Thnh ph : H Ch Minh - Trng : THPT chuyn L Hng Phong

Mn : Ha - Khi : 11
! "# $P $% CH& T&'T ( M) % H*+ ( KH,& 11
Cu I :
-./ 01 /h2y ph3n c2a 40/4 54/y6 a74/a/ 8 9:
;
C /rong c<c 5i /rng 0au:
Trng h=p 1: Trong 5i /rng >i?5@ >hi /Ang nng BC >i?5 6n gDp Bi /hE /c BC phFn
Gng /Ang 6n hai 6HnI %hJn 7./ ny cKng B=c /hDy >hi /Ang nng BC c2a 40/4 6n hai 6HnI
Trng h=p 9: PhFn Gng /huL ph3n B=c /h1c hiMn /rong 5i /rng BM5
Trng h=p N: %gi /a /iOn hnh phFn Gng /huL ph3n /rong 5i /rng a7i/ HC6 ;@;:M
PI Cng hQc c2a phFn Gng B=c nghin cGu RSng c<ch chuTn BC 9:56 hUn h=p phFn Gng
RSng Pung PVch %aWH 8 /Xng /hi BiY5 / Z[i >O/ \uF nh 0au :
/ [ph]/] ; 91 ^: 11_

"
%aWH
`c5
3
] 9a@a 9:@b 9_@N N1@^ a^@9
&I1I Hcy ZiO/ phdng /rEnh BCng hQc c2a phFn GngI Cho RiO/ RJc c2a phFn Gng /rong /Xng
/rng h=pI
&I9I Trong TH1: %Ou cho ;@;1 5o6 7]/ Z ;@;1 5o6 40/4 Zo 16i/ n[c e745 nh /hY /ch
/hay Bfi >hng B<ng >YgI hau 9;; ph]/ /hE Ni: 6=ng 40/4 cha RV ph3n huLI Tnh hSng
0 /c BC phFn Gng >
1

&INI Trong TH N: Hcy /nh hSng 0 /c BC phFn Gng >
N
Z /hi gian BY 40/4 ph3n huL hO/
:;jI TX B hcy 0o 0<nh gi< /rV >
1
Z >
N

p n
&I1I %hJn 7./:
TH1: Z k >
1
`40/4l
a
I`WH
-
l
R
m >hi /Ang nng BC c2a 40/4 honc Raod 6n gDp
hai 6Hn /hE Z cKng /Ang 6n gDp Bi m a k R k 1 m Z k >
1
`40/4l`WH
-
l
"Jy /rong TH1 RJc c2a phFn Gng 6 RJc 9
1 im
TH9: Ta c Z k >`40/4l`WH
-
l I %hng /rong 5i /rng BM5 nn `WH
-
l k
con0/ m Z k >
9
`40/4l Z[i >
9
k >`WH
-
l
THN: Z k >`40/4l`a7i/l po a7i/ 6Dy P nn >`a7i/l k con0/ k>
N
m Z k >
N
`40/4l
"Jy /rong TH9@ N RJc phFn Gng 6 RJc 1
1 im
&I9I "E nng 40/4 Z a7i/ RSng nhau Z `+
;
l k ;@;1M nn /a c
kt
A x A
=
l `
1
l `
1
; ;
Z[i `+
;
l 6 nng BC c2a 40/4q `+
;
l ( 7 6 nng BC c2a
40/4 /ri /hi BiY5 /
L=ng 40/4 cha RV /huL ph3n 6 9i:`+
;
l m
kt
A
A
=
l `
1
l `
:
9
1
;
;
m >k ;@^: 5o6
-1
ILIph]/
-1
k >
1

1 im
&INI Ta c
x A
A
t
k

=
l `
l `
6g
N;N @ 9
;
;

%Ou "

8 /hi BiY5 / k

6 /hY /ch Gng Z[i 01 >O/ /h]c /huL ph3n

40/4
/rong 5i /rng a7i/@ "
;
6 /hY /ch Gng Z[i /hi BiY5 /k ; /hE hiMu "

- "
;
0s /t 6M Z[i nng BC BHu c2a 40/4I Cun hiMu "

- "
/
0s /t 6M Z[i nng BC 40/4
/ri /hi BiY5 / e "
/
6 /hY /ch Gng Z[i /hi BiY5 / gI po B:

/ `ph]/l 91 ^: 11_
"
%aWH
`c5
N
l 9:@b 9_@N N1@^
>
N
ph]/
-1
;@;;N;1v ;@;;N99a ;@;;N9aa
1
N ;;N1v1 @ ;

