Professional Documents
Culture Documents
SULIT 4541/1
4541/1 http://spmchem.blogspot.com/
CHEMISTRY
Kertas 1
Sept. 2009
1¼ jam
CHEMISTRY
Paper 1
SULIT 2 4541/1
http://spmchem.blogspot.com/
3. Answer each question by blackening the correct space on the answer sheet.
Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan.
5. If you wish to change your answer, erase the blackened mark that you have made.
Then blacken the space for the new answer.
Sekiranya anda hendak menukar jawapan, padamkan tanda yang telah dibuat.
Kemudian hitamkan jawapan yang baru.
6. The diagrams in the questions provided are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukis mengikut skala kecuali dinyatakan.
SULIT 3 4541/1
http://spmchem.blogspot.com/
1 Which of the following substances exists as atoms?
Antara bahan berikut, yang manakah wujud sebagai atom?
A Carbon
B Oxygen
C Water
D Chlorine
A Hydrochloric acid
B Ethanoic acid
C Sulphuric acid
D Nitric acid
SULIT 4 4541/1
http://spmchem.blogspot.com/
4 Which of the following is a property of iodine?
Antara berikut, yang manakah sifat iodin?
A Accepts an electron
Menerima satu elektron
B Releases an electron
Membebas satu elektron
C Accepts two electrons
Menerima dua elektron
D Shares a pair of electrons
Berkongsi sepasang elektron
A Glucose
B Copper
C Naphthalene
D Sodium chloride
SULIT 5 4541/1
http://spmchem.blogspot.com/
8 Diagram 1 shows the set-up of apparatus of a chemical cell.
Rajah 1 menunjukkan susunan radas bagi sel kimia.
Diagram 1
Which of the following substances is most likely to be Y?
Antara bahan berikut, yang manakah mungkin Y?
A Iron
B Magnesium
C Silver
D Copper
Diagram 2
SULIT 6 4541/1
http://spmchem.blogspot.com/
10 Which of the following statements is true about an acid?
Antara pernyataan berikut, yang manakah benar tentang asid?
2HCl + Mg → MgCl 2 + H 2
Which of the following statements will increase the rate of production of hydrogen
gas ?
Antara pernyataan berikut, yang manakah akan meningkatkan kadar penghasilan
gas hidrogen?
A Polypropene
B Polysaccharide
C Polyisoprene
D Silk
SULIT 7 4541/1
http://spmchem.blogspot.com/
14 Which of the following salt can be prepared by double decomposition reaction?
Antara garam berikut, yang manakah boleh disediakan melalui tindak balas
penguraian ganda dua?
A Sodium nitrate
B Potassium carbonate
C Calcium sulphate
D Magnesium chloride
H H O H
Figure 3
H C C C O C H
H H H
Based on the figure above, what is the general formula of the compound?
Berdasarkan rajah di atas, apakah formula am bagi sebatian tersebut?
A C n H 2n COOH
B C n H 2n+1 COOH
C CH 2n+1 COO C m H 2m+1
D C n H 2n+1 COO C m H 2m+1
16 Which of the following pairs of compounds are in the same homologous series?
Manakah antara pasangan sebatian berikut berada dalam siri homolog yang
sama?
Compound 1 Compound 2
A C2H4 C3 H6
B C2H6 C3 H6
C C 2 H 5 OH CH 3 CO 2 H
D C 2 H 5 OH C 2 H 5 COOH
A Paracetamol
B Streptomycin
C Antiseptic
D Aspirin
SULIT 8 4541/1
http://spmchem.blogspot.com/
18 The heat of neutralisation between hydrochloric acid and potassium hydroxide is
higher than the heat of neutralisation between ethanoic acid and potassium
hydroxide because
Haba peneutralan antara asid hidroklorik dan kalium hidroksida adalah lebih
tinggi daripada haba peneutralan antara asid etanoik dan kalium hidroksida
kerana
I potassium ion, K+
II magnesium ion, Mg2+
III calcium ion, Ca2+
IV hydroxide ion, OH –
A I and II only
B II and III only
C I and III only
D III and IV only
20. Aspirin is a medicine for headache, but it can also cause stomachache. Why?
Aspirin ialah ubat untuk sakit kepala, tetapi ia juga boleh mengakibatkan sakit
perut. Mengapa?
SULIT 9 4541/1
http://spmchem.blogspot.com/
21 Diagram 4 shows the heating curve of solid naphthalene.
Rajah 4 menunjukkan kelok pemanasan pepejal naftalena.
Diagram 4
23
22 The symbol of sodium atom is 11 Na
The nucleus of this atom contains
23
Simbol atom natrium adalah 11 Na
Nukleus atom ini mengandungi
SULIT 10 4541/1
http://spmchem.blogspot.com/
23 Diagram 5 shows an apparatus set-up for a chemical cell prepared by a student.
Rajah 5 menunjukkan susunan radas bagi sel kimia yang disediakan oleh seorang
pelajar.
