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Intelligent Maturity Cure Prediction Model (IMCPM) For Polymer Matrix Composite Curing
Intelligent Maturity Cure Prediction Model (IMCPM) For Polymer Matrix Composite Curing
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Abstract—In this paper, a novel Intelligent Maturity Cure Prediction Model(IMCPM) is designed to predict the mature cure rate
and temperature required for ideal curing of composite materials. Pre defined knowledge discovery models and numerical
simulation models are integrated as an Intelligent Maturity Cure Prediction Model (IMCPM) for predicting and analysis of cure
status that has inherently associated with polymer matrix, reinforcement fiber and the pultrusion process conditions. Polymer
resign matrix and reinforcement fiber properties satisfying the composite component are revealed by the data mining/knowledge
discovery models. The experimentally determined process conditions are defined in the knowledgebase of the proposed system
for improving decision making performance. The maturity cure status of composite materials is analyzed with kinetic model and
heat governing partial differential equation. IMCPM is a knowledge based prediction model, which incorporates heat transfer
and resin kinetic models coupled with materials database, knowledgebase of prerequisite processing strategies, and knowledge
discovery models for the prediction of polymer resign and reinforcement fiber satisfying the composite component. It predicts
optimal cure rate and temperature imperative for the ideal curing of epoxy resin impregnated composites, preventing part
overheating while maintaining maximum cure heat up rate. This results in a significant reduction in total cure time over standard
methods. The system uses a cure process model to determine optimal cure profiles for tool/part configurations of varying
thermal characteristics. These profiles indicate the heating and cooling necessary to insure a complete cure of part in the
pultrusion in the minimum amount of time. The model is shown to be a particularly convenient method for examining the
qualitative aspects of various process scenarios prior to running the pultruder.
Index Terms- Intelligent Cure Model, Polymer Matrix Composite, Pultrusion Technology.
—————————— ——————————
1. INTRODUCTION
Cure is a process which converts a liquid mixture into The currently using black box approach for cure
a solid by means of a physical process or more usually processing [3] is based on a rigorous compliance to the
by means of a chemical reaction, which is often supplier’s recommended schedule assumptions that
activated by heat. Various techniques for cure analysis are made about the material state, curable time
are used to improve processing efficiency for quality schedules and materials properties. Thus, a rigid set of
assurance of composite materials, to study cure processing conditions (temperature and pressure) are
process to prevent wastage due to failure of resign to adhered to, based on assumed material behavior
react, to predict incorrect proportion of resign before, during and after cure, where conservative cure
components and to avoid poor mixing of resign, or times are used, including safety and quality
incorrect processing conditions. There is a diverse considerations. Thus require optimization of cure
range of materials that can undergo cure [15] with a process to avoid material degradation and improve the
number of manufacturing process involving either material performance.
discrete or continuous part production. The major
manufacturing process such as Spray Lay-Up, Wet Design of optimal cure temperature cycle is an
Lay-Up/Hand-Lay Up, Vacuum Bagging, Filament imperative and active research area [3],[4],[5] for low-
Winding, Pultrusion, Resign Transfer, Molding (RTM), cost of manufacturing matrix composites and several
Injection Molding (IM), Prepeg, Resign Film Infusion, research attempts have been made to design optimal
Autoclaving and etc, involve the curing process with
cure cycles. Knowledge based expert system was
environmental conditions, tooling requirements and
developed to analyse cure cycles of thick polymer
part access.
matrix composites [6]. Numerical simulation together
with knowledge of curing process for thin laminate
was developed to determine the cure cycle for thick
laminates [7].