= phut k

"Jy >
1
gDp
N
k
>hoFng 9N^@9^ 6HnI
/
N
k
k 6n9 m / k 91_ ph]/
1 im
Cu II :
1
Thnh ph : H Ch Minh - Trng : THPT chuyn L Hng Phong
Mn : Ha - Khi : 11
Tnh pH c2a Pung PVch CH
N
CWWH ;@1MI
&&I1I PhFi /h5 Zo 1 L/ Pung PVch /rn Rao nhiu ga5 %aWH BY B=c Pung PVch c pH
kNI
&&I9I -<c BVnh BC /an c2a +gC% /rong Pung PVch BM5 c pH kNI
&&INI &on phGc +ge%H
N
g
9
w
RV ph3n huL /rong 5i /rng a7i/ /h4o phFn Gng:
+ge%H
N
g
9
w
w 9H
w
+g
w
w 9%H
a
w

Y _;j ion phGc c /rong Pung PVch +ge%H
N
g
9
w
;@1M

RV ph3n huL /hE nng BC H
w
/ri
/rrng /h<i c3n RSng 6 Rao nhiuI
xiO/ :hSng 0 a7i/ c2a CH
N
CWWH 6 K
1
k 1;
-a@^v
q HC% 6 K
9
k 1;
-_@N:
q
%H
a
w
6 K
N
k 1;
-_@9a

+gC% +g
w
w C%
-
T k 9@9I 1;
-1v
+g
w
w %H
N
+ge%H
N
g
w

1
k 1;
N@N9
+ge%H
N
g
w
w %H
N
+ge%H
N
g
9
w

9
k 1;
N@_9
p n:
&&I1I CH
N
CWWH CH
N
CWW
-
w H
w
C eMg ;@1
` l eMg ;@1 ( 7 7 7
k 1;
-a@^v
yiF 0z@ 7 {{ ;@1 nn 0uy ra 7 k 1;
-9@bb
k| pH k 9@bb
1 im
&&I9I CH
N
CWWH w %aWH k CH
N
CWW%a w H
9
W
eMg C C
CH
N
CWW%a CH
N
CWW
-
w %a
w
eMg C C
CH
N
CWWH CH
N
CWW
-
w H
w
K
a
k 1;
-a@^v
C
;
eMg ;@1- C C
` l eMg ;@1- C ( 1;
-N
C w 1;
-N
1;
-N

pH k N k| `H
w
l k 1;
-N
eMg


^v @ a
N
N N
1;
1; 1 @ ;
1; g 1; e

=

+
C
C
C k ^@;bI 1;
-a
eMg
k| n
%aWH
k ^@;bI 1;
-a
e5o6g k| 5
%aWH
k a;7 ^@;bI 1;
-a
k ;@;9b egg
1 im
&&INI
+gC% +g
w
w C%
-
T k 1;
-1:@vv
H
w
w C%
-
HC% K
9
-1
k 1;
_@N:

+gC% w H
w

+g
w
w HC% K k TK
9
-1
k 1;
-v@N1

C eMg 1;
-N

` l eMg 1;
-N
w h h h
k 1;
-v@N1

h
9
- 1;
-v@N1
h - 1;
-_@N1
k ;
h k 9@9I1;
-:
1 im
II.4.
+g
w
w %H
N
+ge%H
N
g
w

1
k 1;
N@N9
+ge%H
N
g
w
w %H
N
+ge%H
N
g
9
w

9
k 1;
N@_9
+g
w
w 9%H
N
+ge%H
N
g
9
w
k 1;
^@9a
+ge%H
N
g
9
w
+g
w
w 9%H
N

-1
k 1;
-^@9a

%H
N
w H
w
%H
a
w
7 9 K
N
-1
k 1;
_@9a
1 im
9
Thnh ph : H Ch Minh - Trng : THPT chuyn L Hng Phong
Mn : Ha - Khi : 11
+ge%H
N
g
9
w
w 9H
w
+g
w
w 9%H
a
w
K k
-1
eK
N
-1
g
9
k 1;
11@9a

Khi phGc RV ph3n huL _;j /hE :
`+ge%H
N
g
9
w
l k ;@1 ( ;@1 7 ;@_ k ;@;1 eMg
`+g
w
l k ;@;_ eMg
`%H
a
w
l k ;@;_ 7 9 k ;@1b eMg
+ge%H
N
g
9
w
w 9H
w
+g
w
w 9%H
a
w
K k 1;
11@9a

