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Concept of Degree of Unsaturation & Isomerism by S.K.sinha See Chemistry Animations at sinhalab.com

Concept of Degree of Unsaturation & Isomerism by S.K.sinha See Chemistry Animations at sinhalab.com

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Published by myiitchemistry
One of the unique approach of problem Solving evolved by the great teacher in organic chemistry S.K.Sinha Sir.
Here the concept is original with problem solving orientation. Thanks to Sinha Sir
One of the unique approach of problem Solving evolved by the great teacher in organic chemistry S.K.Sinha Sir.
Here the concept is original with problem solving orientation. Thanks to Sinha Sir

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Categories:Types, School Work
Published by: myiitchemistry on Sep 12, 2010
Copyright:Attribution Non-commercial

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05/10/2013

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11
Isomerism Isomerism and D.U and D.U 
 
22
Isomers Isomers 
Isomers:Isomers:different compounds with the same molecular formula.
Same number of carbon and other atoms.
Same degree of unsaturation.
Same % of elemental composition.
Must have different physical or chemical properties.
 
33
Isomers Isomers 
D
egree of unsaturation from Structural formula
D
egree of unsaturation from Structural formula
It is defined as the sum of no of It is defined as the sum of no of 
TT
bonds and number of cycles in abonds and number of cycles in acompound.compound.
Ex
ample
Ex
ample
CyclopropaneCyclopropane
TT
bond=0bond=0 cycle=1cycle=1
D
u =1
D
u =1
P
ropene
P
ropene
TT
bond=1bond=1 cycle=0cycle=0
D
u =1
D
u =1
CyclopropeneCyclopropene
TT
bond=1bond=1 cycle=1cycle=1
D
u =2
D
u =2
B
enzene
B
enzene
TT
bond=
3
 bond=
3
cycle=1cycle=1
D
u =4
D
u =4
N
apthalene
N
apthalene
TT
bond=5bond=5 cycle=2cycle=2
D
u =7
D
u =7

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