————————————————
# Post-Graduate Department of Studies and Research in Computer Science
Mangalore University, Mangalagangotri-574 199, Karnataka, INDIA
2. INTELLIGENT MATURITY CURE PREDICTION The basic curing process shown in the figure 1 is
same in each manufacturing process. The polymer
MODEL
matrix resign usually with low viscosity and the fiber
Intelligent Maturity Cure Prediction Model (IMCPM) reinforcement with high viscosity are mixed to form
is a knowledge based prediction model which liquid composite mixture at gel state filled with cavity
incorporates heat transfer and resin kinetic models[13] of the curing chamber. The cure process progresses
coupled with materials database[ 15], knowledgebase with increase in the number and density of 3-D
of prerequisite processing strategies, and knowledge structural cross-links follows until finally the material
discovery models for the prediction of polymer resign achieves solid state [1]. At this point the material is
and reinforcement fiber satisfying the composite usually a hard, glassy solid with a glass transition
component. It predicts optimal cure rate and temperature higher than the cure temperature and no
temperature imperative for the ideal curing of epoxy further cure reaction can be achieved at the chosen
resin impregnated composites, preventing part cure temperature. This marks the end of cure. At this
overheating while maintaining maximum cure heat up point a particular degree of cure has been achieved,
rate. This results in a significant reduction in total cure defined as the percentage of unreached species
time over standard methods. The system uses a cure conversion as compared to a fully cured material. A
process model to determine optimal cure profiles for fully cured material has undergone as much reaction
tool/part configurations of varying thermal as possible such that further temperature increases or
characteristics. These profiles indicate the heating and cure duration will not achieve further reaction.
Continue heating of cured material may result in
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degradation of the cured solid with a reduction in Pultrusion study is increasingly important in many
cross-links and a corresponding loss in performance. applications in manufacturing industries in these days.
Therefore, it has been an active research area.
3. MODELLING AND SIMULATION OF MATURITY Numerous research efforts have also been undertaken
CURE ANALYSIS to model and numerically simulate the thermal and
One of the most cost-effective manufacturing methods curing characteristics by different approaches and
for polymer composites is pultrusion and is typically focuses on transient and steady state problems such as
used for high volume production on traditional one dimensional, two dimensional, or three
composite structure applications. Pultrusion process dimensional and a variety of resign systems. Two main
involves numerous variables that affect the quality and numerical methods have been used in the literature to
mechanical properties of the finished products. These simulate the heat transfer and curing process: finite
variables include pulling speed, dies wall temperature element method and finite difference method [17],[18].
profile, die length, filler and fiber type, fiber volume 3.1 Heat Transfer Model
fraction, fiber/resign wet-out and the kinetic
A numerical model for curing system has been
properties of the resign and etc. The die temperature
implemented to simulate heat transfer in and cure of
and line speed are two most important process
polymer matrix composite. In this work, a thin
variables for a specific resign/fiber system.
rectangular cross section profile is pultruded. A three
Inadequate or excessive heating and improper pulling
dimensional model is applied for simulating the
speed will result very poor product performance or
temperature and degree of cure along the length of
even failure.
resign. Cartesian coordinates are used to describe the
systems. The energy balance equation [16] with
The pultrusion process begins when reinforcing
chemical reaction from resign acts as a source term is
fibers are pulled from a series of creels. The fibers pass
expressed as follows
through a bath, where they are impregnated with
formulated polymer resin. The resin-impregnated
Heat in Heat Heat Change in
fibers are preformed to the shape of the profile to be flow genearted leaving int erval (1)
produced. This composite material is then passed
in with in the the body energy
through a heated steel die that has been machined
precisely to the final shape of the part to be time dt body in dt in time dt during dt
manufactured. Heat initiates an exothermic reaction
thus curing the thermosetting resin matrix. The profile The basic assumption of the model are [14]
is continuously pulled and exits the mould as a hot, 1. The pultrusion is steady state process with a fixed
constant cross sectional member. The profile cools in line speed
ambient or forced air, or assisted by water. The 2. The matrix and fiber have perfect bonding and the
product emerges from the puller mechanism and is cut same temperature every where
to the desired length by an automatic and flying cutoff 3. The velocity of composite in the radial and
saw. transverse directions is zero.
The governing differential equation of heat for
Polymer matrix resign and reinforcement fiber measuring rate of heat generated in the composite
properties required in the modelling process include material is given in Cartesian coordinate
composed density, specific heat, thermal conductivity,
heat of reaction[12], pre-exponential constant, 1 T T T T
Hs (2)
t x x y y z z
activation energy, heat of reaction and order of
reaction are the retrieved properties from the materials
property data space and the polymer matrix composite
properties are predicted by “Rule-Of-Mixture” model. kc
Where , thermal diffusivity, T is the
c Cc v
temperature of the polymer matrix composite, v is the
velocity of the composite of axial direction,
c v f f (1 v f )m
,
Cc v f f C f (1 v f ) m C p
,
kl v f k f (1 v f )km (3)
Figure 2. Schematic diagram of pultrusion technology
are the bulk density, specific heat, longitudinal,
thermal conductivity, transverse thermal conductivity
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and total thermal conductivity of polymer matrix They include the given temperature and the degree of
composite, respectively The variable x, y and z cure at boundaries. At the entrance of the resign both,
represent three Cartesian coordinates. The degree of the polymer matrix composite temperature T0 is zero.