` l eMg ;@;1 y ;@;_ ;@1b
k 1;
11@9a
y k `H
w
l k 1@N I1;
-v
eMg

Cu III : 6 im
&&&I1I Hua /an b@;;g 1 hiPro7i/ >i5 6ori cha RiO/ c cng /hGc MeWHg
9
Zo 1@;;P5
N
n[c
/hE /hu B=c v@:9 g chD/ r}n >hng /an cun 6riI Th5 /iOp :1@vv Me%W
N
g
9
Zo Pung
PVch /hE /hDy >hi 6=ng pha r}n /Ang BOn ^@vNgI
Hcy 7<c BVnh /n >i5 6ori nyI yiF /hiO/ rSng /hY /ch Pung PVch >hng /hay Bfi Z c<c
chD/ /an B?u /an hon /onI
&&&I 9I Cho phFn Gng : Cuerg w CuC6
9
ePPg 9 CuC6erg
&&&I9I1I ~ 9:
;
C phFn Gng 7Fy ra /h4o chi?u no@ nOu ngi /a /rCn 5C/ Pung PVch chGa
CuhW
a
;@9Mq %aC6 ;@aM Z[i RC/ Cu 6Dy P
Cho T
CuC6
k 1;
-^
@ V E V E Cu Cu Cu Cu NN: @ ; q 1: @ ; i
;
i
;
9 9
= =
+ + +
&&&I9I9I Tnh hSng 0 c3n RSng K c2a phFn Gng /rn 8 9:
;
CI
<p <n :
&&&I 1I ChD/ r}n >hng /an cun 6ri 6 MeWHg
9
Khi 6=ng hiPro7i/ /an Zo n[c : b@;; ( v@:9 k 1@ab g

5o6
Na M
1@ab
n
9
MeWHg
+
=

%ng BC c<c ion /rong Pung PVch :
eMg
Na M
1@ab
l `
9
+
=
+
M
eMg
Na M
9@_v

Na M
1@ab 7 9
l `
+
=
+
=

OH
0,5 im
Tch 0 /an c2a MeWHg
9
/rong n[c :
9
N
9 9
MeWHg N
a 7 1@ab
T `M l`WH l
eM Nag
+
= =
+
L=ng M
9w
/h5 Zo :
eMg
19a M
:1Ivv
9
+
=
+
M
C
0,5 im
po Me%W
N
g
9
hua /an hO/ Zo PP nn 7Fy ra 01 Pi 5Gc c3n RSng :
MeWHg
9
M
9w
w 9WH
-
xan BHu
19a M
:1Ivv
+
1;
-^
iMn 6y 7 7 97
C3n RSng e7 w
19a M
:1Ivv
+
g e1;
-^
w 97g
Mn/ >h<c : 7 k
eMg
Na M
;@N^
Na M
^@vN - b
+
=
+
1 im
N
Thnh ph : H Ch Minh - Trng : THPT chuyn L Hng Phong
Mn : Ha - Khi : 11
Tri c3n RSng 5[i :
eMg
Na M
;@^a
97g 1; e l `
^ -
+
+ =

OH
eMg
19a M
:1@vv
Na M
;@N^
l `
9

+
+
+
=
+
M
0,5 im
g eM
Na M
;@^a

19a M
:1@vv
Na M
;@N^
l l`WH `M T
N
9
9
MeWHg
9

+
+
+
= =
+

19a M
:1@vv
Na M
;@N^
Na M
9N@vb
+
+
+
=
+
M k a;
"Jy >i5 6ori 6 Can7i I HiPro7i/ 6 CaeWHg
9
0,5 im
&&&I 9I Ta c : Cu
9w
w 94 k Cu @
1
G
Cu
9w
w 14 k Cu
w
@
9
G
Cu
w
w 14 k Cu @
N
G

+ + + +
+ =
=
Cu Cu Cu Cu Cu Cu E F E F E F
G G G
i
;
i
;
i
;
9 1 N
9 9
I I 1 I I 9 I I 1
+ + + +
= Cu Cu Cu Cu Cu Cu E E E i
;
i
;
i
;
9 9
9
k 9I;@NN: - ;@1: k ;@:9 "I
1 im
Ta c :
l `
l `
6g ;:_ @ ;
9
i
;
i
9
9
+
+
+ =
+ +
+ +
Cu
Cu
E E Cu Cu
Cu Cu

V a_b @ ;
a @ ; i 1;
9 @ ;
6g ;:_ @ ; 1: @ ;
^
= + =

e Z[i `Cu
w
l k T
CuC6
i
`C6
-
l g

CuwiCu
k
;
CuwiCu
w ;@;:_ 6g `Cu
w
l
k ;@:9 w ;@;:_ 6g 1;
-^
i ;@a k ;@1N"I
1 im
9i Khi c3n RSng :
K
1
k
;:_ @ ; i I
;
1;
E n
k :@N:I1;
-^
K
9
k e 1;
-^
g
-9
k 1;
1a
"Jy :
K k K
1
I K
9
k :@N:I1;
^
I
1 im
Cu IV : 2 im
Hoan chnh s o bien hoa sau:
(CH
3
)
2
CH CH
2
CH
3

