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Alkanes_ Alkenes_ Alkynes _dpp 3

Alkanes_ Alkenes_ Alkynes _dpp 3

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04/27/2014

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ABC CLASSES
126,2
nd
Floor , Kingsway Camp, Delhi-110009,Ph.No:011-47041845.
 
ABC CLASSES FOR IIT-JEE
A
LKANES,
A
LKENES,
A
LKYNES Home Assignment-1
 
1.
 
Me CH = CH
2
on reaction with BrCl gives (A) and with NOCl gives (B). (A) and (B) are :(a) MeCH Cl CH
2
Br, MeCH (Cl) CH
2
NO (b) Me CHCl CH
2
Br, Me CH (NO) CH
2
Cl(c) Me CHBr CH
2
Cl, MeCH Cl CH
2
NO (d) MeCH Br CH
2
Cl, Me CH (NO) CH
2
Cl.2.
 
An alkene (A) is less stable (thermodynamically) than its diastereomer (B). Either of (A) or (B) on ozonolysis givesonly one aldehyde. Which of the following is correct :(a) (A)
 
            
reagents'Baeyer
Meso product (b) (B)
              
acidformicPeroxy
meso product (c) both (d) None.3.
 
An alkene (A) on Sabatier-Senderens reduction gives lowest normal alkane which can perform sulphonation. (A)on ozonolysis may give.(a) n- butyraldehyde and ethanal (b) propionaldehyde (c) acetone & formaldehyde (d) both (a) & (b).4.
 
2 – butene on reaction with O
3
/ CCl
4
gives :(a) Me CHO (b) Me COOH (c) Me CH CH Me (d) Me C C Me..5.
 
elect the wrong statement : (a) Cis 3 hexane on reaction with HCO
3
H gives racemic mixture(b) trans -4- octene on reaction with Baeyer’s reagent gives racemic mixture(c) Cis – 5 – decene on reaction with Baeyer’s reagent gives meso product(d) trans-6-tridecene on reaction with HCO
3
H gives meso product.6.
 
The IUPAC name of : (a) t – pentyl neo hexyl methane is 2, 2, 6, 6 – tetra methyl octane(b) least molecular wt. optically active enyne (CnH2n-4) but not containing tertiary carbon is 3- ethyl-3-methylpent-I-en-4-yne (c) both correct (d) None is correct.7.
 
Propene on reaction with B
2
H
6
– THF followed by reaction with D
2
O
2
- OD
-
gives (A) and on reaction with B
2
D
6
-THF followed by reaction with H
2
O
2
- OH
-
gives (B). (A) and (B) are :(a) same (b) primary alcohol racemic mixture(c) Me CHD CH
2
OD, MeCHDCH
2
OH (d) MeCH
2
CH
2
OD, MeCH
2
CH
2
OH.8.
 
In which of the following triplets member has + M effect, second member has –I effect and third member is moreacidic than water : (a) - NH
2,
- F, CH
CH (b) - OH, - NO
2
, MeOH (c) both (d) None.9.
 
An alkene (A) on hydroboration oxidation or oxymercuration demercuration gives (B). (B) can not be resolved intoenantiomers. (A) may be : (a) Propene (b) 2 - butane (c) 2 - pentene (d) Styrene.10.
 
In which of the following chiral centre is generated :(a) Me CH = CH
2
(b) Me CH = CH
2
(c) both (d) None.11.
 
Maximum no. of carbonyl compounds are obtained in ozonolysis of :(a) CH
2
= CH - CH = CH - CH = CH - CH = CH
2
(b) -Me(c) (d) Me CH = C (D) CH12.
 
In which of the following product written is not correct :(a) Me
2
C = CHMe Me
2
C(OH) CHCl Me (b) Me
2
C = CH
2
Me
2
C(Cl) CH
2
NO(c) Me CH = CHD MeCHDCHD Br (d) CH
2
= CHCH
2
OH H
2
- CH - CHO.13.
 
Structural formula for Lewisite is :(a) CHCl = CHAsCl
3
(b) CH
2
= CHAsCl
3
(c) CHCl = CHAsCl
2
(d) ClC
C AsCl
2
.14.
 
Cetane number of following is assigned to be 100 :(a) n-hexadecane (b) n-icosane (c) a-methyl napthalene (d) pyridine.15.
 
Following on reaction with ammonia will give pyrole under suitable conditions :(a) Benzene (b) Cyclobutane (c) 1, 3 cyclobutadiene (d) Ethyne.16.
 
In the following reaction, the product (C) is : (a) CaC
2
(A) (B) (C) :
O – OOO – OO
DBr / peroxideDCl / peroxide
C Me
HOCl / H+NOClDBr / peroxide
Cold dil. / KMnO
4
 H
2
OHot IronTube
CH
3
ClAlCl
3
 
 
 
(a) Benzene (b) Toulene (c) Ethylbenzene (d) n-propyl benzene.17.
 
(CH
3
)
3
CMgCl on reaction D
2
O produces :(a) (CH
3
)
3
CD (b) (CH
3
)
3
OD (c) (CD
3
)
3
CD (d) (CD
3
)
3
OD.18.
 