Diagram 5
The student wants to modify the chemical cell so that it produces a higher
voltage. What modification should the student make?
Pelajar tersebut ingin mengubahsuai sel kimia itu supaya voltan yang dihasilkan
adalah lebih tinggi. Apakah pengubahsuaian yang perlu dilakukan oleh pelajar
tersebut?
Figure 6
A Iron
B Nickel
C Platinum
D Vanadium(V) oxide
SULIT 11 4541/1
http://spmchem.blogspot.com/
26 The information below shows three characteristics of a compound P.
Maklumat berikut mununjukkan tiga ciri bagi sebatian P.
Soluble in water
High melting and boiling points
Does not conduct electricity in the solid state
What is P?
A Zinc
B Sulphur
C Silver chloride
D Sodium nitrate
Diagram 7
Which of the following half-equations represents the reaction that occurred at
electrode P?
Antara persamaan setengah berikut, yang manakah mewakili tindak balas yang
berlaku di elektrod P?
A Na+ + e Na
+
B 2H + 2e H2
C 2Cl- Cl 2 + 2e
D 4OH- O 2 + 2H 2 O + 4e
A -2
B 0
C +7
D +8
SULIT 12 4541/1
http://spmchem.blogspot.com/
29 A precipitate is formed when hydrochloric acid is added to solution X. Which of
the following solutions is most probably solution X?
Mendakan terbentuk apabila asid hidroklorik ditambah kepada larutan X.
Antara larutan berikut, yang manakah mungkin larutan X?
A Zinc nitrate
B Silver nitrate
C Calcium nitrate
D Magnesium nitrate
Figure 8
The atom of element X can form a covalent bond with another atom through
Atom unsur X membentuk ikatan kovalen dengan atom lain melalui
31 Potassium and sodium are in the same group in the Periodic Table. Which of the
following statements is true about potassium?
Kalium dan natrium adalah dalam kumpulan yang sama dalam Jadual Berkala.
Antara pernyataan berikut, yang manakah benar mengenai kalium?
SULIT 13 4541/1
http://spmchem.blogspot.com/
32 Figure 9 shows an ester produced when an alcohol reacts with a carboxylic acid.
Gambarajah 9 menunjukkan sejenis ester yang terhasil apabila sejenis alkohol
bertindak balas dengan sejenis asid karboksilik.
O
II
CH 3 CH 2 C O CH 2 CH 2 CH 3
Figure 9
Which of the substances are used in the reaction?
Manakah antara sebatian berikut digunakan dalam tindak balas tersebut?
A CH 3 CH 2 OH
B
CH 3 CH 2 CH 2 OH
CH 3 CH 2 CH 2 CHOH
C
D CH 3 CH 2 CH 2 OH
33 Iron(III) ion, Fe3+ in solution can be converted into iron(II) ion, Fe2+ by adding
zinc powder.
Which of the following can replace zinc powder in the reaction?
Larutan yang mengandungi ion ferum(III), Fe3+ boleh ditukarkan ke ion
ferum(II), Fe2+ dengan menambahkan serbuk zink.
Antara berikut yang manakah boleh menggantikan serbuk zink di dalam tindak
balas ini?
A Bromine water
B Potassium iodide solution
C Potassium hexacyanoferrate(II) solution
D Acidified potassium manganate(VII) solution
SULIT 14 4541/1
http://spmchem.blogspot.com/
34 Figure 10 shows the graph of total volume of carbon dioxide against time for the
reaction of a metal carbonate with dilute acid for experiment P and experiment Q.
Rajah 10 menunjukkan graf bagi jumlah isipadu karbon dioksida melawan masa
bagi tindak balas karbonat logam dengan asid cair bagi eksperimen P dan
eksperimen Q.
Figure 10
Which of the following explains the differences between both curves from the
experiments?
Antara berikut, yang manakah menerangkan perbezaan antara dua lengkuk bagi
eksperimen tersebut?
SULIT 15 4541/1
http://spmchem.blogspot.com/
35 Figure 11 shows the energy level diagram that represents the reaction between A
and B.
Rajah 11 menunjukkan gambar rajah aras tenaga mewakili tindak balas antara A
dan B.
Figure 11
A T2
B T2 – T1
C T3 - T1
D T3 – T2
A 39
B 55
C 62
D 78
A XO 2
B X2O
C X2O3
D X2O5
SULIT 16 4541/1
http://spmchem.blogspot.com/
38 2.10 g of element Q combined with 0.80 g of element R to produce a compound
with formula Q 3 R 4 . What is the relative atomic mass of element Q?
2.10 g unsur Q berpadu dengan 0.80 g unsur R untuk menghasilkan sebatian
dengan formula Q 3 R 4 . Berapakah jisim atom relatif unsur Q?
