Professional Documents
Culture Documents
IMPORTANT INSTRUCTIONS
1. Immediately fill the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen.
Use of pencil is strictly prohibited.
2. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out the Answer Sheet and
fill in the particulars carefully.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 432.
5. There are three parts in the question paper. The distribution of marks subjectwise in each part is as under for each correct response.
6. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each question. ¼ (one fourth) marks
will be deducted for indicating incorrect response of each question. No deduction from the total score will be made if no response is
indicated for an item in the Answer sheet.
7. Use Blue/Black Ball Point Pen only for writing particulars/marking responses on Side-1 and Side-2 of the Answer Sheet. Use of pencil
is strictly prohibited.
8. No candidate is allowed to carry any textual material, printed or written, bits of papers, paper, mobile phone, any electronic device, etc.,
except the Admit Card inside the examination hall/room.
9. Rough work is to be done on the space provided for this purpose in the Test Booklet only. This space is given at the bottom of each
page.
10. On completion of the test, the candiate must hand over the Answer Sheet to the Invigilator on duty in the Room/Hall. However, the
candidates are allowed to take away this Test Booklet with them.
11. Make sure that the CODE printed on Side-2 of the Answer Sheet is the same as that on this booklet. In case of discrepancy, the condidate
should immediately report the matter to the Invigilator fo replacement of both the Test Booklet and the Answer Sheet.
12. Do not fold or make any stray marks on the Answer Sheet.
3
Sol. N2(g) + H (g) NH3 (g) ; Hfº = – 46.0 kJ mol–1
2 2
1 3
NH3(g) N2(g) + H2 (g) ; H = + 46
2 2
3 3
H 3 H ; H = + 436 ×
2 2 2
1 1
N N ; H = + 712 ×
2 2 2
––––––––––––––––––––––––––––––––––––––––––––––––
1056
Average bond energy of N–H bond = = + 352 kJ mol–1
3
2. The time for half life period of a certain reaction A Products is 1 hour. When the initial concentration
of the reactant ‘A’, is 2.0 mol L–1 , how much time does it take for its concentration to come from 0.50 to 0.25
mol L–1. If it is a zero order reaction?
(1) 4 h (2) 0.5 h (3) 0.25 h (4) 1 h
Ans. (3)
( t1/ 2 )1 a1
( t 1/ 2 ) 2 a 2
1 2
( t1/ 2 )2 0.50
0 .5
t1/2 = = 0.25 h.
2
Page # 2
3. A solution containing 2.675 g of CoCl3 . 6 NH3 (molar mass = 267.5 g mol–1) is passed through a cation
exchanger. The chloride ions obtained in solution were treated with excess of AgNO3 to give 4.78 g of AgCl
(molar mass = 143.5 g mol–1). The formula of the complex is (At. mass of Ag = 108 u)
(1) [Co(NH3)6 ] Cl3 (2) [CoCl2 (NH3)4] Cl (3) [CoCl3(NH3)3] (4) [CoCl(NH3)5] Cl2
Ans. (1)
2.675
Sol. Mole of CoCl3 . 6NH3 = = 0.01
267.5
4.78
Mole of AgCl = = 0.03
143 .5
[H ][HS ]
Keq =
[H2S]
K eq [H2 S]
[HS–] =
[H ]
[Cl2 ][H2S]
= K1Keq
[H ]
5. If 10–4 dm3 of water is introduced into a 1.0 dm3 flask at 300 K, how many moles of water are in the vapour
phase when equilibrium is established ?
(Given : Vapour pressure of H2O at 300 K is 3170 Pa ; R= 8.314 J K–1 mol–1)
(1) 5.56 × 10–3 mol (2) 1.53 × 10–2 mol (3) 4.46 × 10–2 mol (4) 1.27 × 10–3 mol
Ans. (4)
Page # 3
Sol. PV = nRT
V = 1 dm3 = 10–3 m3
P = 3170 Pa
R = 8.314 J K–1 mol–1
T = 300 K
3170 × 10–3 = n × 8.314 × 300
3170 10 3
n= = 1.27 × 10–3 mol.
8.314 300
6. One mole of a symmetrical alkene on ozonolysis gives two moles of an aldehyde having a molecular mass
of 44 u. The alkene is :
(1) propane (2) 1-butene (3) 2-butene (4) ethene
Ans. (3)
Sol. CnH2nO = 44
CnH2n = 44 – 16
CnH2n = 28
n=2
O / Zn
CH3–CH=CH–CH3 3 CH3–CH=O
7. If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous solution,
the change in freezing point of water (Tf), when 0.01 mole of sodium sulphate is dissolved in 1 kg of water,
is (Kf = 1.86 K kg mol–1)
(1) 0.0372 K (2) 0.0558 K (3) 0.0744 K (4) 0.0186 K
Ans. (2)
HO
Sol. Na2SO4 (s) 2 2Na+ (aq.)+ SO42– (aq.)
Tf = i Kfm
= 3 1.86 0.01
= 0.0558 K
8. From amongst the following alcohols the one that would react fastest with conc. HCl and anhydrous ZnCl2,
is
(1) 2-Butanol (2) 2-Methylpropan-2-ol (3) 2-Methylpropanol (4) 1-Butanol
Ans. (2)
Sol. Reaction of alcohol with HCl and anhydrous ZnCl2 is an SN reaction.
