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المعايرة الحمضية القاعدية

المعايرة الحمضية القاعدية

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05/02/2013

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ELGHZIZAL’ S Scribd Documents
ةيدعاقل ةضمحل ريامل
(
I
سايقب ةراعمل
pH
1
)
: فيرت
دعاقل وأ ( مسمل محل زكرت نت ه ) دعا وأ ( م ريا : أدبملعات مس دعا – م عات اجإ لذو ، ئامل حمل  ) ةمسملريامل
: ريامل عات ي أ جي : طورشل
اك دحمل عامل  سي : اك
رص د د وأ اظحل ي : اير
. ريامل ل   عاي  : ائاق
: ةقيرل
. عال خ عال ل ل رغت ىع دمت : ةمل ريامل
عال ل ة ت بت ىع دمت : ةمل اق ريامل
  اق ريامل
 pH
 ت بت ىع دمت :
 pH
. عال خ
: ؤالةبال امل س) ر ِ يامل و ر َ يامل ( نعامل ءاخ دع ، ريامل خ ؤال قحي. ريامل عات ةلامل )ةيركسل(: اث
A
1
H
)aq
+ A
2 – )aq
A
1-
+ A
2
HC
1
V
1
= C
2
V
2
 
n)A
1
H = n )A
2-
 ؤال دع
:
: ؤال ةموأ ل : رغ لذو ، عال خ رغمل ةئايزل زممل امل رغلا ؤال م
 pH
. ل ةوأحمل ج مسو ، ند ب ) ر ِ يامل و ر َ يامل ( نعامل ا امك ت ؤال دع:  ل زرو ؤال ج ، اضمل ر ِ يامل
V
E
.
ةلامل
CH
3
COOH +HO
-
CH
3
COO
-
+ H
2
O
 م ريامل
A
دعاق
B
: ةلال ل ب
1.
امج خ ةا ة
V
A
ن ا زكرت ذ ر َ يامل حمل رمغو رقمل ءامل ن  ل فضو ك  بصو جج 
 pH
غشو) اجل يدل( ةياع لاحم ب د ،رساغمل رحمل
2.
،  زكرت ذ ر ِ يامل حمل ةد ةاح ة صقو
 pH
. ةا ك دع ابمل ثمل : ع صحمل ىحمل
 pH
ن ي اضمل دعاقل ج ةلد: ءزأ ة
جحل
V
 b
ن أ
9,5ml
 ربك رغت 
V
 b
اقيف رغت
 pH
يو
HO
-
. دحمل عامل
ml ml 
b
5,105,9
 ا رغت
 pH
 رغت ، ربك رغت اقي جحل  ف
 pH
ه حي ، ؤال ةق ىع ءزجل
ml 
b
5,10
 رغت اقي جحل ربك رغت  ف
 pH
عامل ق ةيد ةم ىل ىهايون دحمل
HO
-
ىل
CH
3
COOH
 
ELGHZIZAL’ S Scribd Documents
 ؤال ةق ديدحت ةك
1.
خ دمت ةده ةقير ه : ااممل ةقيراام
T
1
 و
T
2
ق دع نيقسمل   ، ا
T
امل مل. ام ةاسمل  ىع ديو
2.
خ نمي ودج اما : اق ةقيرىحمل
)
bb
 f  dV dpH 
=
ةل ةقش
 pH
ةلد
V
 b
 ؤال ةق دع : اضمل دعاقل ج
V
 b
=V
 bE
ص ةم (ر ةقشمل ةم ت ،: )اي وأةلدل
f)V
 b
خت عأ ةقل  )ةيصقل ةمقل
V
 bE
= 10ml
 اقت لوقسمل
T
دع
 pH = 8,64
ةلدل ي : ةح
f )V
A
م ة دعا ريا دع )ا ةم
(
II
صومل سايقب ةراعمل
12
ابمل ر ، ةمل اق دعا – م ريا بل : أدبمل )
)
 f  
=
σ  
ةمل ت ثمي ل
σ  
ل نمقسمل نئزجل اقت ؤال يو اضمل جحل ةلد حملىحمل
 
ELGHZIZAL’ S Scribd Documents
 
22
: ىحمل )
III
ينومل ةراعمل )
13
ا  فاك اما ةيدعا – ةضم ريامل ؤال ج دحي : أدبمل ): رياملحمل ىل اضمل مل فال ل رغ ؤال ةق ةم ي ريامل ءاأ. ريامل
23
فال اخ ) 

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