,but no attempt is made to keep in exact step. The historical, in-dustrial, and economic aspects of chemistry are left largely to thelectures, whereas the discussion of problems, both numerical andmanipulative, is left for class room and laboratory.The students of barely passing grade may not complete morethan the posted exercises, but to the enthusiastic student is opena free choice of the other preparations, subject of course to the

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