3° alcohol react faster with HCl and anhydrous ZnCl2 since it forms more stable carbocation intermediate.
NH2
NaNO HBF4
2
A B
HCl, 278 K
Page # 4
Sol. NaNO HCl
2
HBF
4
278 K
10. 29.5 mg of an organic compound containing nitrogen was digested according to Kjeldahl’s method and the
evolved ammonia was absorbed in 20 mL of 0.1 M HCl solution. The excess of the acid required 15 mL of 0.1
M NaOH solution for complete neutralization. The percentage of nitrogen in the compound is :
(1) 59.0 (2) 47.4 (3) 23.7 (4) 29.5
Ans. (3)
Sol. Weight of organic compound = 29.5 mg
(1.5 m mole)
14
weight of nitrogen = 8.5 mg
17
= 7 mg
7
% Nitrogen = 100 = 23.7 %
29.5
11. The energy required to break one mole of Cl – Cl bonds in Cl2 is 242 kJ mol–1 . The longest wavelength of light
capable of breaking a single Cl – Cl bond is
(c = 3 × 108 ms–1 and NA = 6.02 × 1023 mol–1)
(1) 594 nm (2) 640 nm (3) 700 nm (4) 494 nm
Ans. (4)
242 103
= J molecule–1
6.02 1023
hc
E=
Page # 5
12. Ionisation energy of He+ is
19.6 × 10–18 J atom–1 . The energy of the first stationary state (n = 1) of Li2+ is :
(1) 4.41 × 10–16 J atom–1 (2) – 4.41 × 10–17 J atom–1
(3) – 2.2 × 10–15 J atom–1 (4) 8.82 × 10–17 J atom–1
Ans. (2)
Sol. I.E. of He+ = 19.6 10–18 J atom–1
I.E. = – E1
E1 for He+ is = – 19.6 × 10–18 J atom–1
(E1)He ( ZHe )2
=
(E1)Li3 ( ZLi2 )2
19.6 1018 4
(E1)LI2
=
9
19.6 9 1018
E1(Li2+) =
4
Page # 6
15. On mixing, heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid
components (heptane and octane) are 105 kPa and 45 kPa respectively. Vapour pressure of the solution
obtained by mixing 25.0 g of heptane and 35 g of octane will be (molar mass of heptane - 100 g mol–1 and of
octane = 114 g mol–1)
(1) 72.0 kPa (2) 36.1 kPa (3) 96.2 kPa (4) 144.5 kPa
Ans. (1)
0.25 0.307
= 105 + 45
0.557 0.557
(1) (2)
(3) (4)
Ans. (1)
Sol. Conc. H SO
2 4
H shift +
H /
18. In aqueous solution the ionization constants for carbonic acid are
K1 = 4.2 × 10–7 and K2 = 4.8 × 10–11
Select the correct statement for a saturated 0.034 M solution of the carbonic acid.
(1) The concentration of CO32– is 0.034 M.
(2) The concentration of CO32– is greater than that of HCO3–.
(3) The concentration of H+ and HCO3– are approximately equal.
(4) The concentration of H+ is double that of CO32–.
Ans. (3)
Page # 7
Sol. H2CO3 H+ + HCO3– K1 = 4.2 × 10–7
[H ][CO 23 ]
K2 =
[HCO 3 ]
19. The edge length of a face centred cubic cell of an ionic substance is 508 pm. If the radius of the cation is 110
pm, the radius of the anion is
(1) 288 pm (2) 398 pm (3) 618 pm (4) 144 pm
Ans. (4)
Sol.
2 × 110 + 2 × r– = 508
2r– = 288
r– = 144 pm
20. The correct order of increasing basicity of the given conjugate bases (R = CH3) is :
Ans. (4)
1
Sol. Basicity Electronegativity (In period)
If lone pair of electron takes part in conjugation then avialibality of lone pair of electron decrease and basic
strength decrease.
21. The correct sequence which shows decreasing order of the ionic radii of the elements is :
(1) Al3+ > Mg2+ + Na+ > F– > O2– (2) Na+ > Mg2+ > Al3+ > O2– > F–
(3) Na+ > F– > Mg2+ > O2– > Al3+ (4) O2– > F– > Na+ > Mg2+ > Al3+
Ans. (4)
Sol. O2–, F–, Na+, Mg and Al3+ have same number of electrons (i.e. 10 electrons) but different nuclear charges and,
therefore, they are isoelectronic species.
1
For isoelectronic species ionic radii nuclear ch arg e .
So, correct order is 8O2– > 9F– > 11Na+ > 12Mg2+ > 13Al3+
22. Solubility product of silver bromide is 5.0 × 10–13 . This quantity of potassium bromide (molar mass taken as
120 g mol–1) to be added to 1 litre of 0.05 M solution of silver nitrate to start the precipitation of AgBr is :
(1) 1.2 × 10–10 g (2) 1.2 × 10–9 g (3) 6.2 × 10–5 g (4) 5.0 × 10–8 g
Ans. (2)
Page # 8
Sol. Ksp = [Ag+] [Br–] = 5.0 × 10–13
[Ag+] = 0.05 M
[0.05] [Br–] = 5.0 × 10–13
5.0 10 13
[Br–] = = 1 × 10–111 M
0.05
23. The Gibbs energy for the decomposition of Al2O3 at 500ºC is as follows :
2 4
Al2O3 Al + O2, rG = + 966 mol–1 . The potential difference needed for electrolytic reduction of Al2O3
3 3
at 500ºC is at least :
(1) 4.5 V (2) 3.0 V (3) 2.5 V (4) 5.0 V
Ans. (3)
2 4
Sol. Al O Al + O2
3 2 3 3
24. At 25 °C, the solubility product of Mg(OH)2 is 1.0 10–11. At Which pH, will Mg2+ ions start precipitating in the
form of Mg(OH)2 from a solution of 0.001 M Mg2+ ions ?