[Relative atomic mass : R = 16]
A 14
B 42
C 56
D 58
A 114
B 116
C 118
D 132
40 A beaker contains 100 cm3 of 0.5 mol dm-3 sodium hydroxide solution.
Calculate the number of moles of sodium hydroxide in the beaker.
Sebuah bikar mengandungi 100 cm3 larutan natrium hidroksida 0.5 mol dm-3.
Hitung bilangan mol bagi natrium hidroksida dalam bikar.
A 0.05
B 0.50
C 5.00
D 50.0
41 The following equation represents the reaction between hydrochloric acid and
sodium hydroxide.
Berikut ialah persamaan yang mewakili tindak balas antara asid hidroklorik dan
natrium hidroksida.
NaOH + HCl NaCl + H 2 O
What is the mass of sodium chloride formed when 100 cm3 of 0.5 mol dm-3
hydrochloric acid reacts with excess sodium hydroxide solution?
Apakah jisim natrium klorida yang terbentuk apabila 100 cm3 asid hidroklorik 0.5
mol dm-3 bertindak balas dengan larutan natrium hidroksida berlebihan?
[Relative atomic mass: Na = 23, Cl = 35.5]
A 50.0 g
B 5.85 g
C 2.93 g
D 3.55 g
SULIT 17 4541/1
http://spmchem.blogspot.com/
42 Which of the following shows the wrong combination of properties for alloy and
its pure metal?
Antara berikut manakah menunjukkan padanan tentang sifat aloi dan logam
tulennya yang salah?
43 Figure 12 shows the graph of total volume of oxygen gas released against time for
the decomposition of hydrogen peroxide.
Rajah 12 menunjukkan graf bagi jumlah isipadu gas oksigen yang terbebas
melawan masa untuk penguraian hidrogen peroksida.
Figure 12
SULIT 18 4541/1
http://spmchem.blogspot.com/
44 Graph 1 in Figure 13 is obtained from the reaction between 5 g of large marble
chips and 100 cm3 1.0 mol dm-3 of hydrochloric acid.
Graf I dalam Rajah 13 dihasilkan daripada tindak balas antara 5 g ketulan
marmar dan 100 cm3 1.0 mol dm-3 asid hidroklorik.
Figure 13
A 5 g large marble chips added to 100 cm3 1.0 mol dm-3 hydrochloric acid
5 g ketulan marmar ditambah kepada 100 cm3 1.0 mol dm-3 asid hidroklorik
B 5 g crushed marble chips added to 100 cm3 1.0 mol dm-3 hydrochloric acid
5 g serbuk marmar ditambah kepada 100 cm3 1.0 mol dm-3 asid hidroklorik
C 5 g large marble chips added to 50 cm3 1.0 mol dm-3 hydrochloric acid
5 g ketulan marmar ditambah kepada 50 cm3 1.0 mol dm-3 asid hidroklorik
D 5 g crushed marble chips added to 50 cm3 1.0 mol dm-3 hydrochloric acid
5 g serbuk marmar ditambah kepada 50 cm3 1.0 mol dm-3 asid hidroklorik
P + 3O 2 2CO 2 + 3H 2 O
What is compound P?
Apakah sebatian P?
A C2 H4
B C2 H6
C C 2 H 5 OH
D C 3 H 7 OH
SULIT 19 4541/1
http://spmchem.blogspot.com/
46 W is located between magnesium and iron in the reactivity series of metals.
Which oxide cannot be reduced by W?
W terletak di antara magnesium dan besi dalam siri kereaktifan logam.
Oksida manakah tidak boleh diturunkan oleh W ?
A Calcium oxide
B Silver oxide
C Tin(II) oxide
D Copper(II) oxide
48 Figure 14 shows the energy level diagram for a reaction between zinc and
copper(II) sulphate solution.
Rajah 14 menunjukkan gambar rajah aras tenaga bagi tindak balas antara zink
dan larutan kuprum(II) sulfat.
Figure 14
Calculate the temperature change when excess zinc is added to 100 cm3 of
0.1 mol dm–3 copper(II) sulphate solution .
Kira perubahan suhu apabila zink berlebihan ditambah kepada 100 cm3 larutan
kuprum(II) sulfat 0.1mol dm –3.
[Specific heat capacity of water = 4.2 J g-1 oC-1]
A 2 oC
B 4o C
C 6o C
D 8o C
SULIT 20 4541/1
http://spmchem.blogspot.com/
49 The following is a thermochemical equation.
Berikut ialah suatu persamaan termokimia.
HCl + NaOH NaCl + H 2 O ∆H = -57 kJ/mol
Calculate the quantity of heat energy released when 200 cm3 2.0 mol dm-3
hydrochloric acid is added to 300 cm3 2.0 mol dm-3 sodium hydroxide solution.
Hitung kuantiti haba yang dibebaskan apabila 200 cm3 2.0 mol dm-3 asid
hidroklorik ditambah kepada 300 cm3 2.0 mol dm-3 larutan natrium hidroksida.
