TEKNIK REAKSI KIMIA Tugas Soal BAB V (Octave Levenspiel)

Dosen Pengajar : Dr. Ir. H. Susila Arita R., DEA Anggota :

1. Nessa Selviany (03111003014) 2. Karina Mandasari (03111003036) 3. Cahyo Nugroho (03111003094) 4. Dwi Sunu Permatahati (03111003098) 5. Ahmad Ambari (03111003102)

FAKULTAS TEKNIK JURUSAN TEKNIK KIMIA UNIVERSITAS SRIWIJAYA INDRALAYA 2013

5.3. A stream of aqueous monomer A (1 mol/liter, 4 liter/min) enters a 2-liter mixed flow reactor, is radiated therein, and polymerized as follows: A R S T

In the exit stream CA= 0.01 mol/liter, and for a particular reaction product W, Cw = 0.0002 mol/liter. Find the rate of reaction of A and the rate of formation of W. Penyelesaian : Diketahui : CAo = 1 mol/L = 4 L/menit V = 2 liter Cwf = 0.0002/L CAf = 0.01 mol/L Ditanya : -rA = ? rw = ? Jawab : Untuk mixed flow reactor : -rA = -rA = -rA = -rA = -rA = 1,98 mol/L menit

rw = rw = rw = rw =

rw = 0.0004 mol/L menit

5.5. An aqueous feed of A and B (400 liter/min, 100 mmol A/liter, 200 mmol B/liter) is to be converted to product in a plug flow reactor. The kinetics of the reaction is represented by A+B R. rA = 200 CA CB

Find the volume of reactor needed for 99.9% conversion of A to product. Penyelesaian : Diket : Plug flow reactor CAO = 100 mmol/ min = 0.1 mol/ min CBO = 200 mmol/min = 0.2 mol/min = 400 liter/min A+B R. rA = 200 CA CB k = 200 Ditanya : V =? Jawab : Orde reaksi = 2, berdasarkan persamaan 5.14 k CAo (M 1) = ln [ M= = ] , dimana M = =2 ] ] 1 XA = 0.999

k CAo (M 1) = ln [

200 0.1 mol/min (2-1) = ln [

[ ]

= = 0.31/ menit

Volume Reaktor V= . V = 0.31 menit . 400 liter/menit V = 124 liter