(1) 9 (2) 10 (3) 11 (4) 8
Ans. (2)
Sol. KSP = 1.0 × 10–11 = (Mg+2) (OH–)2
1.0 × 10–11 = (0.001) (OH–)2
(OH–) = 10–4
POH = 4
PH = 14 – 4 = 10.
25. Percentages of free space in cubic close packed structure and in body centered packed structure are
respectively.
(1) 30% and 26% (2) 26% and 32% (3) 32% and 48% (4) 48% and 26%
Ans. (2)
Sol. Packing fraction of CCP = = 0.74 74%
3 2
3
Packing fraction of BCC = = 0.68 68%
8
Page # 9
26. Out of the following, the alkene that exhibits optical isomerism is.
(1) 3-methyl-2pentene (2) 4-methyl-1-pentene (3) 3-methyl-1-pentene (4) 2-methyl-2-pentene
Ans. (3)
Sol.
(1) Mn > Cr > Fe > Co (2) Cr > Fe > Mn > Co (3) Fe > Mn > Cr > Co (4) Cr > Mn > Fe > Co
Ans. (1)
Sol. Generally across the first transition series, the negative values for standard electrode potential decrease
(exception Mn- due to stable d5 configuration)
Standard electrode potential –
Mn Cr Fe Co
2+
M /M –1.18 –0.90 –0.44 –0.28 E/V
So, correct order is Mn > Cr > Fe > Co.
29. The polymer containing strong intermolecular forces e.g. hydrogen bonding is
(1) teflon (2) nylon 6,6 (3) polystyrene (4) natural rubber
Ans. (2)
30. For a particular reversible reaction at temperature T, H and S were found to be both +ve. If Te is the
temperature at equilibrium, the reaction would be spontaneous when.
(1) Te > T (2) T > Te (3) Te is 5 times T (4) T = Te
Ans. (2)
Sol. G = H – TS
For spontaneous reaction G must be negative
At equilibrium temperature
G = 0
to maintain the negative value of G
T should be greater than Te
Page # 10
PART - B (PHYSICS)
31. A rectangular loop has a sliding connector PQ of length and resistance R and it is moving with a speed
v as shown. The set-up is placed in a uniform magnetic field going into the plane of the paper. The three
currents 1, 2 and are :
Ans. (2)
vB 2vB
Sol. Current = =
R/2R 3R
vB
1 = 2 =
3R
32. Let C be the capacitance of a capacitor discharging through a resistor R. Suppose t1 is the time taken for the
energy stored in the capacitor to reduce to half its initial value and t2 is the time taken for the charge to
reduce to one-fourth its initial value. Then the ratio t1/t2 will be
1 1
(1) 1 (2) (3) (4) 2
2 4
Ans. (3)
1
e 2 t1 / ô
2
ô
t1 = n2 ....(1)
2
q0 1
and q = q0 e t 2 / ô ; = q0 e t 2 / ô , e t2 / ô
4 4
t2 = 2 ln 2 ....(2)
t1 1
t2 4
Page # 11
Direction : Question number 33-34 contain statement-1 and statement-2. Of the four choices given after the state-
ments, choice the one that best describes the two statements.
33. Statement-1 : Two particles moving in the same direction do not lose all their energy in a completely
inelastic collision.
Statement-2 : Principle of conservation of momentum holds true for all kinds of collisions.
(1) Statement-1 is true, Statement-2 is true; Statement-2 is the correct explanation of Statement-1.
(2) Statement-1 is true, Statement-2 is true; Statement-2 is not the correct explanation of Statement-1
(3) Statement-1 is false, Statement-2 is true.
(4) Statement-1 is true, Statement-2 is false.
Ans. (1)
Sol. If initial momentum of particles is zero, then they loss all their energy in inelastic collision but here initial
momentum is not zero.
Principle of conservation of momentum holds good for all collision.
34. Statement-1 : When ultraviolet light is incident on a photocell, its stopping potential is V0 and the maximum
kinetic energy of the photoelectrons is Kmax. When the ultraviolet light is replaced by X-rays, both V0 and
Kmax increase.
Statement-2 : Photoelectrons are emitted with speeds ranging from zero to a maximum value because of
the range of frequencies present in the incident light.
(1) Statement-1 is true, Statement-2 is true; Statement-2 is the correct explanation of Statement-1.
(2) Statement-1 is true, Statement-2 is true; Statement-2 is not the correct explanation of Statement-1
(3) Statement-1 is false, Statement-2 is true.
(4) Statement-1 is true, Statement-2 is false.
