Technology, Energy Efficiency & Environmental Externalities in The Cement Industry - AIT Thailand

TECHNOLOGY, ENERGY EFFICIENCY
AND ENVIRONMENTAL EXTERNALITIES

IN THE CEMENT INDUSTRY
School of Environment, Resources and Development

Asian Institute of Technology
Bangkok - Thailand
TE O F T E
TU
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I
I A N IN ST
HN
O L O GY
AS
19 5 9
TECHNOLOGY, ENERGY
EFFICIENCY AND
ENVIRONMENTAL EXTERNALITIES
IN THE CEMENT INDUSTRY
Cement Industry
(Dry Process)
Effluent Flow &
Energy Flow Emissions
Raw Materials Raw Materials

(Limestone, Alumina, Iron oxide, (Limestone, Alumina, Iron oxide,
other minor constituents, etc. other minor constituents, etc.
Limestone usually mined on site) Limestone usually mined on site)
Raw Materials
Preparation To
23.5-34.5 Stack
To Electricity
Stack Crushing & Preblending kWh/ton Dust Crushing & Preblending
Screening & Milling Electricity Dust Screening & Milling
Proportioning & Proportioning &

Electricity Dust
Blending Blending
Clinker Production
Flue Flue
gases gases
Stack Electricity & To
(350°C) Drying Energy (Fuel) Stack Drying
- Dry Process √
- Wet Process
- Semi-wet Process
- Semi-dry Process 23-30 kWh/ton
Flue Screening & Milling Electricity Flue Dust Screening & Milling
gases 3-4MJ/kg gases
Electricity
Energy (Fuel) To
Stack Burning in the Kiln Stack Burning in the Kiln
(650°C) (3-4MJ/kg)
Dust (to disposal system)
Dust (1150°C)
Heated Air Heated

(250°C) Air
Exhaust Electricity
Clinker Cooling (Blower) Exhaust Clinker Cooling
(250°C) * The dotted line represents Wet Process only
70°C
Mixing with gypsum and Electricity Mixing with gypsum and

Waste
Finish grinding (30 kWh/ton) Finish grinding
Finishing
Electricity
Packaging and Shipping Packaging and Shipping
(1.5 kWh/ton)
Finished Packaged Finished Packaged

Cement Cement
Brahmanand Mohanty
School of Environment, Resources and Development

Bangkok - Thailand
Technology, Energy Efficiency and Environmental Externalities
in the Pulp and Paper Industry
© Asian Institute of Technology, 1997
Edited by Brahmanand Mohanty
Published by School of Environment, Resources and Development

P.O. Box 4, Pathumthani 12120
Thailand
e-mail: visu@ait.ac.th
NOTICE
Neither the Swedish International Development Cooperation Agency (Sida) nor the Asian
Institute of Technology (AIT) makes any warranty, expressed or implied, or assume any legal
liability for the accuracy, completeness, or usefulness of any information, appratus, product,
or represents that its use would not infringe privately owned rights. Reference herein to any
trademark, or manufacturer, or otherwise does not constitute or imply its endorsement,
recommendation, or favoring by Sida or AIT.
ISBN 974 - 8256 – 70--7
Printed in India by All India Press, Pondicherry.