A 5.70 kJ
B 11.4 kJ
C 17.1 kJ
D 22.8 kJ
Figure 15
A X, iron, Y
B Y, iron, X
C Iron, X, Y
D Iron, Y, X
SULIT 4541/2
4541/2 http://spmchem.blogspot.com/
CHEMISTRY
Kertas 2
Sept.2009
2½
No.jam
Kad P
CHEMISTRY
Paper 2
Two hours and thirty minutes
SULIT
SULIT 2 4541/2
http://spmchem.blogspot.com/
2. Answer all questions in Section A. Write your answers for Section A in the spaces
provided in the question paper.
Jawab semua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam
ruang yang disediakan dalam kertas soalan
3. Answer one question from Section B and one question from Section C.
Write your answers for Section B and Section C on the `writing paper’ provided by the
invigilators.
Answer questions in Section B and Section C in detail.
You may use equations, diagrams, tables, graphs and other suitable methods to explain
your answer.
Jawab satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C.
Tuliskan jawapan bagi Bahagian B dan Bahagian C pada halaman bergaris di bahagian
akhir kertas soalan ini. Jawab Bahagian B dan Bahagian C dengan terperinci. Anda
boleh menggunakan persamaan, gambar rajah, jadual, graf dan cara lain yang sesuai
untuk menjelaskan jawapan anda
5. If you wish to change your answer, neatly cross out the answer that you have done. Then
write down the new answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
6. The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan
7. Marks allocated for each question or part question are shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam
kurungan
SULIT 3 4541/2
http://spmchem.blogspot.com/
Section A
[60 marks]
Answer all questions
Jawab semua soalan
1 Table 1 shows the proton number and nucleon number for atoms P, Q and R.
Jadual 1 menunjukkan nombor proton dan nombor nukleon bagi atom P, Q dan R.
...............................................................................……………................…
[1 mark]
.......................................................................................................................
[1 mark]
.................................................................................................................................
.................................................................................................……………………
[2 marks]
.......................................................................................................................
[1 mark]
SULIT 4 4541/2
http://spmchem.blogspot.com/
[2 marks]
.......................................................................................................................
[1 mark]
.......................................................................................................................
[1 mark]
.......................................................................................................................
[1 mark]
SULIT 5 4541/2
http://spmchem.blogspot.com/
Diagram 2
……………………………………………………………………………………..
[1 mark]
……………………………………………………………………………………..
[1 mark]
(d) Write the half equation for the reaction that takes place at the anode.
Tuliskan setengah persamaan untuk tindak balas yang berlaku di anod.
……………………………………………………………………………………..
[1 mark]
(e) State the factor that affects the selective discharge of ions at the cathode of the
cell.
Nyatakan faktor yang mempengaruhi discas secara pilihan ion di katod sel itu.
……………………………………………………………………………………..
[1 mark]
SULIT 6 4541/2
http://spmchem.blogspot.com/
(f) What happens to the colour intensity of the solution in the cell?
Explain your answer.
Apakah yang berlaku kepada keamatan warna larutan dalam sel itu?
Terangkan jawapan anda.
……………………………………………………………………………………..
……………………………………………………………………………………..
……………………………………………………………………………………..
[2 marks]
………………………………………………………………………………
[1 mark]
(ii) A student wants to electroplate an iron spoon with silver. Draw the
apparatus set-up that will be used by the student.
Seorang pelajar ingin menyadurkan sudu besi dengan argentum.
Lukiskan susunan radas yang akan digunakan oleh pelajar tersebut.
[2 marks]
SULIT 7 4541/2
http://spmchem.blogspot.com/
Alloy Component
90% copper
Bronze
5% element X
96% tin
Pewter 3% copper
1% antimony
Table 3
...……………………………………………………….……………………..........
[1 mark]
…………………………………………………………….………………………
[1 mark]
[1 mark]
(ii) Bronze
Gangsa
[2 marks]
SULIT 8 4541/2
http://spmchem.blogspot.com/
………………………………………………………………..……………...........
………………………………………………………………..……………...........
………………………………………………………………..……………...........
………………………………………………………………..……………...........
[3 marks]
..………………………………………………………..…………….....................
[2 marks]
(a) Based on Table 4, draw a graph of volume of carbon dioxide gas against time.
Berdasarkan Jadual 4, lukis graf isipadu gas karbon dioksida melawan masa.
[4 marks]
SULIT 9 4541/2
http://spmchem.blogspot.com/
SULIT 10 4541/2
http://spmchem.blogspot.com/
(c) If the experiment is repeated by using 50.0 cm3 of 0.1 mol dm-3 hydrochloric
acid, sketch the expected curve in graph (b) .
Jika eksperimen diulangi menggunakan 50.0 cm3 asid hidroklorik 0.1 mol dm-3,
lakarkan lengkung yang dijangkakan dalam graf (b).
