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07a4bs03 Organic Chemistry

07a4bs03 Organic Chemistry

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Published by SRINIVASA RAO GANTA
JNTUH 2009-10 QUESTION PAPERS
JNTUH 2009-10 QUESTION PAPERS

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Published by: SRINIVASA RAO GANTA on Feb 25, 2010
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12/26/2012

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Code No: 44063
R07 Set No. 2
II B.Tech II Semester Supplimentary Examinations,February 2010ORGANIC CHEMISTRYChemical EngineeringTime: 3 hours Max Marks: 80Answer any FIVE QuestionsAll Questions carry equal marks

1. (a) Explain the Friedel - Crafts reactions of isoquinolines.(b) Describe, giving mechanism, the synthesis of pyrroles from 1,4-dicarbonyl com-pounds and primary amines. [8+8]2. (a) Discuss the reaction between acetone and formaldehyde in aq.ethanolic KOHsolution.(b) What happens when benzaldehyde is heated with acetic anhydride in thepresence of potassium acetate? [8+8]3. (a) What is the full structure of Bismark-Brown - R?(b) Summaries the important steps in its synthesis.(c) What are the applications of Bismark-brown-R? [4+8+4]4. (a) Differentiate between “Static” and “Dynamic” stereoismers giving examples.(b) Describe the sequence rules for E-Z system of nomenclature and illustrate youranswer by taking crotonic acid as example? [8+8]5. (a) Explain the difference between the following grades of polyethylene: -i. LDPEii. HDPEiii. LLDPE.(b) How are these grades of polythenes made? What are their properties andapplications? [6+10]6. What happens when(a) p-chloroacetophenone is treated with hydroxylamine hydrochloride in ethano-lic sodium carbonate followed by reaction with sulfuric acid in ether solution?(b) benzene is treated with n-propylbromide in the presence of an anhydrous
AlBr
3
? [8+8]7. (a) What is Polarisability effect ? How does it manifest itself in the reactivity of Molecules ?(b) Explain why toluene is more reactive than benzene towards electrophilicaromatic substitutions ? [8+8]1
 
Code No: 44063
R07 Set No. 2
8. (a) Describe the reaction between HBr and 1-octene in the presence of di(p-methylbenzoyl)peroxide.(b) Discuss the reaction between NBS and 1-heptene. [8+8]

2
 
Code No: 44063
R07 Set No. 4
II B.Tech II Semester Supplimentary Examinations,February 2010ORGANIC CHEMISTRYChemical EngineeringTime: 3 hours Max Marks: 80Answer any FIVE QuestionsAll Questions carry equal marks

1. (a) Draw the resonance structures of allyl carbonium ions and explain theirstability.(b) Among the following which is more stable and explain why?i.
C
3
C
2
C
+
(
C
3
)ii. (
C
3
)
3
+
iii.
C
3
C
2
C
+2
[8+8]2. (a) Discuss the Reimer-Tiemann reaction giving the scope of this reaction.(b) Describe, giving mechanism, the reaction between benzene and benzoylchloride in the presence of anhydrous
AlCl
3
in refluxing 1,2-dichloroethane.[8+8]3. (a) What are dialkyl peroxides ? How are they prepared? Describe their behaviouron thermolysis.(b) What happens when 1-butene is treated with HBr in the presence of dibenzoylperoxide ? [6+10]4. (a) Discuss the reaction between two moles of n-butyraldehyde in aq.KOH at RT.(b) What happens when p-bromobenzaldehyde is heated with KCN in aq.ethanolicsolution? [8+8]5. (a) Draw the structures of pyrrole, pyridine, quinoline and isoquinoline ring sys-tems and provide correct numbering for these ring systems.(b) Explain why pyrrole is a weaker base than aniline? [8+8]6. (a) What is condensation polymerisation?(b) Explain, giving examples, how condensation polymerisation is carried out inindustry? [4+12]7. (a) Draw the Fisher projection formulae of optically active forms of lactic acidand label them as D or L.(b) Draw the geometrical isomeric forms of 2-butene and label them as E or Z.(c) Draw the Newman and Sauhorse projection formulae of ethane & explainthem. [8+4+4]3

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