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07.Surface Chemistry 117-132

07.Surface Chemistry 117-132

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06/29/2011

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1
PREVIOUS EAMCET BITS
1. The extent of Physisorption of an absorbate increases with
(2009 M)
1) increase in temperature2) decrease in surface area of the adsorbent3) decrease in pressure of adsorbate 4) decrease in temperatureAns : 4Sol: Extent of Physisorption increases with decrease in temperature2. Which one of the following reactions is an example of auto-catalysis?
(2008 M)
 1)
( ) ( ) ( )
3 3 2
2 2 3
s s g
 AsH As
+
2)
( ) ( ) ( )
2 2 3
3 2
s
Feg g g
 N H N
+
 3)
( ) ( )
( )
( )
2 2 3
2 2
g
 NOg g g
SO O SO
+
 4)
( )
( )
( ) ( )
12 22 2 6 12 6 1211 6 6
l
 H ll l l
C H O H O C H O C H O
+
+ +
 Ans : 1Sol:
( ) ( ) ( )
3 3 2
2 2 3
s s g
 AsH As
+
 As is auto-catalyst3. Which of the following is not correct
(2007 E)
1) Milk is naturally occurring emulsion 2) Gold is a Lyophilic sol.3) Physical adsorption decreases with rise in temperature4) Chemical adsorption is not unilayeredAns : 2Sol: Gold is a Lyophobic sol.4. Disperse phase and Dispersion medium in blood are respectively
(2007 M)
1) Solid and liquid 2) Liquid and solid 3) Liquid and Liquid 4) Solid and solidAns : 1Sol: Blood is Solid in liquid sol.5. The disperse phase, dispersion medium and nature of colloidal solution (lyophilic or lyophobic) of gold sol’respectively are :
(2006 E)
 1) solid, solid, lyophobic 2) liquid, liquid, lyophobic3)solid, liquid, lyophobic 4) solid, liquid, lyophilicAns : 3Sol: Gold sol Lyophobic solDisperse phase - solidDispersion medium - liquid6. Which of the following is not correct
(2006 M)
1) Enthalpy of physical adsorption is less compared to enthalpy of chemical adsorption2) Milk is an example for emulsion3) Physical adsorption increases with the increase the temperature4) Smoke is an aerosol
 
Ans : 3Sol: Physical adsorption increases with the increase the temperature7. Which of the follwoing is an example for heterogeneous catalysis reaction ?
(2005 E)
7. SURFACE CHEMISTRY
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Surface Chemistry 
2
1)
( )2 2 3
2 ( ) ( ) 2 ( )
 NO g
SO g O g SO g
+
 2) Hydrolysis of aqueous sucrose solution in the presence of aquesous mineral acid3)
P ( )2 2 2 2
2 ( ) 2 ( ) ( )
t s
 H O l H O l O g
 +
 4) Hydrolysis of liquid ester in the presence of aqueous mineral acidAns : 3Sol: Heterogeneous Catalysis
( )
( )
2
P ( )2 2 2 ( )2
2 ( ) 2
s
t s or lg MnO
 H O l H O O
 +
 8. Which of the following is correct
(2005 M)
1) Catalyst undergoes permanent chemical change2) Particle size of solute in true solutions is 10
-3
m3) Starch solution is a hydrosol4) Hydrolysis of liquid ester in the presence of mineral acid is an example of heterogeneous catalysisreactionsAns : 3Sol: Starch solution is an aqual sol or hydrosol9. Which of the following is a lyophobic colloidal solution
(2004 E)
1) Aqueous starch solution 2) Aqueous protein solution3) Gold sol 4) Polymer solution in some organic solventsAns : 3Sol: Gold sol is a lyophobic sol.10. Which one of the following is a lyophilic colloidal solution
(2004 M)
1) smoke 2) Gold sol 3) Starch aqueous solution 4) cloudAns : 3Sol: Starch aqueous solution is a lyophilic.11. Which one of the following equation represents Freundlich adsorption isotherm?
(2003 E)
 1)
 xKPm
=
2)
n
 xKPm
=
 3)
log
n
 xKPm
=
4)
log log
 xKn Pm
=
 Ans : 2Sol: Freundlich adsorption isotherm
n
 xKPm
=
 12. Collidal solution of gold prepared by different methods are of different colours because of
[2003 M]
1) Variable valency of gold2) Different concentrations of gold particles3) Impurities produced by different methods4) Different diameters of colloidal gold particlesAns : 4Sol: Gold sol is blue if particle size is big and red if particle size is small13. Which one of the following statements is not correct
[2002 E]
1) Physical adsorption decreases with increase in the temperature
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