[2 marks]
(d) The factor that affects the rate of reaction in this experiment is concentration.
State two other factors that can affect the rate of reaction in this experiment.
Faktor yang mempengaruhi kadar tindak balas dalam eksperimen ini ialah
kepekatan. Nyatakan dua lagi faktor yang dapat mempengaruhi kadar tindak
balas eksperimen ini.
………………………………………………………………………………….
………………………………………………………………………………….
[2 marks]
5 Figure 5 shows the set up of the apparatus for an experiment to investigate electron
transfer at a distance.
Rajah 5 menunjukkan susunan radas bagi satu eksperimen untuk mengkaji
pemindahan elektron pada satu jarak.
Electrode P Electrode Q
Sulphuric acid
Figure 5
SULIT 11 4541/2
http://spmchem.blogspot.com/
……………………………………………………………………………………
[1 mark]
(c) State the observations for iron(II) sulphate solution and bromine water.
Nyatakan pemerhatian untuk larutan ferum(II) sulfat dan air bromin.
Solution Observation
Larutan Pemerhatian
Iron(II) sulphate
Bromine water
[2 marks]
(d) Write the half equation for the reactions that occur at electrode P and Q.
Tuliskan setengah persamaan bagi tindak balas yang berlaku pada elektrod P
dan Q
(f) State the change of oxidation number for iron in iron(II) sulphate solution.
Nyatakan perubahan nombor pengoksidaan bagi ferum dalam larutan
ferum(II) sulfat.
……………………………………………………………………………………
[1 mark]
(g) Name one chemical substance that can be used to replace bromine water.
Namakan satu bahan kimia yang boleh digunakan untuk menggantikan air
bromin.
……………………………………………………………………………………
[1 mark]
SULIT 12 4541/2
http://spmchem.blogspot.com/
6 Structure A and B represent molecules of two common cleaning agents, soap and
detergent.
Struktur A dan B mewakili molekul bagi dua bahan pencuci, sabun dan detergen.
Structure A
Structure B
Structure A :………………………………………………………………………
Structure B:………………………………………………………………………
[2 marks]
(b) Soap is prepared by heating a mixture of a strong alkali solution and palm oil.
Sabun disediakan dengan memanaskan satu campuran larutan alkali kuat dan
minyak kelapa sawit.
…………………………………………………………………………………..
[1 mark]
…………………………………………………………………………………..
[1 mark]
(iii) Name the homologous series to which palm oil belongs to.
Namakan siri homolog bagi kelapa sawit.
…………………………………………………………………………………..
[1 mark]
SULIT 13 4541/2
http://spmchem.blogspot.com/
………………..………………………………………………………….………...
……………………………………………………………………………………..
[2 marks]
SULIT 14 4541/2
http://spmchem.blogspot.com/
Section B
[ 20 marks ]
Answer any one question.
Jawab mana-mana satu soalan.
24
12 X
Figure 7
(a) Explain how to determine the position of element X in the Periodic Table of
Elements.
Terangkan bagaimana menentukan kedudukan unsur X dalam Jadual Berkala
Unsur.
[5 marks]
(c) Describe an experiment to compare the reactivity of lithium and sodium when
reacted with water.
Your description should also include the observations, the name of products
and chemical equations for the reactions.
Huraikan satu eksperimen untuk membandingkan kereaktifan litium dan
natrium apabila bertindak balas dengan air.
Huraian anda perlu juga mengandungi pemerhatian, nama hasil tindak balas
dan persamaan kimia bagi tindak balas yang berlaku.
[10 marks]
SULIT 15 4541/2
http://spmchem.blogspot.com/
Carbon : 85.7%
Hydrogen : 14.3 %
Relative molecular mass : 42
Relative atomic mass : C=12 ; H=1
Diagram 8
o name P.
namakan P.
[10 marks]
(b) Hydrocarbon P can be converted into hydrocarbon Q by hydrogenation reaction.
Hidrokarbon P boleh ditukarkan kepada hidrokarbon Q melalui tindak balas
penghidrogenan.
(i) Write a chemical reaction for this reaction.
Tuliskan persamaan kimia bagi tindak balas ini.
[1 mark]
[3 marks]
SULIT 16 4541/2
http://spmchem.blogspot.com/
9 Figure 9 shows the symbols which represent three elements W, X and Y.
Rajah 9 menunjukkan simbol yang mewakili tiga unsur W, X dan Y.
12 7 35
6W 3X 17
Y
Figure 9
(a) Elements W and Y react to form a covalent compound, while elements X and Y
react to form an ionic compound.
Unsur W dan unsur Y bertindak balas untuk membentuk sebatian kovalen,
manakala unsur X dan unsur Y bertindak balas untuk membentuk sebatian
ionik.
(b)
`Ionic compound has higher melting point than covalent compound`
` Sebatian ion mempunyai takat lebur yang lebih tinggi daripada
sebatian kovalen`
SULIT 17 4541/2
http://spmchem.blogspot.com/
(a) Write three interpretations or statements that can be obtained from the above
equation.
