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The pKa of esters is about 25, thus the ester enolates behave as
strong bases. Side reactions include E2 processes and
deprotonations.
20-5 Esters in Nature: Waxes, Fats, Oils, and Lipids
Waxes are simple esters, whereas fats and oils are
more complex.
Waxes are esters containing a long-chain carboxylic acid and a
long-chain alcohol.
Waxes are found in nature as hydrophobic and insulating coatings
on skin, fur, feathers, fruits and leaves.
Some waxes are liquid or very soft at room temperature and are
used as lubricants (spermaceti, beeswax).
5. Natural Products –
• Waxes – Long-chain esters.
• Oils and Fats – Triesters of glycerol
• Hydrolysis yields soaps.
• Phospholipids – Triglycerides containing phosphoric
acid ester subunits.
• From micelles and lipid bilayers due to polar head and
hydrophobic tail.
6. Transesterification – Used to convert one ester
into another.
20 Important Concepts