7. ~ ~ fR:r ~ ~ l1'rc>l cp'r a"fr b Clcf) tPl (solid) ~ 3tlx ~ (dashed) ~ 8RT ~ TI"fl1) il ~ .-p) c:'r ~ 8RT ~ \JfT<TI Tf<TI I ~ tPl ~m ~ m -qx -FcP<:rr Tf<TI ~ w s ~ 3tT-x ~T ~m ~ m -qx -FcP<:rr Tf<TI ~ W d ~, Cf6I 31]"QTCf W d / W s Cf)[ ~ ~ 'luITCf) ~ I
4.5
1.5 1.0
4.0 3.5
P 3.0
(atm.)
2.5
2.0
a :;.- .
0.5
0.0
Ans. 2
2 Wd = - {4 x 1.5 + 1 x 1 + 3 x
5
= - {6 + 1 + "3} L atm.
26
=- 3"" L atm.
Wd 26
31\f:, Ws = 3 x 2
~ il ~ lff?[
0,
~
Nwm b~ in ui~bnC6l~b~ w~~ IIT~1J
8.
Ans. 2
Sol. ~CfC'l Na Cf~ F ~ ~L~ 31TCRilCJ)'(ul ~ ~rtc'r ~ I Na+ & F-.
ffiTlFf ~
9. ~ (~ 'I1R = 108 1Tfl1l1'fc;r-1) COT ~ 10.5 9 em-3 ~ I 10-12 m2 ~ ~ LR ~ ~31T CJ5T ~ ~~ ~m ij y x 10x 8RT ~ CJ5T \JlT ~ ~ I x COT ~C"Il" ~:
Ans. 7
Sol. 1 1=i'rC'f Ag ~31T COT ~
_ 108 3
- 10.5 em imole
_ 108 x 1 3
1 Ag ~ COT ~ - 10.5 6.022x1023 em
. ± 3 _ 1 08 x 1 23
31\f., 3TCR -10.5 6.022x1023=1.708XlO-
R3 = 0.407 x 10-23 ern"
R3 = 0.407 x 10-29 m3
):l"~Cf) Ag ~ COT ~~
31\f:, ~ ~ ~~ ij Ag ~31T CJ5T ~
10-12 108
= (0.407 x 10-29m3)2/3 = (1C x 2)
= 1.6 x 107 = Y x lOx
x=7
Sol. [M(abed)]"&cgC'f crl fPiC1C'11Gl ~ (i) (a T b) (e T d); (ii) (a T e) (b T
cfr ~fC;jctf<:Cj) ~f8.'%I~,& p Cf~ Q ~ K2eo3 CJ5T ~ ij >r~ Cf)X cfi <:tTfTrco R ~ t \YI'r fcp HeN cfi X1T~ fcrcr"'q.l Cf)X cfi <:tTfTrco <tw ~ I 31 '"'C'11 GlCj)'(UI Cf~ 'Tl"f ~ -q'( s m ~ Tf<TI ~ ~w ~ :
H3e OH
H;OO
o
12. <:tTfTrco P Cf~ Q ~T: -g'r'lT :
He
H H 3 "-...
3ft\: CH
(D) I
CH3
! \
\
~t,
u Ans. (8)
H
(e)
ilill ul§l;§JOlillcatllllCI§l ~~I-U~J
H3C OH
Ans. (A)
14.
Ans. (0)
CH3 0 CN
1 H,,---/H II I
CH H H3 C"--- /C"--- H3C,,--- /CH,,---
H C/ "---C/ C aq. K2C03
Sol. II C H HCN C OH
3 II + /1
0 (sFrn ~~) /1
(P) 0 H3C CH H3C CH
(0) 2"---OH 2"---OH
(R) (8) \
COOH~
H
~~"I:JPl ct ~ mlnrf Li2+ ~ <TrC'lcf: ~ ~ 81 ij t ~ 100 ~ -;::fr~ ~ I ):l"~T ~Tr1fUT -qx ~ COT ~ 82 ~ ij ID \JfTCfT ~ I ~ 82 ctT 100 ~ ~ ~ 3fR ~ ~ @~~1\J1'l ~ ctT ~ ~ ctT ~ ct 6RT6I"\ ~ I
S2 ~ CJ5T \JJ\Jlf = H-~ ij ~~T-;:::r CJ5T f.19crq ~ ij \JJ\Jlf = - 13.6 eV/atom
= - 13.6 [~: lev/atom
n = 3.