FOREWORD
The use of fossil fuels leads to the emission of so-called "Green House Gases (GHG)", a
concept which comprises carbon dioxide, nitrous oxides, sulfur oxides, etc. In recent years, a
good deal of research has provided enough material to put forward the claim that a big
increase in the concentration of carbon dioxide in the atmosphere would lead to a rise in the
average global temperature, with negative consequences for the global climate. This claim
has been confirmed by the United Nations Intergovernmental Panel on Climate Change
(IPCC) in its second scientific assessment published in 1996.
Global warming can have catastrophic impact on human and global security: island nations
and low lying coastal regions would be permanently drowned by the rise in the level of the
oceans brought on by the melting of polar ice; drought would become widespread; and
desertification would expand and accelerate. Persistent famines, mass migrations and large-
scale conflict would be the result. Agriculture, food and water security, and international
trade would come under severe strain.
Until recently, industrialized countries have accounted for most of the emission of the
GHG, in particular carbon dioxide, because their economic development has been very
strongly based on the use of fossil fuels. However, the same dynamic has also led to a
situation where the newly industrializing countries of Asia and Latin America (the strong
South) are today contributing significantly to the emission of carbon dioxide. This tendency
will spread to and encompass an increasing number of developing countries unless both the
industrialized and the developing countries jointly agree on implementing the measures to
halt and then reverse the global trend towards a rapid rise in the emission of carbon dioxide.
That is the central purpose of the IPCC, which has succeeded in obtaining commitments
from most of the industrialized countries to reduce their emissions of carbon dioxide.
At the 1995 meeting in Berlin of the Conference of the Parties (CoP) to the United Nations
Climate Convention, it was decided to initiate negotiations to strengthen the emission-
reduction measures by the industrialized countries, as well as countries of Eastern Europe
and the Former Soviet Union. The final negotiations are planned to take place at the
December 1997 meeting in Kyoto of the CoP, which ought to result in legal instruments to
ensure that the agreed measures are being fulfilled.
The fossil fuel generated climate problem is very complex, with strong vested interests and
special alliances. There is still considerable skepticism in the developing world about the
need for measures to counter global warming, in particular in the strong South, which in no
way wants to jeopardize its own rapid economic development. It is therefore imperative to
find innovative solutions, both technical and institutional, to the climate problem, which are
acceptable to both the North and the South. Meeting this challenge calls for inter alia
research programs that tackle the technological, techno-economic and policy problems in
promoting the transition to decreasing use of fossil fuels, increasing energy efficiency and
fuel substitution, and carbon recycling systems of energy production and use.
The Asian Regional Research Programme on Energy, Environment and Climate

(ARRPEEC) is part of this global effort, which Sida is very pleased to have initiated and is
fully supporting. The ARRPEEC comprises technological, techno-economic and policy
research on energy efficiency, fuel substitution and carbon recycling in the principal
economic sectors of East, Southeast and South Asian countries.
M R Bhagavan
Senior Research Adviser, Department for Research Cooperation
Swedish International Development Cooperation Agency, Sida
PREFACE
Industries have always played a crucial role in the socio-economic development of a country.
They have contributed primarily to increased prosperity, greater employment and livelihood
opportunities. On the other hand, industries are accused of accelerating the consumption of
scarce fossil fuels and of polluting the local, regional, and global environment by releasing
solid, liquid and gaseous pollutants to their surroundings.
Experiences gained worldwide have shown that these impacts of industries on resource use
and the environment can be contained through more efficient production processes and
adoption of cleaner technologies and procedures. Thus, fossil fuel consumption can be cut
down drastically and waste generation can be avoided or minimized to the lowest possible
level. Regulatory regimes introduced in several countries have led the industries to adopt
appropriate measures. Some countries have adopted economic instruments to reflect the true
cost of goods and services by internalizing the environmental costs of their input,
production, use, recycling and disposal.
The improvement of production system through the use of technologies and processes that
utilize resources more efficiently and achieve “more with less” is an important pathway
towards the long-term sustenance of industries. It is in this context that a research project
was undertaken by the Asian Institute of Technology (AIT), with the support of the Swedish
International Development Cooperation Agency (Sida). The project entitled “Development
of Energy Efficient and Environmentally Sound Industrial Technologies in Asia” was
launched with the specific objective to enhance the synergy among selected Asian
developing countries in their efforts to grasp the mechanism and various aspects related to
the adoption and propagation of energy efficient and environmentally sound technologies.
Three energy intensive and environmentally polluting industrial sub-sectors (cement, iron &
steel, and pulp & paper) and four Asian countries of varying sizes, political systems and
stages of development (China, India, Philippines, Sri Lanka) were selected in the framework
of this study. To enhance in-country capacity building in the subject matter, collaboration
was sought from reputed national institutes who nominated experts to actively participate in
the execution of the project.
The activities undertaken in the first phase of the project were the following:
- Evaluation of the status of technologies in selected energy intensive and
environmentally polluting industries;
- Identification of potential areas for energy conservation and pollution abatement in
these industries;
- Analysis of the technological development of energy intensive and polluting
industries in relation with the national regulatory measures;
- Identification of major barriers to efficiency improvements and pollution
abatement in the industrial sector.
Based on the initial guidelines prepared at AIT under the leadership of Dr. X. Chen,
discussions were held with the experts from the national research institutes (NRIs) of the
four participating countries. The outcomes of these meetings were used as a basis for the
preparation of country reports which were presented at two project workshops held at
Manila in May 1995 and at Bangkok in November 1995. On the basis of the reports
submitted, cross-country comparison reports were prepared at AIT and additional relevant
information was sought from the NRIs to bridge some of the gaps found in their respective
reports. This is the third of the four volumes of documents which have resulted from this
interactive research work between AIT and the NRIs.
This volume on “Technology, energy efficiency and environmental externalities in the pulp
and paper industry” covers a description of the paper manufacturing process, and the energy
and environmental aspects associated with it. Then there is a cross-country comparison of
the pulp and paper sector in the four countries, followed by individual country reports
prepared by the four NRIs. The first five chapters were prepared by Dr. B. Mohanty and Dr.
Uwe Stoll with the assistance of research associates figuring in the Project Team.
Sincere thanks are extended to all the members of the Project Team including the supporting
staff, past and present, for their active participation and contribution to the project. The
enthusiasm and dynamism of Dr. X. Chen during the execution of the first phase and the
understanding and leadership provided by Dr. C. Visvanathan in the crucial completion
period of the project are acknowledged here. The project would have never seen the light of
the day without the support of Sida. Finally, appreciations are due to two individuals who
have actually conceived the Asian Regional Research Programme on Energy, Environment
and Climate (ARRPEEC) and provided constant support and encouragement to this specific
project under the overall program: Dr. M.R. Bhagawan, Senior Research Adviser at Sida, and
Dr. S.C. Bhattacharya, Professor at AIT.
Brahmanand Mohanty
June, 1997
PROJECT TEAM
Faculty Members (Asian Institute of Technology - School of Environment,