Ans. (4)
35. A ball is made of a material of density where oil < < water with oil and water representing the densities of
oil and water, respectively. The oil and water are immiscible. If the above ball is in equilibrium in a mixture of
this oil and water, which of the following pictures represents its equilibrium position?
Ans. (2)
Page # 12
36. A particle is moving with velocity v K( y î x ĵ ) , where K is a constant. The general equation for its path is:
dr
Sol. K( y î x ĵ )
dt
dx dy
=y, =x
dt dt
dy x
So, dx y
y dy x dx
y2 x2
C
2 2
y2 = x2 + constant
37. Two long parallel wires are at a distance 2d apart. They carry steady equal currents flowing out of the plane
of the paper as shown. The variation of magnetic field B along the line XX´ is given by
(1) (2)
(3) (4)
Ans. (1)
Sol.
Towards left of both wires direction of B is downward and at mid point between two wires, magnetic field is
zero
Page # 13
38. In the circuit shown below, the key K is closed at t = 0. The current through the battery is :
VR1R 2 V V V (R1 R 2 )
(1) at t = 0 and at t = (2) at t = 0 and at t =
R12 R 22 R2 R2 R1R 2
V VR1R 2 V (R1 R 2 ) V
(3) R at t = 0 and at t = (4) at t = 0 and R at t =
2 R12 R 22 R1R 2 2
Ans. (2)
Sol. At t = 0, current does not flow through inductor.
V
i= R
2
R1R 2
At t = Req = R R
1 2
V (R1 R 2 )
i=
R1R 2
39. The figure shows the position - time (x – t) graph of one-dimensional motion of a body of mass 0.4 kg. The
magnitude of each impulse is
dx 2
Sol. V1 = 1
dt 1 2
dx
V2 = 1
dt 2
M
The nucleus of mass M + m is at rest and decays into two daughter nuclei of equal mass each.. Speed
2
of light is c.
40. This binding energy per nucleon for the parent nucleus is E1 and that for the daughter nuclei is E2. Then :
(1) E1 = 2E1 (2) E1 > E2 (3) E2 > E1 (4) E1 = 2E2
Ans. (3)
m 2m m m
(1) c (2) c (3) c (4) c
M m M M M m
Ans. (2)
1 M 1 M
Sol. Q = m c2 = × v2 + × v2
2 2
2 2
1
mc2 = × Mv2
2
2m
v=c
M
42. A radioactive nucleus (initial mass number A and atomic number Z) emits 3 -particles and 2 positrons. The
ratio of number of neutrons to that of protons in the final nucleus will be
A
Sol. ZX 3 2 He 4 Z 8 Y A 12 2 1e 0 2
number of proton = Z – 8
number of neutron = (A – 12) – (Z – 8) = A – Z – 4
AZ4
ratio is
Z8
Page # 15
43. A thin semi-circular ring of radius r has a positive charge q distributed uniformly over it. The net field E at the
centre O is :
q q q q
(1) 2 2
ĵ (2) – 2 2
ĵ (3) – 2 2
ĵ (4) ĵ
4ð å 0r 4ð å 0r 2ð å 0 r 2ð å 0 r 2
2
Ans. (3)
2kë ë
Sol. E ( ĵ ) E ( ĵ )
r 2ðå 0r
q q
ë E ( ĵ )
ðr 2ð å 0 r 2
2
(1) OR gate (2) Not gate (3) XOR gate (4) NAND gate
Ans. (1)
Sol.
Truth Table
A B A B AB X = AB A B X
0 0 1 1 1 0 0 0 0
0 1 1 0 0 1 0 1 1
1 0 0 1 0 1 1 0 1
1 1 0 0 0 1 1 1 1
Page # 16
45. A diatomic ideal gas is used in a Carnot engine as the working substance. If during the adiabatic expansion
part of the cycle the volume of the gas increases from V to 32 V, the efficiency of the engine is :
(1) 0.5 (2) 0.75 (3) 0.99 (4) 0.25
Ans. (2)
Sol. TV – 1 = constant
7 7
1 1
T1 V 5 = T2 (32V ) 5
T2 1 1
T1 = (32)2 / 5 = 4
T2 1 3
=1– T =1–
1 4 4
46. If a source of power 4 kW produces 1020 photons/second, the radiation belongs to a part of the spectrum
called :
(1) X-rays (2) ultraviolet rays (3) microwaves (4) -rays
Ans. (1)
4000
Sol. Energy of each photon = = 4 × 1017
1020
It is in X-ray spectrum.
