VIDYANCHAL

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4/1/2009 Topic: Class: XIIth Class Page No. (1)
1. In the given reaction:
C6H5CH=CHCHO  [X]
→ C6H5CH2CH2CH2OH [X] will be :
(a) NaBH4 (b) Aluminium isopropoxide (c) LiAlH4 (d) All of these
2. In the given reaction:
C6H5CH=CHCH2OH  [X] C H CH=CHCH OH [X] will be :
→ 6 5 2

(a) Aluminium isopropoxide + isopropyl alcohol (b) NaBH4 (c) H2/Ni/∆ (d) Both (a) and (b)
3. The product of the reaction:

will be:

(a) C6H5CH=CHCOOH
4. Cinnamic acid is β -phenyl-α , β -unsaturated acid. This acid can be prepared from Perkin reaction by:
(a) C6H5CHO (b) CH3COOH (c) C6H5CHO and CH3COOH (d) C6H5CHO and Ac2O
5.In the reaction sequence:

[X], [Y] and [Z] will respectively be:

6. Benzaldehyde can be converted into benzylbenzoate in one step by:

(a) (C2H5O)3Al (b) Al2O3 (c) Na2[Fe(CO)4] (d) All of these
7. Benzoin condensation is given by:
(a) C6H5CHO (b) CH3—CHO (c) C6H5—CH2—CHO (d) All of these
8. Benzoin is a:
(a) Alcohol (b) Ketone (c) α -Hydroxy ketone (d) α -Hydroxy aldehyde
9. mixture of benzaldehyde and formaldehyde on heating with aqueous NaOH solution gives :
(a) C6H5 CH2OH and HCOONa (b) C6H5COONa and CH3OH (d) C6H5CH2OH and CH3OH (c) C6H5COONa and
HCOONa
10. The given reaction

is known as:
(a) Perkin reaction (b) Knoevenagel reaction (c) Reformatsky reaction (d) Claisen-Schmidt reaction

Answers:-
1. (c) 2.(d) 3. D 4. (d) 5. A 6. (c) 7. (a) 8. (c) 9. (a) 10. (c)

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