Resources and Development)
- Dr. Xavier Chen, Energy Program (Until February 1996)
- Dr. Brahmanand Mohanty, Energy Program
- Dr. Uwe Stoll, Environmental Engineering Program (Until January 1996)
- Dr. C. Visvanathan, Environmental Engineering Program (From January 1996)
Research Associates (Asian Institute of Technology - School of Environment,

Resources and Development)
- Ms. Nahid Amin
- Ms. Lilita B. Bacareza
- Mr. Z. Khandkar
- Mr. Aung Naing Oo
- Mr. K. Parameshwaran
National Research Institutes

- Institute for Techno-Economics and Energy System Analysis, Tsinghua
University, Beijing, China (Prof. Qiu Daxiong)
- Energy Management Centre, Ministry of Power, New Delhi, India (Mr. S.
Ramaswamy)
- Department of Energy, Manila, Philippines (Mr. C.T. Tupas)
- Energy Conservation Fund, Ministry of Irrigation, Power and Energy, Colombo,
Sri Lanka (Mr. U. Daranagama)
Research Fellows
- Dr. Wu Xiaobo, School of Management, Zhejiang University, China (January-
June 1996)
- Ms. Wang Yanjia, Tsinghua University, China (May-November 1996)
- Mr. Anil Kumar Aneja, Thapar Corporate R&D Centre, India (May-November
1996)
- Ms. Marisol Portal, National Power Corporation, Philippines (May-November
1996)
- Mr. Gamini Senanayake, Industrial Services Bureau of North Western Province,
Sri Lanka (May-November 1996)
Table of Contents
1. GENERAL.................................................................................................................................. 1
2. PROCESS DESCRIPTION ...................................................................................................... 2
2.1 CEMENT KILN ....................................................................................................................... 4
2.2 CEMENT KILN PROCESSES .................................................................................................... 5
2.2.1 Wet Process................................................................................................................. 5
2.2.2 Semi-wet Processes ..................................................................................................... 7
2.2.3 Semi-dry Process......................................................................................................... 7
2.2.4 Dry Process................................................................................................................. 8
3. ENERGY ISSSUES IN THE CEMENT INDUSTRY .......................................................... 10
3.1 TYPICAL ENERGY CONSUMPTION PATTERNS ..................................................................... 10
3.2 ENERGY EFFICIENCY MEASURES ........................................................................................ 13
3.2.1 Short Term Measures ................................................................................................ 13
3.2.2 Medium Term Measures............................................................................................ 14
3.2.2.1 Measures on Processed Materials and Products ....................................................... 14
3.2.2.2 Changes and Modifications in Sub-Processes .......................................................... 14
3.2.2.3 Recovery of Waste Heat........................................................................................... 16
3.2.3 Long Term Measures................................................................................................. 17
3.2.3.1 Conversion from Wet to Dry Process....................................................................... 17
3.2.3.2 Cogeneration ............................................................................................................ 18
3.2.3.3 Computer-Controlled System ................................................................................... 18
3.3 NEW ENERGY EFFICIENT TECHNOLOGIES FOR CEMENT MANUFACTURING ...................... 18
3.3.1 Suspension Preheating Technology .......................................................................... 20
3.3.2 Suspension Preheating/Precalcination Technology.................................................. 20
3.4 CONCLUDING REMARKS ..................................................................................................... 21
4. ENVIRONMENTAL POLLUTION AND MANAGEMENT.............................................. 22
4.1 SOURCES AND CHARACTERISTICS OF POLLUTANTS ........................................................... 22
4.1.1 Water Pollution ......................................................................................................... 22
4.1.2 Air Pollution.............................................................................................................. 22
4.1.2.1 Particulates ............................................................................................................... 23
4.1.2.2 Gaseous Substances.................................................................................................. 26
4.1.3 Solid Waste................................................................................................................ 26
4.2 CURRENT POLLUTION ABATEMENT STRATEGY AND TECHNOLOGIES ............................... 26
4.2.1 Air Pollution Control ................................................................................................ 26
4.2.1.1 Dust Collecting Devices ........................................................................................... 26
4.2.1.2 Gaseous Emission Control........................................................................................ 29
4.2.2 Water Pollution Control............................................................................................ 29
4.2.3 Solid Waste Disposal................................................................................................. 30
4.2.3.1 Landfill ..................................................................................................................... 30
4.3 OTHER ENVIRONMENTAL CONSIDERATIONS IN CEMENT INDUSTRY ................................. 30
4.3.1 Noise Pollution.......................................................................................................... 31
4.3.2 Reduction of Ground Vibrations ............................................................................... 32
4.3.3 Raw Materials Resources and Site Restoration ........................................................ 32
4.3.4 Utilization of Waste Materials as Raw Material and Fuel in Cement Industry........ 32
4.4 CONCLUDING REMARKS ..................................................................................................... 35
5. CROSS-COUNTRY COMPARISON OF THE CEMENT SECTOR ................................ 36
5.1 INTRODUCTION ................................................................................................................... 36
5.2 OVERVIEW OF THE INDUSTRY ............................................................................................. 36
5.2.1 Role in National Economy ........................................................................................ 36
5.2.2 Share in Total Energy Consumption ......................................................................... 36
5.2.3 Trends of Production................................................................................................. 37
5.2.4 Mills and Capacities ................................................................................................. 38
i
5.3 CHARACTERISTICS OF THE PARAMETERS AFFECTING ENERGY EFFICIENCY ...................... 40