cure is a function of temperature and also of the The temperature at the entrance of the heater is Th , the
position of the steady state. The velocity of the initial degree of cure is zero as uncured liquid. The
composite in the axial direction is equal to pulling boundary conditions can be expressed as
speed U.
T(x=0, y, z) - T0; T(x=L,y=d,z= w)- Th;
3.2 Cure Model
( x 0, y, z ) 0 ; (7)
The curing behaviour of polymer matrix (resign)
involved in pultrusion is governed by a complex
The outflow boundary condition exists at the outlet
exothermic chemical reaction. Attempts have been
made to describe the relationship among temperature, where the cured composite exits from pultrusion
degree of cure and rate of cure using appropriate chamber. The axial gradient along the longitudinal
model [11],[14]. Heat propagated with polymer resign direction is assigned zero.
and heat generated due to the polymer matrix
exothermic reaction influences and dominates the
dT
polymerization of polymer matrix composite. The heat 0 (8)
source term in the governing differential equation can dx x L
be expressed as:
d
Optimal C ure Temapartre t o H s v f H t (4) The adiabatic boundary conditions set on x and z
dt
directions are
Ht is where the total of the heat of reaction;
d dT dT
is the rate of cure 0; 0 (9)
dt dy y 0
dz z 0
For modelling of the polymer matrix cure kinetics, the
d
rate of cure reaction 0 if 1 and
3.4 Maturity Cure Model
dt
negligible The maturity cure ( M c ) of the polymer composite is
defined as the optimal temperature required for cross
Hence, Arrhenius-type equation [215] is modified to
linking of molecules in the polymer matrix composite
d to develop optimal strength of the polymer matrix
approximate cure rate , 1 .
dt composite. However, in transient thermal condition,
temperature (T) varies simultaneously with time (t)
d EA during pultrusion process and hence the total cure will
K 0 exp (1 (1 ) )
n
(5)
dt RT be a function of both T and t.
EA
t
1
Where K 0 represents pre-exponential constant, EA Mc K 0 exp (1 (1 ) n ) dt (10)
represents the activation energy, R is the universal gas 0
v RT
constant, T is absolute temperature of composites and
n is the order of equation. 4 .EXPERIMENTAL RESULTS
The simulation results of the proposed models are
Since pultrusion is a steady state process, time is
analyzed with composite properties computed from
depended variable. The speed of the traveling along the
the epoxy resign and glass fiber properties discovered
resign bath is equal to the line speed and the speed in
other direction can be thought as zero. Thus time is only a by knowledge discovery models based on the input
function of x, the concentration of the resign species design properties. The computed composite properties
governed by the species equation for degree of cure and the discovered materials are listed in table 1. Heat
source temperature determined by finite element
d 1 d
(6) procedure and the thermal process conditions defined
dx v dt for pultrusion process in the knowledgebase are listed
in table 2.
3.3 Boundary and Initial Conditions
The impregnate fiber package by formed by
Boundary and initial conditions are required in preformed called fiber arrangement plates, before
ordered to solve the heat transfer governing equation. entering into die, which is made of chrome-plated steel
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and multiple pieces depending on the cross section the die wall. Figure 6 shows that the ideal temperature
geometry of the rectangular shape product. The cavity required for ideal curing of composite material
proposed for manufacturing the rectangular shape increases with increases of fiber volume fraction, heat
composite is 2 inch wide, 0.125 inch thick and 36 inch source and pulling speed.
