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Title: Practice Test 1
Started: September 28, 2009 2:55 AM
Submitted: September 28, 2009 2:56 AM
Time spent: 00:00:59
Total score: 0/20 = 0% Total score adjusted by 0.0 Maximum possible score: 20

1. IMF in solution 58
What is the strongest form of intermolecular force between solute and solvent in a solution
of C4H10(g) in C7H16(l)?

Student
Value Correct Answer Feedback
Response
1. ion-dipole 0%
2. dipole- 0%
dipole
3. hydrogen 0%
bonding
4. dipole- 0%
induced
dipole
5. dispersion 100%

Score: 0/1

2. Relative Solubility 42
Which of the following is less soluble in hexane, ethanol or CH3Cl(l). Don't try to type the
subscripts, just use letters and numbers.

Student Response Value Correct Answer

1. not answered 0% Equals ethanol (100%)

Score: 0/1

3. Chapter 8 Molality 7
Determine the molality of a solution prepared by dissolving 8.20 g of cycloheptane in 81.3 g
of benzene.

Student Response Value Correct Answer

Answer not answered 0% 1.03

Score: 0/1

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4. Chapter 8 MF to molal 7
Determine the molality of a solution of water dissolved in ethanol for which the mole fraction
of water is 0.30.

Student Response Value Correct Answer

Answer not answered 0% 9.32

Score: 0/1

5. Ionic Dissociation Calculation 2

How many moles of solute particles are present in 1.00 mL of 0.442 M K3PO4? Use scientific
notation with 3 significant figures!!!!

Student Response Value Correct Answer

Answer not answered 0% 1.77E-3 (1.77 × 10-3)

Score: 0/1

6. General Properties Comparison 3

Consider the solutions, 0.04 m urea [(NH2)2C=O)], 0.04 m AgNO3 and 0.04 m CaCl2. Which
has (i) the highest osmotic pressure, (ii) the highest vapor pressure, (iii) the highest boiling
point?

Student
Value Correct Answer Feedback
Response
1. (a) 0.04 0%
m CaCl2
(b) 0.04
m CaCl2
(c) 0.04
m CaCl2
2. (a) 0.04 100%
m CaCl2
(b) 0.04
m urea
(c) 0.04
m CaCl2
3. (a) 0.04 0%
m urea
(b) 0.04
m CaCl2
(c) 0.04
m urea

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4. (a) 0.04 100%

m CaCl2
(b) 0.04
m urea
(c) 0.04
m urea
5. all will 0%
be the
same

Score: 0/1

7. Chapter 8 VP 1
Calculate the vapor pressure (in torr) at 293 K in a solution prepared by dissolving 30.1 g of
the non-volatile non-electrolye sucrose in 129 g of water. The vapor pressure of water at
293 K is 17.54 torr.

Student Response Value Correct Answer

Answer not answered 0% 17.33

Score: 0/1

8. Chapter 8 BP 5
Calculate the boiling point (in degrees C) of a solution made by dissolving 1.32 g of ethylene
glycol(HOC2H4OH) in 70.0 g of water. The Kbp of the solvent is 0.512 K/m and the normal
boiling point is 373 K.

Student Response Value Correct Answer

Answer not answered 0% 100.156

Score: 0/1

9. Chapter 8 MM bp 6
When 6.6 g of an unknown non-electrolyte is dissolved in 50.0 g of water, the boiling point
increased to 100.805 degrees C from 100 degrees C. If the Kbp of the solvent is 0.512 K/m,
calculate the molar mass of the unknown solute.

Student Response Value Correct Answer

Answer not answered 0% 84

Score: 0/1

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10. Calculate k from Rate Law 34

Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is
[second] order in A, [first] order in B, [first] order in C and [fourth] order overall. USE
WORDS TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! :
Experiment Initial conc of A, Initial conc of B, Initial conc of C, Initial rate,
mol/L mol/L mol/L mol/L.s
1 0.1 0.2 0.4 2 x 10-3
2 0.2 0.2 0.4 8 x 10-3
3 0.3 0.4 0.4 3.6 x 10-2
4 0.4 0.6 0.2 4.8 x 10-2

Calculate the value of k to 3 significant figures.