5.3.1 Process Mix............................................................................................................... 42
5.3.2 Average Kiln Size ...................................................................................................... 42
5.3.3 Energy Consumption by Type ................................................................................... 43
5.3.4 Awareness on Energy Conservation ......................................................................... 43
5.4 CHARACTERISTICS OF THE PARAMETERS AFFECTING POLLUTION ABATEMENT MEASURES44
5.4.1 Causes for the Pollution Problems ........................................................................... 45
5.4.2 Current Pollution Control Strategies........................................................................ 45
5.4.2.1 Pollution Control Strategies in China ....................................................................... 45
5.4.2.2 Pollution Control Strategies in India ........................................................................ 45
5.4.2.3 Pollution Control Strategies in Philippines............................................................... 46
5.4.2.4 Pollution Control Strategies in Sri Lanka................................................................. 46
5.4.3 Comparison of Effluent and Emission Characteristics ............................................. 46
5.5 POTENTIAL FOR ENERGY EFFICIENCY IMPROVEMENTS...................................................... 48
5.5.1 Measures on Structure of the Industry ...................................................................... 48
5.5.2 Potential of Energy Conservation Measures ............................................................ 48
5.6 POTENTIAL FOR POLLUTION ABATEMENT .......................................................................... 49
5.7 CONCLUSION ....................................................................................................................... 50
6. PROFILE OF IRON AND STEEL INDUSTRY IN ASIAN INDUSTRIALIZING
COUNTRIES........................................................................................................................... 52
6.1 COUNTRY REPORT: CHINA.................................................................................................. 52
6.1.1 Introduction............................................................................................................... 52
6.1.2 Technological Trajectory of China’s Cement Industry............................................. 52
6.1.2.1 Higher Growth Rate of Production........................................................................... 54
6.1.2.2 Rapid Increase of Small Size Cement Plants............................................................ 54
6.1.2.3 Production Satisfies the Internal Demand ................................................................ 54
6.1.2.4 Better Production Quality and Low Energy Intensity .............................................. 54
6.1.2.5 Coal as the Main Fuel............................................................................................... 56
6.1.3 Evolution of Energy Efficiency in the Cement Industry ............................................ 58
6.1.4 Environmental Externalities of Technological Development in the Cement Industry60
6.1.5 Potential for Energy Efficiency Improvement and Pollution Abatement through
Technological Change ............................................................................................. 66
6.1.6 Status of Application of New Technologies for Energy Efficiency Improvement and
Pollution Abatement ................................................................................................ 69
6.1.7 Conclusions ............................................................................................................... 71
6.2 COUNTRY REPORT: INDIA ................................................................................................... 73
6.2.1 Introduction............................................................................................................... 73
6.2.2 Technological Trajectory of India’s Cement Industry .............................................. 73
6.2.2.1 Current Scenario....................................................................................................... 73
6.2.2.2 Structure of the Cement Industry.............................................................................. 75
6.2.3 Evolution of Energy Efficiency in the Cement Industry of India............................... 75
6.2.3.1 Process Technology Profile ...................................................................................... 77
6.2.3.2 Plant Size .................................................................................................................. 77
6.2.3.3 Thermal Energy Consumption.................................................................................. 78
6.2.3.4 Electrical Energy Consumption................................................................................ 78
6.2.3.5 Domestic Manufacture of Cement Machinery & Equipment ................................... 79
6.2.4 Environmental Externalities...................................................................................... 84
6.2.5 Status of Application of New Technologies............................................................... 85
6.2.5.1 Status of the Development of Technology in India .................................................. 85
6.2.5.2 Particulate Pollution and Abatement ........................................................................ 88
6.2.5.3 Status of Research and Development ....................................................................... 93
6.3 COUNTRY REPORT: PHILIPPINES ......................................................................................... 94
6.3.1 Introduction............................................................................................................... 94
6.3.2 Technological Trajectory of the Philippine Cement Industry ................................... 94
6.3.2.1 Production Capacity ................................................................................................. 94
ii
6.3.2.2 Plant Development ................................................................................................... 95
6.3.3 Evolution of Energy Efficiency in the Philippine Cement Industry........................... 96
6.3.4 Environmental Externalities of the Cement Industry in the Philippines ................... 98
6.3.4.1 Environmental Standards for Pollution Control and Abatement .............................. 98
6.3.4.2 Pollution Control Equipment.................................................................................... 99
6.3.5 Potential for Energy Efficiency Improvement and Pollution Abatement through
Technological Change ............................................................................................. 99
6.3.6 Status of Application of New Technologies............................................................. 101
6.3.7 Concluding Remarks ............................................................................................... 101
BIBLIOGRAPHY ...................................................................................................................... 102
iii
General 1
1. GENERAL
Rapid industrialization and infrastructure development in Asian developing countries has