long and its boundary initially conditions T=100 0C and
Tw = 120 0 0C. The rate of cure of composite material with
pultrusion technology depends on the exothermic
TABLE 1 chemical reaction and the thermal dipusitivity during
RETRIEVED POLYMER MATRIX AND REINFORCEMENT FIBER reaction. Thermal dipusitivity depends on the volume
PROPERTIES FROM THE MATERIALS DATABASE AND THE fraction of composite such that Vm + Vf = 1.0. The
COMPUTED POLYMER MATRIX COMPOSITE PROPERTIES maturity cure with the varying polymer resign volume
fraction at different time events and the corresponding
Polymer Volume Density Specific Thermal Thermal thermal dipusitivity are plotted in the graph shown in
Matrix Fraction (Kg/M3) Heat Conductiv Dipusitivity Figure 7. The rate of thermal dipusion of polymer and
/fiber/ (J/Kg.K) ity ( ) fiber molecules increases with increases of polymer
Matrix (W/M.K) resign molecules and is similar to the exponential
Composite growth of maturity cure. The maturity state ideal as
Epoxy 0.56 1255.0 670.0 0.2 long as the enough resign volume fraction and it
Resign recycles back to staring degradation point when the
Fiber Glass 0.44 670.0 1255.0 1.04 resign volume fraction falls within certain threshold
5.53497E-09
Composite 1.0 682.5 594457.5 2.2456335 value.
Material
Table 3 shows the predicted temperature ranges,
During pultrusion, the fiber resign package is cure ranges, ideal temperature and ideal cure state for
continuously pulled through the heated die. The heat is different values of fiber volume fraction and heat
transferred from the high temperature die wall to fiber- source and pulling speed. Table 4 shows maturity cure
resign bundle and it starts an exothermic chemical temperature computed for different values of
reaction to initiate the resign to start curing. Figure 3 predicted optimal temperature, resign volume fraction,
shows the decrease of heat generated and flow and the optimal heat source and pulling speed
increase of rate of cure composite material cross linking
of composite materials during exothermic chemical
reaction. If the rate of cure increases with decreases of TABLE 2
heat flow respect to time, the composite material is curing PREDEFINED PROCESS CONDITIONS IN THE
with the deformation of mechanical properties. Hence, an KNOWLEDGEBASE
optimal cure rate to balance the heat generated and the
fixed die wall temperate is essential to avoid deformation Parameters Symbol Data Units
of composite material during curing. It shows the ideal Pre-Exponential Constant K0 2.50E+05 S-1
temperature and cure rate ranges enclosed the optimal
cure rate and optimal temperature required for cross
Activation Energy E A 64.0 KJ/Mol.
linking of composite molecules for avoiding the Heat of Reaction Ht 375.0 KJ/Kg
deformation of composite molecules cross linking. Figure
Order of Reaction n 1.69 --
4 shows the rate of cure of composite materials with
Gas Constant R 8.314 J/K/Mol.
respect to time for different pulling speed along x
direction. The rate of cure decreases with time as the Heat Source Hs 38.0 Degree C
pulling speed of fiber increases. The optimal cure rate
and the optimal temperature will be different for
different pulling speed of fibers.
O p ti m a l C u r e R a te P r e d i c te d
0 .0 0 2 5
Rate of Cure with varying Temparture
LBC R V U BC R V OC R V
0.025 38
Degree of Cure Temparture
0.022581142
0.022543549