Tuliskan tiga interpretasi atau kenyataan yang boleh dibuat dari persamaan di
atas.
[3 marks]
(b) Calculate the mass of butanol that must be burnt to raise the temperature of
400 cm3 of water by 25°C.
Kira jisim butanol yang perlu dibakar untuk menaikkan suhu 400 cm3 air
sebanyak 25°C.
[3 marks]
SULIT 18 4541/2
http://spmchem.blogspot.com/
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
SULIT 19 4541/2
http://spmchem.blogspot.com/
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
SULIT 20 4541/2
http://spmchem.blogspot.com/
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
CHEMISTRY
Paper 3
One hour and thirty minutes
SULIT 2 4541/32
http://spmchem.blogspot.com/
1 A group of students carried out an experiment to investigate the effect of type of electrodes
when aqueous copper(II) chloride solution is electrolysed.
Sekumpulan pelajar menjalankan eksperimen untuk mengkaji kesan jenis elektrod apabila
larutan akueus kuprum(II) klorida dielektrolisis.
Diagram 1.1 shows the set-up of apparatus used for the electrolysis of copper(II) chloride
solution using carbon electrodes.
Rajah 1.1 menunjukkan susunan radas bagi elektrolisis larutan kuprum(II) klorida
menggunakan elektrod-elektrod karbon.
A A
Carbon electrodes
Diagram 1.1
SULIT 3 4541/33
http://spmchem.blogspot.com/
Diagram 1.2 shows the set-up of apparatus for the electrolysis of copper(II) chloride
solution using copper electrodes.
Rajah 1.2 menunjukkan susunan radas bagi elektrolisis larutan kuprum(II) klorida
menggunakan elektrod-elektrod kuprum.
Copper electrodes
Diagram 1.2
(a) Write the observation and inference obtained at the carbon anode and both the
copper electrodes during the electrolysis.
Tuliskan pemerhatian dan inferens yang diperolehi pada anod karbon dan kedua-
dua elektrod kuprum semasa elektrolisis itu.
Copper anode
Anod kuprum
Copper cathode
Katod kuprum
[6 marks]
SULIT 4 4541/34
http://spmchem.blogspot.com/
…………………………………………………………………………..………………
…………………………………….…………………………………………………….
…………………………………………………………………………………………..
[3 marks]
(c) State the hypothesis for the experiment.
Nyatakan hipotesis bagi eksperimen ini.
…………………………………………………………………………………………
…………………………………………………………………………………………
[3 marks]
(d) Based on the experiment in Diagram 1.1, state the colour change of the copper(II)
chloride solution after 45 minutes.
Berdasarkan eksperimen dalam Rajah 1.1,nyatakan perubahan warna larutan
kuprum(II) klorida selepas 45 minit.
…………………………………………………………………………………………
…………………………………………………………………………………………
[3 marks]
(e) Classify all the ions present in copper(II) chloride solution into cations and anions.
Kelaskan semua ion yang hadir dalam larutan kuprum(II) klorida kepada kation dan
anion.
[3 marks]
SULIT 5 4541/35
http://spmchem.blogspot.com/
2 A student carried out an experiment to determine the end-point for the titration of 25.0 cm3 of
1.0 mol dm-3 sodium hydroxide solution with 1.0 mol dm-3 hydrochloric acid. Phenolphthalein is
used as the acid-base indicator. Hydrochloric acid is added until the end-point of titration is
reached.
Table 1 shows the three burette readings for the titrations that have been conducted.
Seorang pelajar menjalankan satu eksperimen untuk menentukan takat akhir bagi pentitratan
antara 25 cm3 1.0 mol dm-3 larutan natrium hidroksida dengan 1.0 mol dm-3 asid hidroklorik.
Fenolftalein digunakan sebagai penunjuk asid – bes. Asid hidroklorik ditambah sehingga takat
akhir pentitratan tercapai.
Jadual 1 menunjukkan tiga bacaan buret bagi pentitratan yang telah dijalankan.
0 13 25
Initial burette
reading 1 14 26
Bacaan awal
burette
2 15 27
12 25 38
Final burette 13 26 39
reading
Bacaan akhir
burette
14 27 40
Table 1
SULIT 6 4541/36
http://spmchem.blogspot.com/
(a) Record the burette readings for the three titrations in the spaces provided in Table 1.
Rekodkan bacaan buret untuk ketiga-tiga pentitratan di ruang yang disediakan dalam
Jadual 1
[3 marks]
(b) Construct a table and record the initial burette reading, final burette reading and the volume
of acid used for each titration.
Bina satu jadual dan rekodkan bacaan awal buret, bacaan akhir buret dan isipadu asid yang
digunakan untuk setiap pentitratan.
[3 marks]
(c) Calculate the average volume of hydrochloric acid used in the experiment.