47. The respective number of significant figures for the numbers 23.023, 0.0003 and 2.1 × 10–3 are
(1) 5, 1, 2 (2) 5, 1, 5 (3) 5, 5, 2 (4) 4, 4, 2
Ans. (1)
48. In a series LCR circuit R = 200 and the voltage and the frequency of the main supply is 220 V and 50 Hz
respectively. On taking out the capacitance from the circuit the current lags behind the voltage by 30º. On
taking out the inductor from the circuit the current leads the voltage by 30º. The power dissipated in the LCR
circuit is
(1) 305 W (2) 210 W (3) Zero W (4) 242 W
Ans. (4)
Page # 17
XL R 200
Sol. tan 30º = XL = =
R 3 3
XC 200
tan 30º = Xc =
R 3
Z= R ( XL XC )2 = 200
220
irms = = 1.1
200
5 r
49. Let there be a spherically symmetric charge distribution with charge density varying as ñ(r ) ñ 0
4 R
upto r = R, and (r) = 0 for r > R, where r is the distance from the origin. The electric field at a distance r (r <
R) from the origin is given by
4ðñ 0r 5 r ñ 0r 5 r 4ñ 0 r 5 r ñ 0r 5 r
(1) (2) (3) (4)
3å 0 3 R 4å 0 3 R 3å 0 4 R 3å 0 4 R
Ans. (2)
5 x
dq = 0 x 4x2 dx
4 R
r
5x 2 x 3
q = 40 dx
0
4
R
5r 3 r 4
q = 40 3 4 4R
kq 1 5r 3 r 4
E= =
× 40 3 4 4R
r2 4 r 2
0r 5 r
E = 4
0 3 R
Page # 18
50. The potential energy function for the force between two atoms in a diatomic molecule is approximately given
a b
by U(x) = 12
, where a and b are constants and x is the distance between the atoms. If the dissocia-
x x6
tion energy of the molecule is D = [U (x = ) – Uat equilibrium], D is
b2 b2 b2 b2
(1) (2) (3) (4)
2a 12a 4a 6a
Ans. (3)
a a
Sol. U= 12 –
X X12
dU 12 a 6b
At equilibrium = 13 + 7 =0
dX x x
1/ 6
2a
x=
b
2
b b
Uat equilibrium = a – b
2a 2a
b b
= 2 b
2a
b2
Uat r =
4a
Uat = 0
b2
D=
4a
51. Two identical charged spheres are suspended by strings of equal lengths. The strings make an angle of 30º
with each other. When suspended in a liquid of density 0.8 g cm–3, the angle remains the same. If density of
the material of the sphere is 1.6 g cm–3, the dielectric constant of the liquid is
(1) 4 (2) 3 (3) 2 (4) 1
Ans. (3)
Sol. At equilibrium
Fe 1 q2 1
tan /2 = mg = 4ð 2 . mg
0 [ sin( è / 2 )]
Page # 19
1 q2 1
tan = 4ð K 2 (mg – F )
2 0 [ sin( è / 2)] B
1 q2 1
= 4ð K 2 . m
0 [ sin( è / 2)] (mg – 0.8 g)
1 .6
0. 8
K 1 – =1 K = 2.
1 .6
52. Two conductors have the same resistance at 0ºC but their temperature coefficients of resistance are 1 and
2. The respective temperature coefficients of their series and parallel combinations are nearly
á1 á 2 á1 á 2 á 1á 2 á1 á 2 á1 á 2
(1) , 1 + 2 (2) 1 + 2 , (3) 1 + 2 , á á (4) ,
2 2 1 2 2 2
Ans. (4)
Sol. Let R be their individual resistance at 0ºC. Their resistance at any other temperature t is
R1 = R (1 + 1 t) and R2 = R (1 + 2 t).
In series
Rseries = R1 + R2 = R [2 +(1 + 2) .t]
1 2
= 2R 1 t .
2
1 2
Series =
2
In Parallel
R 2 (1 1 2 )t )
2
2R(1 1 t)
2
R 1 1 2
t
2 2
1 2
Parallel = .
2
Page # 20
53. A point P moves in counter-clockwise direction on a circular path as shown in the figure. The movement of ‘P’
is such that it sweeps out a length s = t3 + 5, where s is in metres and t is in seconds. The radius of the path
is 20 m. The acceleration of ‘P’ when t = 2 s is nearly.
Sol. S = t3 + 5
Linear speed of the particle
dS
= = 3 t2
dt
at t = 2 s
v = (3 × 22) m/s
= 12 m/s
Linear acceleration
d
a1 = =6t
dt
at t = 2 s,
a1 = 12 m/s2
2 122
a2 = = m/s2
R 20
= 7.2 m/s2
Page # 21
54. Two fixed frictionless inclined planes making an angle 30º and 60º with the vertical are shown in the figure.
Two blocks A and B are placed on the two planes. What is the relative vertical acceleration of A with respect
to B?
(1) 4.9 ms–2 in horizontal direction (2) 9.8 ms–2 in vertical direction
(3) Zero (4) 4.9 ms–2 in vertical direction
Ans. (4)
3
= g sin 60º . sin 60º = g .
4
That for B
1
a2 = g sin 30º . sin 30º = g
4
3g g g
(aAB)= – = = 4.9 m/s2
4 4 2
55. For a particle in uniform circular motion, the acceleration a at a point P (R, ) on the circle of radius R is
(Here is measured from the x-axis)
v2 v2 v2 v2
(1) – cos î + sin ĵ (2) – sin î + cos ĵ
R R R R
v2 v2 v2 v2
(3) – cos î – sin ĵ (4) + ĵ
R R R î R
Ans. (3)
Page # 22
Sol.
V2 V2
aC = – cos î – sin ĵ
R R
medium
Sol.
Beam is incident normally so does not diverge or converge so it travel as a cylindrical beam.
Sol. Beam does not converge or diverge so shape of wave front remain planar.
Page # 23
Sol. = 0 + 2 ()
as it is given that intensity of beam is decreasing with increasing radius, and as decreases also de-
creases.