led to higher cement consumption, and eventually increased production requirement.
Though the production increased mainly due to extended plant capacities and introduction
of new factories, little attention was paid to efficient energy utilization and environmental
pollution control in the cement industry of Asian countries.
Cement is a highly energy intensive product. In a cement factory, the energy bill normally
accounts for 20-25% of the total production cost. The major energy consuming areas in
cement industry are the high-temperature processes; almost 55-85% of the energy input of
the final product is consumed in the high-temperature kiln. Advanced technologies for
waste heat recovery and rationalization of energy use could offer significant energy saving
opportunities in cement industry which is ever exploding due to the rapid global
infrastructure development, especially in developing countries.
This document addresses the cement production technologies in use, various measures for
efficient utilization of energy, major sources of pollution, and the techniques and practices
in vogue to abate pollution in the cement industry to the best possible extent. It further
discusses about other environmental problems such as noise pollution, ground vibration
etc., which are serious concerns for the environmentalists in developed countries, as well as
the possibilities of utilization of waste from other industries by the cement industry. Finally,
country reports on the cement industry for four Asian developing countries, namely, P.R.
China, India, the Philippines and Sri Lanka, which are preceded by a cross-country
comparison of the industry.
2 Technology, Energy Efficiency and Environmental Externalities of the Cement Industry
2. PROCESS DESCRIPTION
The principal raw materials for cement manufacturing are:

- limestone (quarried from the mine, near which the plant is usually located),
- silica and alumina from clay, shale or sand, and
- iron from iron ore or steel mill scale.
The major processes involved in production are:

- excavation of limestone (quarrying)
- crushing of limestone
- preparation of other raw materials
- grinding of raw materials in the raw mill
- storage of raw meal in a raw meal silo
- blending of limestone powder to control CaCO3 percentage
- burning of raw meal to form clinker
- grinding the clinker with gypsum in cement mill
- storage of cement in silo
- packing and distribution of cement
The kiln feed is prepared by proportioning, grinding and blending the raw materials into a
consistent and homogeneous composition so that, after mild heating to drive off any water
and CO2 available in the limestone (CaCO3), one obtains typically 64% calcium oxide
(CaO), 22% silicon dioxide (SiO2), 3.5% aluminum oxide (Al2O3), and 3.0% iron ore (as
Fe2O3) (Sell, 1992). These raw materials are processed at very high temperatures so they
react by solid-solid reactions to form clinker which consists of four major compounds as
shown in Table 2.1. The exact proportions of these final products determine the cement
characteristics; for example, the hardening time, the early strength and the final strength.
Table 2.1. Portland cement clinker compounds

Chemical name Mineral Chemical formula Cement Percentage in
phase chemists ordinary
name designation cement
Tricalcium Silicate Alite 3CaO.SiO2 C3S 45
Diacalcium Silicate Belite 2CaO.SiO2 C2S 25
Tricalcium Aluminate Celite 3CaO.Al2O3 C3A 11
Tetracalcium Alumino-ferrite Iron 4CaO.Al2O3.Fe2O3 C4AF 8
(Source: Dodson, 1990)
The main steps of the cement manufacturing process are shown schematically in Figure
2.1.
Process Description 3
Fig. 2.1. Steps in the manufacture of Portland cement

The largest volume of raw material is CaCO3 or comparable materials (such as oyster shells
in locations where appropriate). The CaCO3 as mined is often in chunks up to 750 mm in
diameter. These must be crushed to about 10 mm, and then mixed with the sand, shale,
and other ingredients for further grinding to about 60µm in diameter. Frequently, the initial
crushing is done at the quarry, prior to transport to the cement plant. After grinding,
depending upon the exact process, water may be added. The mixture is then taken to some
high-temperature processing unit known as rotary kiln for conversion to cement clinker.
The clinker must be cooled before further processing. Then it is either stored, sold or
transported (to individual grinding mills), or is ground at the plant with gypsum and other
possible additives to a fine powder of finished cement. The cement is either packaged or
sold in bulk to the distributors.
2.1 Cement Kiln
The Cement kilns are large; up to 230 m in length and 8 m in diameter; inclined at an angle
of three to six degrees, and lined with temperature-resistant refractory brick. They rotate at
about 50 to 70 revolutions per hour in the older generation plants, and 170 to 180 in the
more modern ones. The feed material is introduced at the elevated end and is moved
slowly by the rotation of the kiln down towards the firing end, where heat is applied by a
flame of coal, gas, oil or a combination of these fuels. Coal is most widely used as the kiln
fuel nowadays.
Several distinct thermal zones exist in the kiln. At the elevated end where the feed is
introduced, is a drying and preheating zone in which the material reaches a temperature of
about 800oC. This is followed by the calcining zone where carbon dioxide is driven off the
limestone, converting it to free lime at a material temperature close to 1000oC. The
chemical reaction taking place in this zone is as follows:
CaCO3 ⇑ CaO + CO2
By the time the calcination is complete, the free lime enters the intermediate zone where
temperature prevails in the range of 1000 - 1200oC and the basic oxide (CaO) reacts with
silica (SiO2) and alumina (Al2O3) as shown:
Al2O3 + CaO ⇑ CaO.Al2O3 (mono-calcium aluminate)