fPilCJ)'(ul (1) ij ffi -q'( e 1
31cf:, Cf)~ => 3p
1(1
p q r S t
AG®®eO B@C90®CD cGC9®®CD O@®®eo
18. q;l<'fl'l I CJ5T ~31T cp'r q;l<'fl'l II cfi ~ ~ cfi X1T~ fi1c;nl:t I
q;l<'fl'll
0
OH OH II
I I /C CH3
(8) H C-C-C-CH, H2SO4 HC "C/'
3 I I ~ 3 I---CH3
CH3CH3 CH3
(C)Q-e-° 1. LiAIH4 Q-cH'0H
- 'CH3 2. H3O+ 'CH
3
(D) HS-Q-CI Base a
(q) ~ (addition)
(r) ):l"~ (substitution)
(s) ~~ (coupling) ~
Ans. (A) - r,s ; (8) - t ; (C) - p, q ; (0) - r
Q-N=N
OH
Sol. (A) 6 N.OH
OH OH I I
(8) H C-C-C-CH W
3 I I 3
CH3CH3
(-W)
OH CH3 I I
H C-C-C-CH
3 ffi I 3
CH3
o
(C) ~:~!l«JIl#ljG~~:~~ fi\W'I)
(D) HS-Q-CI IffR ~~rcl 3Rl~T~lij) j;[fu~ a
19. q;l<'fl'l I ij ~ wft <:tTfTrcp \JfC>l cfi X1T~ >r~ C!ffi'r ~ I ~ ~31T cfi ~ cp'r q;l<'fl'l II ij ~ ~ ~ cfi X1T~ fi1c;rrct I
AB = 21 + 1 ol + 11k and AD = - 1 + 2} + 2k . *ilil'lI'i1'< ~:t\Jf ct ~ ij :!\JlT AD co'r 100 ~"'l" co'rur a -fr ~1=fT<Tf \JlT(ff ~ ~ fcp AD, AD' q;:r I:JlTCfi ~ 1 ~ AD' , AB ct "*iT~ ~ q;:mfi t ill cos (a) COT11T'l" f.19 ~
8 (A) - 9
(B) J17 9
1 (C) - 9
(D) 4J5 9
Ans. (8)
-2+20 +22 8
Sol. cos 8 = =
15 x 3 9
8 + a = 900
a = 900 - 8
J17
cos a = sin 8 = -9- ~ ~ -q 5"s:f~ ~ I "s:f~c:p "s:f~ m~\'ft'F~~:t-'=~~~~~~[ufllll"'I=c:pcp ~ I 3it3ll"X~ (OR5) -q "s:f~ ~~ ~
~Tffi ~ ~ 1"[1) ~<>ffi -q ~ ~ \"1 1101 ~ I
\
~ det (adj A) + det (adj B) = 106, ill [k]
! \
r2k -1
A= 2-Jk -2-Jk
2-Jk 2-Jkj
1 -2k
2k -1
COT 11T'l" ~
(;:fie: adj M"FcP"m crl 31fC2l-g M COT adjoint Cf~ [k], ~ 'lurTCf) I:il'r k -fr CJ)11 <TI ~ ~ I]
~ ~ ij 2 ]:l"~-;::r ~ 1 ~ 100 ]:l"~-;::r ij "ifI\ Cf)~ (A, B, C 3tT-x 0) c:p'f<'f1'l-1 ij ~ it ~ 3tT-x c:p'f<'f1'l-1I ij clTcq Cf)~ (p, q, r, S 3tT-x t ~ 'Tit ~ 1 c:p'f<'f1'l-1 ij ~ 'Tit Cf)~ ij -fr 100 Cf)~ c:p'f<'f1'l-1I ij ~ 'Tit 100 <TI ~ (Column-II) ct 100 "lIT 100 ~
CJ5T t ~ LR c:-\ ~ I ~ 4. 16 ~ cfi "6fTC:" ~ ~fumtfl'lf LfC;T~ cfi ~ CJ5T ~ P "£1CCP -fr CJ)l1 -g'r "\JfTCfi t p COT ~~I
€~~r O_U __ ._ I-----+----I--~""'--.l,-----I 2
1+-~--~~--~~~
2 3 456 7 8
Ans. 8
Years
46. 20 m ~ ct 100 ~ c;cIUT CJ5T 311"\ ~T 311;f -qx \JlTC'r Sit 100 fuq COT >rFc'rfi:iq 30 sec. ij 235 m ~ 570 m-qx RSl fjC!) C"11 ~ I fuq CJ5T "'mC'l km/h 0 u r ij Cfm -g'r<jT ?