0.022502268
0.02245673
0.022406241 0.022676156
0.022647082
0.022615522 0 .0 0 2
0.022349946
0.022286783
0.022215414
0.022134129
0.021932216
0.021652628
36.94674448 0.021239915 37
0.020569466
0.02 0.020048378
0.019291391
36 0 .0 0 1 5
35.72570125
C ure Rate
0.015914211
0.015
Degree of Cure
Temparture
35
34.65801575 0 .0 0 1
0.010829994
33.94880787 34
0.01 33.78984069
33.68041204
33.53961792
33.45294815
33.39423471
33.35183294
33.33476314
33.31977564
33.3065114
33.29468941
0 .0 0 0 5
33.2840866
33.27452364
33.26585474
33.25796011
33.25074048
33.24411283
33.23800722
33
0.005 0.005015502
32 0
5 8 10 12 14 16 18 20 22
0 31 35 40 45 50 55 65 70 75 80
5 10 20 40 50 60 80 100 120 140 150 160 170 180 190 200 210 220 230 240 250
0 .1 5 0 .2 5 0 .3 5 0 .4 5 0 .5 5 0 .6 5 0 .7 5 0 .8 5 0 .9 5
Time
D i f fe r e n t V a l u e s o f V , H S a n d V f
T e m p . D e g re e C
40 3 9 .1 8 3
3 7 .5 7
0.002 cure with v = 10 cure with v= 15 3 3 .0 2
cure with v = 20 cure with v = 25 30
20
Cute0.0015
Rate
10
0.001 0
35 40 45 50 55 65 70 75 80
0.0005 5 8 10 12 14 16 18 20 22
0 .1 5 0 .2 5 0 .3 5 0 .4 5 0 .5 5 0 .6 5 0 .7 5 0 .8 5 0 .9 5
0
5 10 20 40 50 60 80 100 120 140 150 160 170 180 190 200 210 220 230 240 250
V a r y in g H e a t S o u r c e ( H S ) , P u llin g S p e e d ( V ) a n d F ib e r V o lu m e F r a c t io n ( V f )
Time(Miniutes)
Figure 4. Shows the cure rate for different pulling speeds with
varying time
M a tu ri ty C u re D e pe n ds V o l u m e F ra cti o n o f R e s i g n
1 .4 1 .0 0 0 0 0 E - 0 8
M a tu r i ty C u r e
T h e r m a l D i p u s i ti v i ty 9 .0 0 0 0 0 E - 0 9
1 .2
8 .0 0 0 0 0 E - 0 9
1 7 .0 0 0 0 0 E - 0 9
6 .0 0 0 0 0 E - 0 9
0 .8
T h e r m a l D ip u s it iv it y
M a t u r it y C u r e
5 .0 0 0 0 0 E - 0 9
0 .6
4 .0 0 0 0 0 E - 0 9
0 .4 3 .0 0 0 0 0 E - 0 9
2 .0 0 0 0 0 E - 0 9
0 .2
1 .0 0 0 0 0 E - 0 9
0 0 .0 0 0 0 0 E + 0 0
0 .8 5 0 .7 5 0 .6 5 0 .5 5 0 .4 5 0 .3 5 0 .2 5 0 .1 5 0 .0 5
5 10 15 20 25 30 35 40 45
R e s ig n V o lu m e F r a c t io n a n d V a r y in g T im e
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TABLE 3
SIMULATED RESULTS APPROXIMATE CUTE TEMPARATURE OBTAINED FOR DIFFERENT VALUES OF VOLUME FRACTIONS OF FIBER AND
HEAT SOURCE AND PULLING SPEED
Fiber Heat Velocity of Thermal Predicted Predicted Approximate Approximate
Volume Source Pulling dipusitivity Cure range Temperature Cure point Curing
Fraction Computed Speed Computed Range Temperature
0.15 35 5 3.55404E-09 ( 0.001524, 0.0021234 ) ( 32.545 ,33.532 ) 0.00185 33.02
0.25 40 8 4.09088E-09 ( 0.001098, 0.0014743) ( 37.522, 38.315 ) 0.00145 37.57
0.35 45 10 4.66810E-09 ( 0.001791, 0.0018261) ( 39.165 ,46.238) 0.00176 39.18
0.45 50 12 5.30045E-09 ( 0.000864, 0.0012694) ( 46.822 ,49.799 ) 0.00111 47.82
0.55 55 14 6.06720E-09 ( 0.000839, 0.0012333) ( 51.945 ,52.925) 0.00119 52.67
0.65 65 16 6.81192E-09 ( 8.12717E-05, 0.0001294 ) ( 55.884 ,57.024 ) 0.00014 56.33
0.75 70 18 7.75067E-09 ( 0.0008425, 0.001231) ( 60.230 ,61.815 ) 0.00089 60.45
0.85 75 20 8.87283E-09 ( 0.0008680, 0.001273) ( 64.641 ,66.354 ) 0.00099 65.12
0.95 80 22 1.02538E-09 ( 0.000134, 0.0001634) ( 74.219 ,74.249 ) 0.00015 74.38
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TABLE 4
MATURITY CURE COMPUTED FOR DIFFERENT VOLUME FRACTIONS OF RESIGNS, OPTIMAL
HEAT SOURCE, PULLING SPEED AND FOR PREDICTED OPTIMAL TEMPERATURE.
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