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The Mannich Reaction - Org Rxn (Vol 01 - Chap 10) - Ff Blicke - Pg 303-341

The Mannich Reaction - Org Rxn (Vol 01 - Chap 10) - Ff Blicke - Pg 303-341

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Published by jtjdp4
Article/Chapter Title: The Mannich Reaction
Text/Book: Organic Reactions, Volume 01 -- Chapter 10 -- Pgs 303-341
Author: F.F. Blicke
Pages: 303-341

CONTENTS:
Scope of the Mannich Reaction
Use of Secondary Amines
Ketones, aldehydes, acids, esters, phenols, acetylenes, alpha-picolines, quinaldines,
Use of Primary Amines
Use of Ammonia
Related Reactions
Application of the Mannich Reaction in Synthesis
Unsaturated Compounds
Preparation of Ethylenic Compounds, Pyrazolines
Use of Mannic Base as a source of unsaturated ketone for condensation with an active methylene compound
Conversion of a ketone to its next higher homolog
syntheses dependent on the active methylene group in the Aminoketone
Syntheses dependent on the activity of the Dimethylamino group in the Dimethylaminomethylphenols
Reduction of Aminoalcohols
Products derived by transformation of the aldehyde group in Beta-Diakylaminoaldehydes
Beta-Monoalkylaminoketone Condensation Products
Condensation Products from one mole of a primary amine, two moles of formaldehyde, and two moles of ketone
Experimental conditions and procedures
Solvents
Nature of Formaldehyde & Time of Reaction
Relative Amounts of Components
Isolation of Product
By-Products
Procedures
Phenyl Beta-piperidinoethyl Ketone Hydrochloride
1-Keto-2-(1,2,3,4-tetrahydroisoquinolinomethyl)-1,2,3,4-tetrahydronapthalene
2,4,6-Tri-(dimethylaminomethyl)-phenol
Examples of the Mannich Reaction
Article/Chapter Title: The Mannich Reaction
Text/Book: Organic Reactions, Volume 01 -- Chapter 10 -- Pgs 303-341
Author: F.F. Blicke
Pages: 303-341

CONTENTS:
Scope of the Mannich Reaction
Use of Secondary Amines
Ketones, aldehydes, acids, esters, phenols, acetylenes, alpha-picolines, quinaldines,
Use of Primary Amines
Use of Ammonia
Related Reactions
Application of the Mannich Reaction in Synthesis
Unsaturated Compounds
Preparation of Ethylenic Compounds, Pyrazolines
Use of Mannic Base as a source of unsaturated ketone for condensation with an active methylene compound
Conversion of a ketone to its next higher homolog
syntheses dependent on the active methylene group in the Aminoketone
Syntheses dependent on the activity of the Dimethylamino group in the Dimethylaminomethylphenols
Reduction of Aminoalcohols
Products derived by transformation of the aldehyde group in Beta-Diakylaminoaldehydes
Beta-Monoalkylaminoketone Condensation Products
Condensation Products from one mole of a primary amine, two moles of formaldehyde, and two moles of ketone
Experimental conditions and procedures
Solvents
Nature of Formaldehyde & Time of Reaction
Relative Amounts of Components
Isolation of Product
By-Products
Procedures
Phenyl Beta-piperidinoethyl Ketone Hydrochloride
1-Keto-2-(1,2,3,4-tetrahydroisoquinolinomethyl)-1,2,3,4-tetrahydronapthalene
2,4,6-Tri-(dimethylaminomethyl)-phenol
Examples of the Mannich Reaction

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Categories:Types, Research, Science
Published by: jtjdp4 on Jun 02, 2010
Copyright:Attribution Non-commercial

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02/15/2013

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