I use Ez Internet Timer software that restricts internet access. It allows to block Internet browsers, e-mails, Ftp file downloads, messengers and keep them blocked for as you wish. I also use it to restrict web surfing at work (setup browsing time during the lunch only). It has even the ability to set browsing and messenging timers separately from emails.

block all porn sites on google.com

Check out parental control software http://www.parentalfiltercontrol.com A couple of products are more on the restrictive side, i.e. allow only selected sites to display