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Flame Emission Spectrometry

Flame Emission Spectrometry

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Published by shal2006
flame emission spectrometry
flame emission spectrometry

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Published by: shal2006 on Feb 01, 2010
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12/25/2014

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FLAME EMISSIONSPECTROMETRY
PrincipleM.ShaliniDept of ChemicalAdhiyamaan college of Engg,hosur
 
 
Relationship Betw een Atom ic
 
Absorption and Flam e Em ission
 
Spectroscopy
 
Flame Emission
>
 
it measures the radiation
 
emitted by
 
the excited atoms that is related
.
to concentration
 
->
Atomic Absorption it measures the
 
radiation absorbed
 
by the unexcited atoms
.
that are determined
 
Atomic absorption depends only upon the number
,
of unexcited atoms the absorption intensity
 
is not directly affected by the temperature of
.
the flame
,
The flame emission intensity in contrast
 
being dependent upon the number of excited
,
atoms is greatly influenced by temperature
.
variations
 
 
COMPARISON OF FES AND AAS
.
1
 
FES is better for determinations
, -
of alkali alkaline earth and rare
,
earth elements as well as Ga In
.
and Ti
.
2
 
Flame AAS permits
,,,,,,,,,
Ag Al Au Cd Cu Hg Pg Te Sb Se and Sn
 
to be detected with high
.
sensitivity
.
3
-
FES permits quantitative multi
.
element analysis
.
4
 
Flame noise is greater in FES
.
than AAS

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