Hitungkan isipadu purata asid hidroklorik yang digunakan dalam eksperimen tersebut.
[3 marks]
(d) If the experiment is repeated by replacing 1.0 mol dm-3 of hydrochloric acid with
1.0 mol dm-3 of sulphuric acid, predict the volume of sulphuric acid needed to reach the end-
point of titration.
Jika eksperimen itu diulang dengan menggantikan 1.0 mol dm-3 asid hidroklorik dengan
1.0 mol dm-3 asid sulfurik, ramalkan isipadu asid sulfurik yang diperlukan untuk mencapai
takat akhir pentitratan.
………………………………………...………………………………………………………..
[3 marks]
.....................................................................................................................................................
.....................................................................................................................................................
[3 marks]
SULIT 7 4541/37
http://spmchem.blogspot.com/
2H 2 O 2 2H 2 O + O 2
[17 marks]
1
SULIT http://spmchem.blogspot.com/ 4541
4541
CHEMISTRY
Sept. 2009
MARKING SCHEME
CHEMISTRY PAPER 1,2 & 3
PAPER MARKS
1 50
2 100
3 50
TOTAL 200
j2kk
2
http://spmchem.blogspot.com/
1 A 26 D
2 B 27 B
3 D 28 C
4 A 29 B
5 B 30 C
6 A 31 A
7 D 32 B
8 B 33 B
9 D 34 C
10 C 35 D
11 D 36 C
12 C 37 D
13 A 38 C
14 C 39 D
15 D 40 A
16 A 41 C
17 B 42 A
18 D 43 B
19 B 44 D
20 A 45 C
21 D 46 A
22 A 47 A
23 B 48 C
24 B 49 D
25 A 50 B
j2kk
3
http://spmchem.blogspot.com/
CHEMISTRY PAPER 2
Number of shells(3) 1
R
Number of electrons 1
(iii) 7 1
(iv) R- 1
(v) Atom R accepts one electron 1
Total 10
4
http://spmchem.blogspot.com/
(ii)
Iron spoon
Silver plate
Silver nitrate
solution
3 (a) Tin 1
(b) Atom 1
(c) (i) 1
(ii)
Correct drawing 1
Correct label 1
5
http://spmchem.blogspot.com/
Total 10
4 (a) Labelling of axis is correct 1
Suitable scale 1
Transferring of point is correct 1
Graph is smooth and start from zero 1
(b) 36 1
120
= 0.3 cm3s-1 1
(c)
Volume of gas/cm3
I
11
Time/s
(d) Temperature 1
Total surface area 1
Total 10
(ii)Br 2 + 2e 2Br- 1
(e) (i) Bromine water 1
j2kk
6
http://spmchem.blogspot.com/
(f) +2 to +3// +2 +3 1
(g) Chlorine water // Acidified potassium manganate(VII) 1
Solution//Acidified potassium dichromate(VI) solution
Total 10
6 (a) A: detergent 1
B: soap 1
(b) (i) saponification 1
(ii) sodium hydroxide / potassium hydroxide 1
(iii) ester 1
(c) Detergent does not form scum (insoluble salt) with the Ca2+ or Mg2+ 1
ions present in the hard water.
Soap forms scum in hard water. 1
(d) analgesic 1
antibiotic 1
psychotherapeutic 1
Total 10
j2kk
7
http://spmchem.blogspot.com/
Section B
(c) Procedure
1-A small piece of lithium is cut using a knife 1
2-The oil on the surface of lithium is removed using filter paper 1
3-Lithium is then placed slowly on the surface of water in a
beaker/basin 1
4-The experiment is repeated using sodium 1
Observation
Lithium moves slowly on the surface of water 1
Name of products: lithium hydroxide and hydrogen 1
Sodium moves rapidly/faster/vigorously on the surface of water 1
Name of products: sodium hydroxide and hydrogen 1
Equations
2Li + 2H 2 O 2LiOH + H 2 correct formulae 1
balanced equation 1
or
2Na + 2H 2 O 2NaOH + H 2 10
Total 20
j2kk
8
http://spmchem.blogspot.com/
8 (a)
Elements Carbon Hydrogen
Mass/g 85.7 100- 85.7 = 14.3 1
85.7 14.3 1
No of mole 12 1
= 7.14 =14.3
7.14 = 1 14.3 = 2 1
Mole ratio
7.14 7.14
Empirical 1
CH 2
formula
structural formula:
H H H
I I I
H–C=C–C–H 1
I
H
propene 1
C n H 2n , n=2,3….. 1
10
(b) (i) C 3 H 6 + H 2 C 3 H 8 1
1
(ii)
P // C 3 H 6 Q // C 3 H 8
9
http://spmchem.blogspot.com/
Y
Y
W
10
http://spmchem.blogspot.com/
X Y
11
http://spmchem.blogspot.com/
12
http://spmchem.blogspot.com/
CHEMISTRY PAPER 3
Question No.