Ans. 3
Sol. R=20m,f=10m
c;cIUT ct ~
Sol.
dN
-- =AN dt
dN
-- = AN e-At
dt 0
y = mx + c m=-A
1 A= - 2
fn2 T=A
4.16 = 2 x 0.693 = -n
n=3=~~~ p = Z3 = 8. Ans.
1 1 1
-+-=-
V U f
1 1 1
--+-=-
25/3 U1 10
3
50
111 --+- -- 5017 U2 - 10
! \
\
U1 = - 50 cm
- --
U2 25
U2 = -25 cm
~ 5 18
krn/hr rl = 6" x 5 = 3 km/hr.
47. 100 ~ -qx coTcq (J.l = 5/3) COTS em 1=I'r~ COT 100 ~ ~CCPT ~T ct 100 ~ ~Cf -qx \m ~ I <:ffi ~m \JlTClT ~ fcp ~ ~ ~1Q ~ ~T R em ~ ct CJ:'fITCl)R~?f ~ ~ PiCJ)C'1C11 ~ I R COT =n= ~ ~ I
Ans. 6
R tanG = 8
............ (i)
5
3" sinG = 1.sin900
3 sinG = 5"
G = 37°
3 R
=
4 S
R = 6 em.
48. 100 1 0 cITC'C CJ5T ~cil" A 3tT-x B ~31T -qx m ~ ll<'r ~~ ij ~ t = 0 -qx \Jl'rtl" \JfTCfi ~ I ~ x=l~ -qx >lWB
ij cp'r~ ~ 31fcr~T -;::r -gT ill ~ Xi +t I ~ \t -gTTjT ?
I:Jl6I 31i~ ij p ~ CJ5T 100 ~ c; q I ...& ; I q ell c>1T IJ"lTCfi ~ I ~ ~ \3?4"\ c>fl'r qc;:q coT
~ LR ~ ~ m ~ B-G LR ~. 1'( COT ~ ~ ~ ~ I ~ ~ ~
<:rg l"J"A ~ ~ fco ffi cnc>1T ~G COT ~ ~ t crmfco ~ ~ ij 1fCD ~ ij ~ ~ ~ ~ I ¥ ~ ~ COT frrmXUT ~ ~ ~ ~ R ~ CJ5T ~G LR ~1Q ~ T ~ CJ)T\UT cgC'f "GltcITtR 6fC'l COT ~ qm'r ~ I I:Jl6I <:rg 6fC'l ~G ~ lfR "fr CJ)l1 -g'r \JlTCff t ~G ~ "fr 31c'flT -g'r IJ"lTCfi ~ I
(r« R l"J"AC'r s~)
(A) z-rr
in
Ans. (C)
Sol.
51. ~ r = 5 x ] 0-4 m, p = 103 kgm-3, 9 = 10 ms-2,T = 0.11 Nm-1, cITl:Jl6I 'ic:- ~ ~ 31cYfTf -g'rcfi t ~ ~ (C'flTlflT) ~ -g'rTjT, m ~ fctcPc;q'f ij ~ ~~ I
(A) 1.4 x 10-3 m
(8) 3.3 x10-3 m
(C) 2.0 x 10-3 m
(D) 4.1 x10-3m
Ans. (A)
Sol. ~c:- -qx qc;:ff cpr ~c>Pl ~ -qx
[ 2 J1I4
3Tr
R= -- 2pg
[ 8 J1/4
= 3 x 0.11 x 25 x 10-
2x103 x10
(8) 2.7 x
(D) 8.1 x 1O-6J
= 14.25 x 10-4 m = 1.425 x 10 3
Ans. (8)
Sol. t=c:- CJ5T "9:15 ~
U=TA
= 0.11 x4n(1.4x10-3)2
= 2.7x10-6J
fl~ 53 3tlv 55 cff ~ ~cr
mcT-;::r cfi ~ 311\ ~l1c'r ~~T-;::r cfi cp'rufm xfcr'T COT CfCli~, ql--gx cfi ~~ ~ xiT~l=f ~Cf COT lj~ 31TtrR ~ I -gl=[ ~ ~Cf cp'r 311\ 3Wr ~Tc'r s~ 100 ~ ~uf-;::r llfC'r cfi ~ ~'T C!ffi'r ~ Cf~ 100 f8 q'(li I fill CI CJ) ~ cp'r ¥. ~ sit ~ CfCII <ilCild ~ ~ R1 CJ)I c'i ,'I I ~ ~ m cfi CfCI i 21 CIld ~t[ ~ f.1<:r:r COT ~ fcR:rr~ I