Student Response Value Correct Answer

1. not answered 0% Equals 2.50 (100%)

Score: 0/1

11. Determine Rate Law 5

Consider the reaction of A(g) + B(g) + C(g) => D(g) for which the following data were
obtained:
Experiment Initial [A], mol/L Initial [B], mol/L Initial [C], mol/L Initial rate,
mol/L.s
1 0.0500 0.0500 0.0100 6.25 x 10-3
2 0.100 0.0500 0.0100 1.25 x 10-2
3 0.100 0.100 0.0100 2.50 x 10-2
4 0.0500 0.0500 0.0200 6.25 x 10-3

What is the rate law for the reaction?

Student Correct
Value Feedback
Response Answer
1. rate = 0%
k[A][B][C]
2. rate = 0%
2 2
k[A] [B] [C]
3. rate = 0%
2
k[A] [B][C]
4. rate = 0%
k[A]2[B]2
5. rate = 100%
k[A][B]

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Score: 0/1

12. IRL 1 t 8

A reaction has a rate constant of 0.00507 sec-1, how long will it take (in minutes) until
0.493 mol/L of the compound is left, if there was 0.744 mol/L at the start? (give answer to 3
sig figs using E notation)?

Student Response Value Correct Answer

Answer not answered 0% 1.353

Score: 0/1

13. IRL 1 c 4

A reaction has a rate constant of 0.00482 sec-1, how much of the compound (in mol/L) is left
after 7.39 sec, if there was 0.868 mol/L at the start? (give answer to 3 sig figs using E
notation)?

Student Response Value Correct Answer

Answer not answered 0% 0.838

Score: 0/1

14. Known Rate Law, Change Conc 7

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2

By what factor does the rate change if the concentration of BrO3- is halved? Just put in the
number as a whole number or fraction.

Student Response Value Correct Answer

Equals 0.5 (100%)
1. not answered 0% Equals 1/2 (100%)
Equals .5 (100%)

Score: 0/1

15. Known Rate Law, Change Conc 29

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2

By what factor does the rate change if the concentration of BrO3- is quadrupled and that of
Br- is quadrupled? Just put in the number as a whole number or fraction.

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Student Response Value Correct Answer

Equals 16 (100%)
1. not answered 0%
Equals 16/1 (100%)

Score: 0/1

16. Chapter 5 IMF 48

Which type of intermolecular force ("interparticle force") is the most important in
PF3(l)?

Student
Value Correct Answer Feedback
Response
1. London 0%
Dispersion
2. Dipole- 100%
dipole
forces
3. Ion-dipole 0%
forces
4. Hydrogen 0%
bonds
5. Ionic 0%
bonds

Score: 0/1

17. Chapter 5 IMF 69

Which type of intermolecular force ("interparticle force") is the most important in
NaCl(aq)?

Student
Value Correct Answer Feedback
Response
1. London 0%
Dispersion
2. Dipole- 0%
dipole
forces
3. Ion-dipole 100%
forces
4. Hydrogen 0%
bonds
5. Ionic 0%
bonds

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Score: 0/1

18. Chapter 5 Phys Props 49

Which of the following substances has the lowest heat of vaporization?

Student
Value Correct Answer Feedback
Response
1. NH3 0%
2. PH3 100%
3. AsH3 0%
4. SbH3 0%

Score: 0/1

19. Chapter 5 Phys Props 21

Which of the following substances would be expected to have the highest melting point?

Student
Value Correct Answer Feedback
Response
1. methane 0%
2. SiH4 0%
3. SnH4 0%
4. GeH4 0%
5. PbH4 100%

Score: 0/1

20. Phase Change enthalpies 2

What is the heat change in J associated with 20.3 g of liquid water at 5.00 ° C changing to
solid water at -5.00 °C?

c(H2 O) (liq) = 4.184 J/(g.K)

c(H2O) (s) = 2.09 J/ (g.K)

DHfus(H2 O) = 6.02 kJ/mol

Enter your answer in scientific format with TWO DECIMAL PLACES (that is, 3 significant
figures total): 1.23X104 =1.23E4. Do not include units. You will not get credit for the
question if you do not use the correct format!!!

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Student Response Value Correct Answer

Answer not answered 0% -7.42E3 (-7.42 × 103)

Score: 0/1

Done

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