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DOE Handbook Primer in Spon Heat and Pyrophoicity

DOE Handbook Primer in Spon Heat and Pyrophoicity

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METRICDOE-HDBK-1081-94December 1994
DOE HANDBOOK
PRIMER ON SPONTANEOUS HEATING ANDPYROPHORICITY
U.S. Department of EnergyFSC-6910Washington, D.C. 20585
DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited.
 
This document has been reproduced directly from the best available copy.Available to DOE and DOE contractors from the Office of Scientific andTechnical Information. P.O. Box 62, Oak Ridge, TN 37831; (615) 576-8401.Available to the public from the U.S. Department of Commerce, TechnologyAdministration, National Technical Information Service, Springfield, VA 22161.(703) 487-4650Order No. DE95003576
 
 DOE-HDBK-1081-94SPONTANEOUS HEATING AND PYROPHORICITY 
Rev. 0Pyrophoricity
The
Primer on Spontaneous Heating and Pyrophoricity
is approved for use by allDOE Components. It was developed to help DOE facility contractors prevent fires causedby spontaneous combustion. Spontaneously combustible materials include those that ignitebecause of a slow buildup of heat (spontaneous heating) and those that ignite instantly in air(pyrophoricity). The scientific principles of combustion and how they affect materialsknown to be spontaneously combustible are explained. The fire hazards of specificspontaneously heating and pyrophoric materials are discussed as well as techniques toprevent their ignition. Suitable fire extinguishing agents are included for most materials aswell as safety precautions for storage and handling.The Department of Energy (DOE) Primers are a set of fundamental handbooks onsafety-related topics of interest in the DOE Complex. The Primers are written as aneducational aid for operations and maintenance personnel. The Primers attempt to supplyinformation in an easily understandable form which will help them perform their duties in asafe and reliable manner. Persons trained in other technical areas may also find the Primersuseful as a guide or as a reference source for further investigation.The DOE Primer series draws heavily upon the subject-specific Primers and trainingmaterials previously developed by DOE sites (Savannah River, Rocky Flats, and Mound)and is intended for distribution to all DOE contractors. Information is also drawn from theapplicable volumes of the
 DOE Fundamentals Handbook 
series developed by the DOEOffice of Nuclear Safety Policy and Standards. References to other material sources areindicated in the text where applicable and a bibliography is included.Beneficial comments in the form of recommendations and any pertinent data that maybe of use in improving this document should be addressed toJohn A. YoderEH-63/GTNU.S. Department of EnergyWashington, D.C. 20585Phone (301) 903-5650Facsimile (301) 903-6172by using the U.S. Department of Energy Standardization Document Improvement ProposalForm (DOE F 1300.x) appearing at the end of this document or by letter.
Key words:
Combustion,
 
Fire, Spontaneous, Ignition, Heating, Pyrophoricity,Temperature, Hypergolic, Extinguishing Agent, Hydrocarbons, Organic, Heating, SpecificArea, Liquids, Gases, Metals, Oxidizer

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