In the following groups - OAC(I), -OMe(II), -OSO
2
Me(III), -OSO
2
CF
3
(IV) the order of leaving group ability is :(a) I >II>III>IV (b) IV>III>I>II (c) III>II>I>IV (d) II>III>IV>I.19.
 
2-methyl but-1-ene reacts with mercuric acetate in presence of water to form a product, which on reduction withNaBH
4
yield :(a) 2 methyl butan-2-ol (b) 2 methyl butan-1-ol (c) 3 methyl butan-2- ol (d) None of these.20.
 
In the chlorination of propane , what would be the expected product ratio of n-propyl chloride to Isopropylchloride if all the H-atoms were abstracted at equal rates : (a) 1 : 1 (b) 2 :1 (c) 3 : 1 (d) 6 : 1.21.
 
Phthalic anhydride + benzene Final compound. Write the final Compound :(a) (b) (c) (d) (e) None of these.22.
 
Consider the following substaces -1)1, 3 di methyl benzene 2)1 ,4 dimethyl benzene3) Toulene 4) Benzene 5) 1, 3, 5trimethyl benzene . Arrange these substances in decreasing order of their relative reactivity towards electrophile :(a) 5 > 1 > 2 >3 > 4 (b) 1 > 2 > 5 >3 > 4 (c) 1 > 5 > 2 >3 > 4 (d) 2 > 1 > 5 >3 > 4.23.
 
Main product is : (a) (b) (c) (d) .24.
 
undergoes electrolyphilic substitution reaction preferentially :(a) at 2 position (b) at 3 position (c) at 4 position (d) at 2 & 4 position.25.
 
Identify the final product C
6
H
5
CH
3
final product.(a) pClC
6
H
4
CH
2
CH
2
CH
2
OH (b) pHOC
6
H
4
CH
2
CH
2
OH(c) pClC
6
H
4
CH
2
CHOH (d)pClC
6
H
4
CH
2
CH
2
CH
2
OH26.
 
3 mole mixture of 1 butyne and 2 butyne forms 11.2 It H
2
gas at N.T.P. Hence mole fraction of 1-butyne is :(a) 0.25 (b) 0.75 (c) 0.66 (d) 0.33.27.
 
CH
C - C - OH A A is : (a) CHOCH
2
COOH (b) (c) (d) No reaction.28.
 
CH
3
-C
C - CH
3
(A) (B) :(a) A is cis - 2 butene, B is meso compound (b) A is trans 2 butene, B is reacemic mixture(c) A is cis -2 butene, B is racemic mixture (d) A is trans2butene, B is meso compound.29.
 
Propyne is reacted with ammonical cuprous chloride and the product is treated with oxygen to obtain A, A is :(a) CH
3
- C
C - OH (b) CH
3
C
C - C
C - CH
3
(c) CH
3
CH
2
CHO. (d) CH
3
COCH
3
.30.
 
CH
CH + HCl → CH
2
= CH - C
l
+ ? (a) Chloroprene (b) P.V.C. (c) Bakelite (d) Neoprene.31.
 
Following will not yield a cyclic compound on heating :(a) (b) (c) (d)32.
 
Cold & dil KMnO
4
combines with but-2yne to form :(a) butan-2one (b) butnane-2,3dione (c) butane-2,3diol (d) butane1,3diol.33.
 
2 – butyne on reduction with H
2
-Lindlar’s catalyst gives (A). (A) on treatment with the Baeyer’s reagent gives (B).Which of the following is correct :(a) (A) is Cis-2-butene, (B) can be resolved (b) (A) is trans-2-butene, (B) is meso product(c) (A) is cis-2butene, (B) is racemic mixture (d) None of these.34.
 
Acetylene on reduction with H
2
/ p – 2 catalyst gives (A) and on reduction with H
2
/ Pt catalyst gives (B). Which ofthe following is correct : (a) (A) on reaction with Me
3
C – Cl in presence of AlCl
3
gives Me
3
C – CH
2
CH
2
Cl.(b) (B) on reaction with conc. HNO
3
at about 500
0
C gives two products having difference in molecular wt. of 14.(c) both (d) None.35.
 
In which of the following pairs both members can not be prepared by Sabatier Senderens method:
AlCl
3
 
1) Zn/Hg, HCl2) PCl
3
 
AlCl
3
 
OOC
COCl
OHCH
3
 CH
3
 CH
3
 
H
2
SO
4
 
CH
3
 CH
3
 CH
3
 CH
3
 CH
3
 CH
3
 CH
3
 CH
3
 CH
3
 CH
3
 CH
3
CH
3
 
4
 
32N1
..
Cl
2
 Fe
NBS
Mg(1 mole)Ether1) ethylene oxide2) H
3
O
+
 HgSO
4
 H
2
SO
4
 
CH
3
CCOOHO
 
CH
2
=CH-C-OHO
 Lindlar’sAlkalineKMnO
4
 
COOHCH
2
COOHCH
2
COOHCH
2
COOHCH
2
COOHCH
2
CH
2
COOHCOOHCOOH

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