You are seeing our new document Reader view. Click here to revert. Feel free to leave us feedback on this feature .
×
  • Embed Doc
  • Readcast
  • Collections
  • CommentGo Back
Download
 
Protection from Light Damage
Beth Lindblom Patkus
 
Preservation Consultant
 
Walpole, MA
 
Introduction
Light is a common cause of damage to library and archival collections. Paper,bindings, and media (inks, photographic emulsions, dyes, and pigments, and manyother materials used to create words and images) are particularly sensitive to light.Light damage manifests itself in many ways. Light can cause paper to bleach, yellow,or darken, and it can weaken and embrittle the cellulose fibers that make up paper. Itcan cause media and dyes used in documents, photographs, and art works to fade orchange color. Most of us recognize fading as a form of light damage, but this is only asuperficial indication of deterioration that extends to the physical and chemicalstructure of collections. Light provides energy to fuel the chemical reactions thatproduce deterioration. While most people know that ultraviolet (UV) light isdestructive, it is important to remember that all light causes damage. Light damage iscumulative and irreversible.
The Nature of Light
Light is a form of electromagnetic energy called radiation. The radiation that we knowfrom medicine and nuclear science is energy at wavelengths far shorter than the lightspectrum; radio waves are much longer wavelengths. Visible light, the form of radiation that we can see, falls near the center of the electromagnetic spectrum.The visible spectrum runs from about 400 nanometers (nm, the measurement appliedto radiation) to about 700 nm. Ultraviolet wavelengths lie just below the short end of the visible spectrum (below 400 nm). The wavelengths of infrared light lie just abovethe long end but our eyes cannot see them. This type of light also damagescollections.
How Does Light Do Its Damage?
Light energy is absorbed bymolecules within an object. Thisabsorption of light energy canstart many possible sequencesof chemical reactions, all of which damage paper. Thegeneral term for this process isphotochemical deterioration.Each molecule in an objectrequires a minimum amount of energy to begin a chemicalreaction with other molecules.This is called its activationenergy. Different types of molecules have differentactivation energies.If the light energy from naturalor artificial light equals orexceeds the activation energy of a particular molecule, themolecule is “excited,” or madeavailable for chemical reactions.Once this happens, the moleculemay behave in a variety of ways. The excess energy mayshow up as heat or light; theenergy may break bonds withinthe molecule (this will createsmaller molecules and weakenthe paper); the energy may cause a rearrangement of atoms within the molecule; orthe energy may be transferred to another molecule. One of the primaryphotochemical reactions is oxidation, in which the “excited” molecule transfers itsenergy to an oxygen molecule, which then reacts with other molecules to initiatedamaging chemical reactions. While the sequence of events can be extremelycomplex, the end result is always deterioration.Shorter wavelengths of light (UV light) have a greater frequency (that is, they occurcloser together) as well as more energy than longer wavelengths. This means thatthey bombard an object with more energy in a shorter time, and that their energy islikely to meet or exceed the required activation energy for many different types of 
    of 00

    Leave a Comment

    You must be to leave a comment.
    Submit
    Characters: ...
    You must be to leave a comment.
    Submit
    Characters: ...