Rubric Score
1 (a) Able to write all observations and corresponding inferences 6
correctly.
Sample Answer:
Question No.
Rubric Score
1 (b) Able to state the three variables correctly. 3
Sample Answer:
Manipulated variable: Types of electrodes.
Responding variable: Product at the anodes
Constant variable: Electrolyte// Copper(II) chloride solution
j2kk
13
http://spmchem.blogspot.com/
Question No.
Rubric Score
1(c) Able to write the hypothesis correctly with direction 3
Sample answer:
Carbon anode produces oxygen gas while copper anode
dissolves/produces copper(II) ion.
Sample answer:
Carbon anode produces different product compared to
copper anode.
Question No.
Rubric Score
1 (d) Able to state the colour change in copper(II) chloride 3
solution accurately after 45 minutes.
Sample answer:
The blue colour of copper(II) chloride solution becomes light
blue/ paler // The intensity of blue copper(II) chloride
solution decreases. [Reject colourless]
Sample answer:
The colour of copper(II) chloride solution becomes paler //
The intensity of copper(II) chloride solution decreases.
Sample answer:
j2kk
14
http://spmchem.blogspot.com/
Light blue
Question No.
Rubric Score
1 (e) Able to classify all the ions present in the copper(II) chloride 3
solution accurately.
Sample answer:
Positive ion: Copper(II) ion / Cu2+ and hydrogen ion / H+
Negative ion: hydroxide ion / OH- and chloride ion / Cl-
Question No.
Rubric Score
2(a) Able to record all the volumes with units accurately. 3
15
http://spmchem.blogspot.com/
Question No.
Rubric Score
2(b) Able to construct a table correctly containing three labelled 3
columns with correct units and record all the burette
readings and volume of acids used accurately.
Suggested answer:
Titration No. I II II
Initial burette 0.80 13.40 25.90
reading/cm3
Final burette 13.40 25.90 38.40
reading/cm3
Volume of acid 12.60 12.50 12.50
used/cm3
[Able to construct a table correctly containing three labelled 2
columns without units/one decimal place and record all the
volumes accurately]
[Able to construct a table with at least three labels and four 1
correct readings]
No response or wrong response 0
Question No.
Rubric Score
2(c) Able to calculate the average volume of acid used correctly 3
and with unit
Suggested answer:
Volume of acid used = 12.6 + 12.5 + 12.5
3
= 12.5 cm3
Able to calculate the average volume correctly but without 2
unit.
Able to show the calculation of average volume of acid used 1
but incorrect answer
No response or wrong response 0
Question No.
Rubric Score
2(d) [Able to state the volume correctly] 3
6.25 cm3
Able to state the volume but to one decimal place 2
6.3 cm3// [6.0 – 7.0] cm3
Able to state the volume but inaccurately 1
12.5 cm3//25.0 cm3
No response or wrong response 0
j2kk
16
http://spmchem.blogspot.com/
Question No.
Rubric Score
2(e) Able to state operational definition correctly. 3
Sample answer:
A point at which pink colour of the phenolphthalein in the solution
turns colourless when acid is added.
17
http://spmchem.blogspot.com/
Sample answer: 3
How does a catalyst affect the rate of reaction?
** [If aim is given, award score 2].
[Able to write the problem statement of the experiment correctly.]
Sample answer: 2
Does a catalyst affect the rate of reaction?
Sample answer: 1
Catalyst affects the rate of reaction . //
Manganese(IV) oxide affects the rate of decomposition of
hydrogen peroxide.
[No response given or wrong response]
0
Sample answer:
Manipulated variable : Presence of manganese(IV) oxide
18
http://spmchem.blogspot.com/
Sample answer: 2
Catalyst / Manganese (IV) oxide changes the decomposition of
hydrogen peroxide.
Sample answer: 1
Catalyst/ manganese(IV) oxide affects the rate of reaction.
Sample answer:
Substances: 20-volume hydrogen peroxide solution,
3
manganese(IV) oxide powder.
Apparatus: test tube, wooden splinter, test tube rack, spatula,
10cm3 measuring cylinder.
19
http://spmchem.blogspot.com/
Sample answer: 2
Test tube Observation
A
B
[Able to construct a table with at least the title]
20
http://spmchem.blogspot.com/
Sample answer:
Substances: [10- 20-volume] hydrogen peroxide solution,
manganese(IV) oxide powder, water. 3
Apparatus: 50cm3 measuring cylinder, 100 cm3 conical flask,
basin, delivery tube, burette, retort stand with clamp,
stop watch.
21
http://spmchem.blogspot.com/
Sample answer:
2
Time/s 0 30 60 90 120 150 180 210 240
Burette
reading/cm3
Volume of
gas/cm3
[Able to construct a table with at least the title]
Time
Burette reading 1
Volume of gas
0
[No response given or wrong response]