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Table Of Contents

Reaction Intermediates in Organic Chemistry: the "Big Picture"
(ii) "Sandwich" complexes (metallocenes)
Benzyne (arynes)
Carbenes (singlet)
Carbenes (triplet)
Carbene (Arduengo)
Dications
(i) Benzidine rearrangement
(ii) Dications synthesized in magic acid
(iii) Violenes
(i) Azomethine ylide
(ii) Carbonyl oxide (Criegee zwitterion)
(iii) Carbonyl ylide
(iv) Nitrile ylide
(v) Thiocarbonyl ylide
(i) Azomethines
(ii) Azonium imines
(iii) Carbonyl imines
(v) Nitrosoimines
(vi) Thiocarbonyl imines
Extended Cumulenones
Heterocumulenones (iminopropadienones)
Janovsky complex
Nitrenes
Nitrilium Ions
Oxenium ions
(i) Acetoxonium ions
(ii) Flavinium salts
(iii) Flavylium salts
(iv) Meerwein salts
(v) Methoxonium ions
Phenonium Ions
Radicals
(ii) Alkyl radicals
(iii) Aryl radical (phenyl radical)
Group V centred radicals (N, P)
(v) Nitroxide radicals
(ix) Verdazyls
(ii) Selanyl
Radical Anions
Radical Cations
Distonic radical cations
Transition Metal Carbene Complexes
Transition Metal Carbyne Complexes
Transition Metal Silene Complexes
Transition Metal Vinylidenecarbene (allenylidene) Complexes
Wallach intermediate (see Dications)
Wanzlich carbenes
Ylides (1,2-Dipoles)
(ii) Oxonium ylides
(vii) Trapping of carbenes generated by flash photolysis
Index
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