primary secondary tertiary quaternary - Importance of the protein structures - Detail notes on secondary structures Primary structure describes the order of covalently linked Amino acid residues. Secondary structure describes the way in which certain lengths of polypeptides interact through CO:NH hydrogen bonds either intramolecularly or Iintermolecularly. Intramolecular H bonding in globular protein Intermolecular H bonding between different chains in fibrous protein Tertiary Structure Tertiary structure describes how the chains with secondary structure Further interact through the side chains (R groups) of the amino acid residues To give 3-D shape.