C
Now by V =
59. A small particle of mass m is projected at an angle with the x-axis with an initial velocity v0 in the x-y plane
v 0 sin è
as shown in the figure. At a time t < , the angular momentum of the particle is
g
1 1
(3) – mg v0 t2 cos k̂ (4) mg v0 t2 cos î
2 2
where î, ĵ and k̂ are unit vectors along x, y and z-axis respectively..
Ans. (3)
Page # 24
Sol.
V0
1 2
Angular momentum = m ( v 0 sin gt )( V0 cos t ) ( V0 cos ) V0 sin t 2 gt
1
=– mg V0 t2 cos 0 k̂
2
60. The equation of a wave on a string of linear mass density 0.04 kg m–1 is given by y = 0.02 (m) sin
t x
2ð . The tension in the string is :
0.04(s) 0.50(m)
Sol. By equation
1
f= and = 0.5
0.04
1 25
V= × 0.5 =
0.04 2
2
T 25 625
by V = = T= × 0.04
2 0.04 4
T = 6.25 N
Page # 25
PART - C (MATHEMATICS)
4 5
61. Let cos( + ) = and let sin( – ) = , where 0 , . Then tan 2 =
5 13 4
56 19 20 25
(1) (2) (3) (4)
33 12 7 16
Ans. (1)
3 5
tan( ) tan( )
4 12 (9 5 )4 14 4 56
Sol. tan 2 = tan (( + ) + ( – )) = = = = =
1 tan( ) tan( ) 3 5 48 15 33 33
1 .
4 12
63. Let a ĵ – k̂ and c î – ĵ – k̂ . Then the vector b satisfying a b c 0 and a . b 3 is
Ans. (4)
Sol. Since a b c 0
a (a b) a c 0
(a . b)a (a . a) b a c 0
Since a c = 2 î ĵ k̂
3( ĵ k̂ ) 2b 2 î ĵ k̂ 0
b î ĵ 2k̂
Page # 26
4
64. The equation of the tangent to the curve y = x + , that is parallel to the x-axis, is
x2
(1) y = 1 (2) y = 2 (3) y = 3 (4) y = 0
Ans. (3)
4
Sol. y=x+
x2
8 4
y = 1 – 3 =0 x3 = 8 x=2 y=2+ =3
x 22
(2, 3) is point of contact . Thus y = 3 is tangent . Hence correct option is (3)
65. Solution of the differential equation cosx dy = y(sinx – y) dx, 0 < x < is
2
(1) y sec x = tan x + c (2) y tan x = sec x + c (3) tanx = (sec x + c)y (4) secx = (tanx + c) y
Ans. (4)
d( y cos x ) dx
2 2 =–
y cos x cos 2 x
1
– y cos x = – tan x + c
– sec x = y (– tan x + c)
sec x = y(tan x + k)
Hence correct option is (4)
3
66. The area bounded by the curves y = cos x and y = sinx between the ordinates x = 0 and x = is
2
Ans. (4)
/4 5 / 4 3 / 2
/4 5 / 4
= 2 sin x cos x 0 + cos x – sin x / 4 = 4 2 – 2
Hence correct option is (4)
Page # 27
67. If two tangents drawn from a point P to the parabola y2 = 4x are at right angles, then the locus of P is
(1) 2x + 1 = 0 (2) x = – 1 (3) 2x – 1 = 0 (4) x = 1
Ans. (2)
Sol. Locus of P will be directrix of parabola which is x = – 1
Hence correct option is (2)
68. If the vectors a î – ĵ 2k̂ , b 2 î 4 ĵ k̂ and c î ĵ µk̂ are mutually orthogonal, then ( , µ) =
and
b.c 0 + 4 + = 0 ........(ii)
m p
S = { , | m, n, p and q are integers such that n, q 0 and qm = pn}
n q
Then
(1) neither R nor S is an equivalence relation
(2) S is an equivalence relation but R is not an equivalence relation
(3) R and S both are equivalence relations
(4) R is an equivalence relation but S is not an equivalence relation
Ans. (2)
Sol. (x, x) R for w = 1
R is reflexive
If x 0, then (0, x) R for w = 0 but (x, 0) R for any w
R is not symmetric
R is not equivalence relation
m m
, S as mn = mn
n n
S is reflexive
m p
, S qm = pn np = mq
n q
p m
, S
q n
S is symmetric
m p p a
, S and , S
n q q b
Page # 28
qm = pn and bp = aq
m p p a m a m a
= and = = , S
n q q b n b n b
S is transitive
S is equivalence
Hence correct option is (2)
k – 2 x , if x –1
f(x) =
2x 3 , if x –1
1
(1) 0 (2) – (3) –1 (4) 1
2
Ans. (3)
f(–1) = k + 2
lim f(x) = k + 2
x ( 1)
71. The number of 3 × 3 non-singular matrices, with four entries as 1 and all other entries as 0, is
(1) 5 (2) 6 (3) at least 7 (4) less than 4
Ans. (3)
a1 a 2 a3
Sol. Let A = b1 b 2 b3
c 1 c 2 c 3
Page # 29
Directions : Question number 72 to 76 are Assertion-Reason type questions. Each of these questions
contains two statements.
Statement - 1 : (Assertion) and
Statement - 2 : (Reason).
Each of these questions also has four alternative choices, only one of which is the correct answer. You have
to select the correct choice.
