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Pure aluminum and 316L stainless steel were exposed to alcohol/KOH solutions, called alkoxides, which are commonly used in biodiesel
synthesis. The corrosion behavior of these materials was studied through polarization and Electrochemical Impedance Spectroscopy (EIS)
measurements. The results show that aluminum behavior in alkoxides is similar to its behavior in an aqueous alkaline solution. It was also
observed that stainless steel is more resistant to corrosion than aluminum in alkoxide solutions at different KOH concentrations.
Aluminio puro y acero inoxidable 316L fueron expuestos en soluciones de alcohol y KOH conocidas como alcóxidos, empleados comúnmente
en la obtención de biodiesel. El comportamiento de la corrosión de los metales mencionados fue estudiado mediante polarización e Impedan-
cia electroquı́mica (EIS). Los resultados mostraron que el aluminio se comporta de manera similar al aluminio inmerso en una solución
alcalina acuosa. También se determino que el acero inoxidable tiene mayor resistencia a la corrosión en una solución alcohólica con difer-
entes concentraciones de KOH, que la que ofrece el aluminio en la misma solución.
ear polarization and electrochemical impedance spectroscopy Inc. USA) in a typical cell of three electrodes, using a plat-
measurements. inum wire as the auxiliary electrode and an Ag/AgCl wire as
the reference electrode. Aluminum and stainless steel were
used as the working electrodes. The metallic samples were
2. Experimental procedure mounted in epoxy resin with an exposed cross section. Be-
2.1. Materials fore each experiment, the exposed surface was polished and
cleaned with deionized water, degreased with acetone and
Pure aluminum (99.99%) and 316L stainless steel (18-Cr, 10-
Ni, 3-Mo, Fe-bal), both obtained from Goodfellow Materials
Ltd, were used. The materials were obtained in rods of 6 mm
in diameter (cross sectional area: 0.28 cm2 ). The ethoxide
was prepared using reagent grade ethanol anhydrous (EtOH)
and potassium hydroxide (KOH).
TABLE I. Average Ecorr , Icorr and corrosion rate (CR) values obtained by Tafel analysis.
Materials Concentrations Ecorr (mV) Icorr (µA) Corrosion rate (mpy)
1M -1930 160 261.92
Aluminum 0.5M -1890 41.600 68.099
0.25M -1390 19 31.103
1M -686 1.150 1.882
Stainless Steel 0.5M -633 0.501 0.820
0.25M -500 0.262 0.428
* (mpy) = mili-inch per year
dried. The measurements were carried out in the fol- steel, which indicates a greater susceptibility to corrosion for
lowing order: open circuit potential (OCP), electro- aluminum in the media studied. Table I shows the obtained
chemical impedance spectroscopy (EIS) in the range of averages values for Ecorr and icorr , which confirm that alu-
10 mHz - 100 kHz with an amplitude signal of 10 mV on the minum is more susceptible in this media than stainless steel.
open circuit potential and, finally, linear polarization. The Figure 3 shows the Nyquist diagram for the stain-
measurements were repeated at least three times for each con- less steel, which exhibited typical behavior for a mecha-
centration of KOH. nism controlled by the diffusion of species at the stainless
steel/solution interface. This behavior confirms the high cor-
3. Results and discussion rosion resistance of stainless steel in the alkoxide media.
Impedance data for aluminum is shown in Fig. 4. This
Figure 1 shows the Tafel curves obtained for the 316L stain- Nyquist diagram of aluminum in alkoxide is very similar to
less steel. It can be observed that the anodic part does not the Nyquist diagrams reported for aluminum immersed in al-
exhibit changes with the KOH concentration. The same be- kaline aqueous solutions [14-16].
havior is observed for the cathodic part. Therefore, the anodic
and cathodic reactions do not change with different KOH
concentrations. It was also shown that the corrosion current
4. Conclusions
decreases as KOH concentration decreases, indicating a less Pure aluminum and 316L stainless steel are materials used di-
corrosive alcoholic solution. Decreasing the KOH concen- rectly or indirectly in biodiesel synthesis (in a process called
tration also moves the corrosion potential, toward the noble transesterification), so were studied in contact with alcoholic
potential region. solutions at different KOH concentrations. Aluminum corro-
Figure 2 shows the polarization curves for the aluminum sion after immersion in alcoholic/KOH solutions is similar to
immersed in the alcoholic solutions at different KOH con- aluminum immersed in water. The results indicate that stain-
centrations. The corrosion mechanism of aluminum in aque- less steel has greater corrosion resistance than aluminum in
ous media involves three stages of electron transfer and one alkaline alcoholic solutions, called alkoxides, which are used
final chemical stage for the formation of Al(OH)3 [10-12]. in biodiesel production.
Aluminum in a methanol/KOH solution behaves similarly to
aluminum in aqueous media with KOH [13].
The presence of alkaline compounds is the major cause of Acknowledgement
corrosion effects on aluminum, where the compound in this
case is KOH. Decreasing the KOH concentration decreases The authors are grateful for the financial support received
the aggressiveness of the media. However, the measured cor- from CONACYT (Consejo Nacional de Ciencia y Tec-
rosion current region is greater in aluminum than stainless nologı́a) under project 47197/A-1.
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