Br
2
, as

!a"H, r#$u
B
Br
2
, CC%
&
C
2'"H, r#$u

( )
ap an:
(CH
3
)
2
CH CH
2
CH
3

Br
2
, as
(CH
3
)
2
CBr CH
2
CH
3
!a"H, r#$u
(CH
3
)
2
C*CH CH
3

1 im
a
Thnh ph : H Ch Minh - Trng : THPT chuyn L Hng Phong
Mn : Ha - Khi : 11
Br
2
, CC%
&
(CH
3
)
2
CBr CHBr CH
3

2'"H, r#$u

CH C"
"
CH C"
CH
2
CH
2
CH
CH
CH
3
1 im
Cu V : 4im
+,-, Cha. h#/u c (0) %a 1o2. r#$u no, nh3 ch#c, 1a$ch h4,
(un5 63ch 0 728 .ron5 n#c co nhie2. o2 o9n5 a:c %a
;3<
-;
-
o
C
+,2, 0ac 3nh co9n5 .h#c cau .a$o cu4a (0), Bie. ha=n5 so
n5hie21 %a$nh cu4a n#c %a -,>7,
+,3, ?r@nh baA 3 cach Bhac nhau eC ieu che (0) .# e.A%en,
+,&, 'hi co 1a:. cha. Duc .ac .hEch h$F .h@ cha. (0) Bh#4
n#c .a$o ra cha. (), ?ron5 1o9i .r#n5 Bie1, hai Fha9n .#4
() Be. h$F Gi nhau .a$o ra cha. (B) Bho9n5 ben, 'hi un
non5 .h@ (B) .ach n#c .a$o ra cha. ((), ?# (() cho .ac 6u$n5
Gi HC% .a$o cha. ()),
?h#$c hie2n s#$ chuAeCn hoa .re9n eC Dac 3nh co9n5
.h#c cau .a$o cu4a , B, ( ),
(un5 c che Fha4n #n5 eC 5ia4i .hEch Hua .r@nh () .a$o
.hanh (B),
()) co on5 Fha9n %a2F .heC haA Bho9n5 I Ha/A Dac 3nh
cau .ruc cac on5 Fha9n %a2F .heC cu4a ()) Ga 5o$i .e9n
(neu co),
Bai giai
+,-, Ja:. C??K cu4a 0: C
n
H
2nL2MB
("H)
B
,
L 'hoi %#$n5 0 co .ron5 -<<< 5a1 H
2
":
-<<<,72 3-<<<
3> -;
=


0
0
1 3-<<<
N B -,>7, 72(5O 1o%)
;3< .
-; <
-;
= = =

D

+

-&n L -7B * 7<
!5hie21 Fhu h$F: B * 2 Ga n * 2
C?P? cu4a 0: C
2
H
&
("H)
2
C?C? cu4a 0:

1im
"I9I L CH
2
* CH
2

66 'Nn"&, %a$nh
L CH
2
* CH
2

C%
2
, CC%
&

66 !a"H, .
o
L CH
2
* CH
2

H
2
"

1im
:
CH
2
CH
2
"H "H
CH
2
CH
2
"H "H
CH
2
CH
2
C% C%
CH
2
CH
2
"H "H
CH
2
CH
2
"
CH
2
CH
2
"H "H
"
2
5, .
o
CH
2
C
CH
3
CH CH
2
CH C"
"
CH C"
Thnh ph : H Ch Minh - Trng : THPT chuyn L Hng Phong
Mn : Ha - Khi : 11
+,3, L Q o chuAeCn hoa:
CH
3
CH"
"H
M

(0) () (B)
.
o


()) :
L C che: CH
3
CH"
"H
M

CH
3
CH"

1,5 im
()): co on5 Fha9n %a2F .heC:
on5 Fha9n Huan5 ho$c 6o co C
R

CH
2
M CH"
H C%
CH
3
S
CH
2
M CH"
C% H
CH
3
Q
0,5im
v
CH
2
CH
2
"H "H
CH
3
CH CH
2
CH"
"H
CH
3
CH CH CH"
(()
LHC%
CH
3
CH CH
2
CH"
C%
CH
3
CH CH
2
CH"
"H
CH
2
CH"
M
CH
3
CH "
CH
3
CH CH
2
CH"
"
M
" H
2
CH
3
CH CH
2
CH"
"H
H
2
Q"
&
a:c
-T<
o
C
"H
M
M H
2
"
CH
3
CH CH
2
CH"
C%
*