Professional Documents
Culture Documents
Trong :
: t phn hon nguyn (hay mc hon nguyn)
: t trng qung
(2)
Trong :
- mc hon nguyn
t thi gian hon nguyn
xc nh hng s k, t cc bng s liu (, t) lp th -ln(1-) theo thi gian, phng
trnh 1. Lp th bc nht i qua gc (0,0) ta thu c k bng h s gc ca th.
Xc nh nng lng hot ha:
k =
(3)
ta vit li (3) thnh lnk = lnA-
C
)
Time (min)
Mc Hon nguyn Biu din th ln(1-f)~ Kt
0 20 40 60 80 100 120
0.0
0.5
1.0
1.5
2.0
850C
950C
1050C
-
l
n
(
1
-
f
)
Time (min)
Nhit , C K
850 5.84*10
-3
950 14.47*10
-3
1050 17.94*10
-3
7.0 7.5 8.0 8.5 9.0
-5.5
-5.0
-4.5
-4.0
-3.5
l
n
K
1/T*10^4
=
(Arrhenius equation)
K hng s tc phn ng
E Nng lng hot ha
A - Hng s Arrhenius (Hay Frequency Factor)
R Hng s kh 8.314472 J K
-1
mol
-1
T nhit (K)
Hng s tc phn ng
Nng lng hot ha
Mc Hon nguyn Biu din th ln(1-f)~ Kt
0 20 40 60 80 100 120
0
20
40
60
80
100
850C
950C
1050C
R
e
d
u
c
t
i
o
n
d
e
g
r
e
e
(
%
)
Time (min)
0 20 40 60 80 100 120
0.0
0.5
1.0
1.5
2.0
2.5
-
l
n
(
1
-
f
)
Time (mins)
850C
950C
1050C
7.0 7.5 8.0 8.5 9.0
-4.8
-4.5
-4.2
-3.9
l
n
K
10^4/T
Nhit , C K
850 7.89*10
-3
950 15.15*10
-3
1050 18.97*10
-3
=
(Arrhenius equation)
K hng s tc phn ng
E Nng lng hot ha
A - Hng s Arrhenius (Hay Frequency Factor)
R Hng s kh 8.314472 J K
-1
mol
-1
T nhit (K)
Hng s tc phn ng
Nng lng hot ha
Mc Hon nguyn Biu din th ln(1-f)~ Kt
0 20 40 60 80 100 120
0
20
40
60
80
100
900C
950C
1000C
1050C
R
e
d
u
c
t
i
o
n
d
e
g
r
e
e
(
%
)
Time (Min)
0 20 40 60 80 100 120
0.0
0.5
1.0
1.5
2.0
2.5
900C
950C
1000C
1050C
-
l
n
(
1
-
f
)
Time (Min)
7.0 7.5 8.0 8.5 9.0
-4.5
-4.2
-3.9
-3.6
L
n
K
10^4/T
Nhit , C K
900 12.57*10
-3
950 16.32*10
-3
1000 19.86*10
-3
1050 22.03*10
-3
=
(Arrhenius equation)
K hng s tc phn ng
E Nng lng hot ha
A - Hng s Arrhenius (Hay Frequency Factor)
R Hng s kh 8.314472 J K
-1
mol
-1
T nhit (K)
Hng s tc phn ng
Nng lng hot ha
Nhit
, C
Hng s tc phn ng, k
(10
-3
)
5mm 10mm 15mm
850 7.89 5.84
900 12.57
950 16.32 15.15 14.47
1000 19.86
1050 22.03 18.97 17.94
E = 70.34,
54.79
48.8 kJ
ng hc qu trnh hon nguyn ph
thuc kch thc ng knh qung vin
Nhit : 1050C
Qung st ban u Qung vin, nung 1200C, 2h
Hu ht -xt st dng Fe
2
O
3
Qung vin 15mm, hon nguyn
1050C, 15 pht
Qung vin 15mm, hon nguyn
1050C, 90 pht
Hu ht pha kim loi ch cn l Fe
Qung vin, nung 1200C, 2h Hon nguyn 15 pht Hon nguyn 90 pht
Qung vin 15 mm
Nhit hon nguyn: 1050C
B mn K thut gang thp 45
tin hnh th nghim hon nguyn vi qung vin 5, 10 v
15mm trn nn than. Cc kt qu th nghim cho thy:
Tng nhit lm tng mc hon nguyn.
Tng thi gian gi nhit lm tng mc hon nguyn. Mc hon
nguyn tng nhanh trong 45 pht u v tng rt chm nu ko di thi
gian gi nhit.
Phn tch thnh phn pha cho thy:
15 pht hon nguyn ban u, phn ln -xt st l Fe
3
O
4
, FeO, Fe v
cc -xt khc.
Sau 90 pht hon nguyn, trong sn phm ch cn li pha kim loi Fe v
-xt ca Si.
Cc thng s ng hc ca qu trnh hon nguyn, tun theo quy lut ng hc phn ng
bc nht, nhn c nh sau
Gi tr nng lng hot ha tng ng i vi cc qung vin kch thc 15, 10 v 5 mm l
E = 70.34, 54.79 v 48.8 kJ, cho bit qu trnh phn ng thuc min ng hc
Mc kim loi ha ca qung vin 15mm sau khi hon nguyn ti 1050C trong 15 v 90
pht tng ng l: 44.34 v 96.39%.
Nhit , C
Hng s tc phn ng, k
Mu 5mm Mu 10mm Mu 15mm
850
7.89*10
-3
5.84*10
-3
900 12.57*10
-3
950 16.32*10
-3
15.15*10
-3
14.47*10
-3
1000 19.86*10
-3
1050 22.03*10
-3
18.97*10
-3
17.94*10
-3