72. Four numbers are chosen at random (without replacement) from the set {1,2,3,.....,20}.
Statement -1 : The probability that the chosen numbers when arranged in some order will form an AP is
1
.
85
Statement -2 : If the four chosen numbers form an AP, then the set of all possible values of common
difference is {±1, ±2, ±3, ±4, ±5}
(1) Statement -1 is true, Statement-2 is true ; Statement -2 is not a correct explanation for Statement -1.
(2) Statement-1 is true, Statement-2 is false.
(3) Statement -1 is false, Statement -2 is true.
(4) Statement -1 is true, Statement -2 is true; Statement-2 is a correct explanation for Statement-1.
Ans. (2)
20
Sol. Statement-1 Total ways = C4
number of AP's of common difference 1 is = 17
number of AP's of common difference 2 is = 14
number of AP's of common difference 3 is = 11
number of AP's of common difference 4 is = 8
number of AP's of common difference 5 is = 5
number of AP's of common difference 6 is = 2
_______
total = 57
57 1
probability = 20 =
C4 85
73. Statement -1 : The point A(3, 1, 6) is the mirror image of the point B(1, 3, 4) in the plane x – y + z = 5.
Statement -2 : The plane x – y + z = 5 bisects the line segment joining A(3, 1,6) and B(1, 3, 4).
(1) Statement -1 is true, Statement-2 is true ; Statement -2 is not a correct explanation for Statement -1.
(2) Statement-1 is true, Statement-2 is false.
(3) Statement -1 is false, Statement -2 is true.
(4) Statement -1 is true, Statement -2 is true; Statement-2 is a correct explanation for Statement-1.
Ans. (1)
Sol. Let image be ()
1 3 4 1 3 4 5
= = =–2
1 1 1 3
1 3 4
= = =2
1 1 1
Page # 30
= 3, = 1, = 6
A(3, 1, 6) statement 1 is true
Now midpoint of A(3, 1, 6) and B(1, 3, 4) is (2, 2, 5)
equation of plane is x – y + z = 5
coordinates of midpoint lies on the plane so plane bisects the line segment AB. But it is not correct explana-
tion of statement-1
Hence correct option is (1)
10 10 10
2 10
74. Let S1 = j ( j – 1)
j 1
10
Cj , S2 = j j 1
10
Cj and S3 = jj 1
C.j
Statement -1 : S3 = 55 × 29 .
Statement -2 : S1 = 90 × 28 and S2 10 × 28.
(1) Statement -1 is true, Statement-2 is true ; Statement -2 is not a correct explanation for Statement -1.
(2) Statement-1 is true, Statement-2 is false.
(3) Statement -1 is false, Statement -2 is true.
(4) Statement -1 is true, Statement -2 is true; Statement-2 is a correct explanation for Statement-1.
Ans. (2)
10
10(10 1) 8
Sol. S1 = j( j 1) . Cj–2
j 1
j ( j 1)
10
8
S1 = 9 × 10 C j2
j2
S1 = 90 . 28
10
10 9
S2 = j.
j 1
j
C j –1 = 10.29
10 10 10 10 10
10 10 10 8 9
S3 = ( j( j 1) j) Cj = j( j 1) Cj j C j = 90 C j2 10 C j1
j 1 j 1 j 1 j2 j 1
75. Let A be a 2 × 2 matrix with non-zero entries and let A2 = I, where I is 2 × 2 identity matrix. Define
Tr(A) = sum of diagonal elements of A and |A| = determinant of matrix A.
Statement -1 : Tr(A) = 0
Statement -2 : |A| = 1
(1) Statement -1 is true, Statement-2 is true ; Statement -2 is not a correct explanation for Statement -1.
(2) Statement-1 is true, Statement-2 is false.
(3) Statement -1 is false, Statement -2 is true.
(4) Statement -1 is true, Statement -2 is true; Statement-2 is a correct explanation for Statement-1.
Ans. (2)
Page # 31
a b
Sol. Let A =
c d
a b a b a 2 bc b(a d) 1 0
2
A = = 2 =
c d c d c(a d) bc d 0 1
a+d=0 and a2 + bc = 1
Tr(A) = 0
Statement-1 is true
Statement-2 |A| = ad – bc = – a2 – bc = – 1
Statement-1 is true statement-2 is false.
Hence correct option is (2)
1
f(x) = .
e 2e – x
x
1
Statement -1 : f(c) = , for some c R.
3
1
Statement -2 : 0 < f(x) , for all x R.
2 2
(1) Statement -1 is true, Statement-2 is true ; Statement -2 is not a correct explanation for Statement -1.
(2) Statement-1 is true, Statement-2 is false.
(3) Statement -1 is false, Statement -2 is true.
(4) Statement -1 is true, Statement -2 is true; Statement-2 is a correct explanation for Statement-1.
Ans. (4)
1 1
e x 2e x 2 2
1
f(x) > 0 so statement- 2 is correct
2 2
1 1
so f(c) = for some c. because f(x) is continuous [since f(0) = ]
3 3
77. For a regular polygon, let r and R be the radii of the inscribed and the circumscribed circles. A false statement
among the following is
r 1 r 2
(1) There is a regular polygon with R . (2) There is a regular polygon with .
2 R 3
r 3 r 1
(3) There is a regular polygon with . (4) There is a regular polygon with .
