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Trial P1

Trial P1

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Published by Taksing
SMK Seafield
STPM Chemistry Trial Exam 2010
SMK Seafield
STPM Chemistry Trial Exam 2010

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Published by: Taksing on Sep 13, 2010
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Trial Exam ± 2010/Looi CY
SEKOLAH MENENGAH KEBANGSAAN SEAFIELD, SUBANG JAYAUpper Six Time: 1 ¾ hours
Trial Examination2010CHEMISTRY ± Paper 1
 Answer all the questions in
Section A
and 
Section B.Section A
1.
 
Part of the mass spectrum for 
241212
is shown below. Assumingthat bromine consists of two isotopes of 
79
and r 
81
in equal abundance, which of the graphs is correct?AD2.
 
The table shows the enthalpies of vaporization of ammonia and water.
Molecule Enthalpy of vaporization/kJ mol
-1
 
 NH
3
 H
2
O21.743.9Which statement explains the difference inenthalpy of vaporization between ammoniaand water?A Water is a liquid whereas ammonia isa gas.B The van der Waals forces in water arestronger than those in ammonia.C Hydrogen bonding in water is stronger than in ammonia.D Covalent bond in water is stronger than that in ammonia.3.
 
Ammonia is a non-ideal gas. What is thereason?A The volume occupied by the moleculescannot be ignored.B The intermolecular forces are strong.C The gas is easily compressed at high pressure.D The molecules are small.Prepared by:«««««««««..(Pn. Looi Chui Yean)Checked by:««««««««««(Pn. Poh Bee Lee)Verified by:««««««««..(Pn. Viani Aba)
m/eRelativeintensity186 188 190m/eRelativeintensity186 188 190m/eRelativeintensity186 190m/eRelativeintensity188
 
Trial Exam ± 2010/Looi CY
4.
 
Which of the following statements explainswhy magnesium is a conductor of electricity whereas diamond is aninsulator?A The conduction band of diamond isnot filled with electrons.B The valence band of magnesium isfilled with electrons.C The valence band and the conduction band in magnesium overlap with oneanother.D The difference in energy between theconduction band and the valence bandin diamond is small.5.
 
Going across Period 3 (sodium to chlorine)in the Periodic TableA the electronegativity of the elementsdecreases.B the ionization energy of the elementdecreases.C the standard electrode potential of theelements increases.D the strength of the elements as areducing agents increases.6.
 
Which of the following electronicconfigurations represents an element thatforms a simple ion with a charge of -3?A 1s
2
2s
2
2p
6
3s
2
3p
3
 B 1s
2
2s
2
2p
6
3s
2
3p
6
3d
1
4s
2
 C 1s
2
2s
2
2p
6
3s
2
3p
6
3d
3
4s
2
 D 1s
2
2s
2
2p
6
3s
2
3p
6
3d
5
4s
2
 7.
 
A closed flask contains 3 moles of nitrogenand 5 moles of neon. The total pressureexerted by the mixture at 298 K is
 p
atm.What is the partial pressure of nitrogen inthe flask?A
 p
53
C
 p
83
 B
 p
35
D
 p
51
 8.
 
Fullerene us an isotope of carbon. What isthe coordination number of the carbonatom in fullerene?A 2B 3C 4D 59.
 
The diagram shows the phase diagram of asubstance.Which is the physical state of thesubstance at the conditions marked µP¶ inthe diagram?A LiquidB SolidC Solid in equilibrium with liquidD Solid in equilibrium with gas10.
 
The graphs show the energy distribution of the molecules in a sample of ethane gas at279K and 289K. Which of the followinggraphs is correct?ABCDPressure/P 
 
 
Trial Exam ± 2010/Looi CY
311.
 
The figure below shows the log ionisationenergy for the electrons in the outer shellsof an atom X.The atom X is most likely to beA argon C potassiumB aluminium D calcium12.
 
Which of the following species does not possess coordinate bonding?A NH
4+
C Al
2
Cl
6
B BF
3
D H
3
O
+
13.
 
The structural formulae of benzene-1,4-diol (hydroquinone) and benzene-1,2-diolareThese two organic compounds havedifferent boiling points although they havethe same relative molecular mass. This is because benzene-1,4-diolA can form intermolecular hydrogen bondsB can form intramolecular hydrogen bondsC is more polar than benzene-1,2-diolD has stronger covalent bonds14.
 
2W + X + Y
ZThe rate equation for the reaction israte = k [X]
2
[W].Which condition will n
ot
increase the rateof the forward reaction?A Increasing the temperatureB Adding a suitable catalystC Increasing the concentration of YD Increasing the concentration of W15.
 
When 2.0 mol of hydrogen iodide is heatedto 460
o
C in a 1.0 dm
3
container, 1.56 molof hydrogen iodide remained atequilibrium. Calculate the K 
c
for thefollowing equilibrium.2HI(g) H
2
(g) + I
2
(g)A 0.12
 
B 0.03C 0.02D 0.0116.
 
Which species is drawn with the correctshape?ABCD17.
 
The reaction of acidified potassium iodidewith hydrogen peroxide2I
-
(aq) + H
2
O
2
(aq) + 2H
+
(aq)
I
2
(aq) + 2H
2
O(l)is thought to involve the following steps:H
2
O
2
+ I
-
 
H
2
O + OI
-
(slow)OI
-
+ H
+
 
HOI (fast)HOI + H
+
+ I
-
 
I
2
+ H
2
O (fast)Which of the following conclusions
cannot
be drawn from this information?A The acid is the catalyst.B The reaction is first order with respectto the iodide ion.C The rate determining step isH
2
O
2
+ I
-
 
H
2
O + OI
-
 D The rate equation for the reaction is :Rate = k[H
2
O
2
][ I
-
]

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