R 2 R 2
Ans. (2)
Page # 32
r
Sol. = cos
R n
2
Let cos = for some n 3, n N
n 3
1 2 1
As cos cos cos
2 3 2 3 n 4 3 n 4
3 n < 4, which is not possible
so option (2) is the false statement
so it will be the right choice
78. If and are the roots of the equation x2 – x + 1 = 0, then 2009 + 2009 =
(1) – 1 (2) 1 (3) 2 (4) –2
Ans. (2)
x2 – x + 1 = 0
x = – , –2
2009 + 2009 = –2009 – 4018 = – 2 – = 1
Hence correct option is (2)
80. A line AB in three-dimensional space makes angles 45º and 120º with the positive x-axis and the positive y-
axis respectively. If AB makes an acute angle with the positive z-axis, then equal
(1) 45º (2) 60º (3) 75º (4) 30º
Ans. (2)
1 1
Sol. = , m=–
2 2
2 + m2 + n2 = 1
1 1
n2 = n=±
4 2
1
cos = , = 60º
2
Hence correct option is (2)
Page # 33
x y
81. The line L given by = 1 passes through the point (13, 32). The line K is parallel to L and has the
5 b
x y
equation = 1. Then the distance between L and K is
c 3
17 23 23
(1) 17 (2) (3) (4)
15 17 15
Ans. (3)
x y
Sol. + =1
5 b
13 32 32 8
+ =1 =– b = – 20
5 b b 5
x y
– =1 4x – y = 20
5 20
3
Line K has same slope – =4
c
3
c=– 4x – y = – 3
4
23
distance =
17
82. A person is to count 4500 currency notes. Let an denote the number of notes he counts in the nth minute. If
a1 = a2 = .....= a10 = 150 and a10, a11,....are in an AP with common difference –2, then the time taken by him
to count all notes is
(1) 34 minutes (2) 125 minutes (3) 135 minutes (4) 24 minutes
Ans. (1)
Sol. a1 + a2 + .... + an = 4500 notes
As a1 + a2 + .... + a10 = 150 × 10 = 1500 notes
a11 + a12 + ..... + an = 3000
148 + 146 ...... = 3000
(n 10)
[2 × 148 + (n – 10 – 1) (–2)] = 3000
2
n = 34, 135
a34 = 148 + (34 – 1) (–2) = 148 – 66 = 82
a135 = 148 + (135 – 1) (–2) = 148 – 268 = – 120 < 0
so answer in 34 minutes is taken
Hence correct option is (1)
Page # 34
f (3 x ) f ( 2x )
83. Let f : R R be a positive increasing function with xlim = 1. Then xlim .
f(x) f ( x )
2 3
(1) (2) (3) 3 (4) 1
3 2
Ans. (4)
f (3 x )
Sol. lim =1
x 0 f ( x)
f ( 2 x ) f (3 x )
1
f(x) f ( x)
f (2x )
using sandwitch theorem lim =1
x f ( x)
Hence correct option is (4)
84. Let p(x) be a function defined on R such that p(x) = p(1 – x), for all x [0, 1], p(0) = 1 and p(1) = 41. Then
p( x) dx equals
0
1 1
= p( x) dx ; = p(1 x) dx
0
0
1 1 1
c dx 42 dx
2 = (p( x) p(1 x )) dx =
0 0 0
2 = 42 = 21
Hence correct option is (1)
85. Let f : (–1, 1) R be a differentiable function with f(0) = – 1 and f(0) = 1. Let g(x) = [f(2f(x) + 2)]2. Then g(0).
(1) – 4 (2) 0 (3) – 2 (4) 4
Ans. (1)
Sol. g(x) = 2f(2f(x) + 2) . f (2f(x) + 2) . 2f(x)
g(0) = 2f (2f(0) + 2) f (2f(0) + 2) . 2f(0)
= 2f(0) f(0) 2f(0) = (2) (–1) (1) (2) (1) = – 4
Hence correct option is (1)
Page # 35
86. There are two urns. Urn A has 3 distinct red balls and urn B has 9 distinct blue balls. From each urn two balls
are taken out at random and then transferred to the other. The number of ways in which this can be done is
(1) 36 (2) 66 (3) 108 (4) 3
Ans. (3)
3
98
Sol. C2 × 9 C2 = 3 × = 12 × 9 = 108
2 1
Hence correct option is (3)
88. An urn contains nine balls of which three are red, four are blue and two are green. Three balls are drawn at
random without replacement from the urn. The probability that the three balls have different colours is
2 1 2 1
(1) (2) (3) (4)
7 21 23 3
Ans. (1)
3.4.2
3
C1 4 C1 2 C1 9.8.7 2
Sol. = 9 = =
C3 3 . 2 .1 7
89. For two data sets, each of size 5, the variance are given to be 4 and 5 and the corresponding means are given
to be 2 and 4, respectively. The variance of the combined data set is
11 13 5
(1) (2) 6 (3) (4)
2 2 2
Ans. (1)
Page # 36
2
xi
2
x i2
Sol. x = 4 – n =4
n
2
xi
– (2)2 = 4 xi2 = 40
5
2 2 2 2
2
xi yi xi yi 145 10 20
= – = – = 5.5
10 10 10 10
Ans. (1)
Sol. r= 4 16 5 = 5
6 16 m
<5
5
Page # 37