2CaO + CaO.Al2O3 ⇑ 3CaO.Al2O3 (tri-calcium aluminate)
SiO2 + 2CaO ⇑ 2CaO.SiO2 (di-calicium silicate)
2CaO + Fe2O3 ⇑ 2CaO.Fe2O3
2CaO.Fe2O3 + 2CaO + Al2O3 ⇑ 4CaO.Al2O3.Fe2O3
Next is the sintering zone where, at a temperature of about 1300oC, sintering of the
materials begins. While sintering, di-calcium silicate gets saturated with the remaining free
lime and forms tri-calcium silicate.
2CaO.SiO2 + CaO ⇑ 3CaO.SiO2 (tri-calcium silicate)
By the time the materials reach the flame area, they are white hot (1425 -1550oC). In a
semi-liquid state at this stage, they acquire a greenish black color and form nodules about
25 mm in diameter which, on cooling, is referred to as clinker. After this extremely hot
area, the temperature drops, and the clinker starts to cool. The materials then finally drop
out of the kiln onto a cooler, through which large volume of relatively cool air is passed.
The air from the cooler, rather than being wasted, is channeled into the kiln as combustion
air for the flame. This air, in traversing the kiln, becomes turbulent, and often picks up
some of the finer raw material particles which become entrained in the air stream. The air
simultaneously transfers heat to the back end of the kiln. Before the air can exit the kiln, it
is passed through a dense curtain of chains that serves two purposes:
- removes some of the entrained dust, and
- acts as a mechanism for heat transfer in order to retain heat as much as possible
within the kiln.
The air, after leaving the kiln, is ducted to an electrostatic precipitator for particulate
removal, and then to the stack. The clinker is then conveyed to the finish-grinding section
where about five percent of gypsum is added to it. The mixture is finely ground in ball or
tube mills, close-circuited with air separators, to give finished cement. The cement is
conveyed to the storage silos, usually by pneumatic conveyors.
2.2 Cement Kiln Processes
There are four basic types of cement kilns currently in use: wet process, semi-wet process,
semi-dry process, and dry process. Of these, the dry process is the most energy efficient
and most commonly used technology nowadays.
2.2.1 Wet process
Worldwide, a considerable proportion of cement clinker is still produced by the wet

process wherein the raw materials are prepared and mixed with the aid of water (30-40%)
and fed into the upper end of the kiln as a slurry. Wet process is particularly useful when
the raw materials contain a significant amount of moisture as quarried. This process has the
advantage of uniform feed blending, but requires more energy than the other types of kilns,
since the water must be evaporated during the process. Similar process reactions as
described in section 2.1 lead to the formation of clinker. A typical wet-process rotary kiln is
shown in Figure 2.2.
Fig. 2.2. Diagram of a typical wet procvess rotary kiln
Fig. 2.3. Diagram of a typical preheater system

2.2.2 Semi-wet processes
Semi-wet cement processing employs grate-kiln methods (Figure 2.3). In the semi-wet
cement manufacturing process the raw materials prepared by wet processing are first
mechanically dewatered - preferably with filter presses - and then fed in the form of
nodules to a drying unit. This drying unit may be the third compartment of a traveling grate
preheater. Nowadays, a dispersion dryer or impact dryer is preferably installed ahead of the
preheater or precalciner kiln. In cases where former wet kilns have been converted into
one-stage or two-stage preheater kilns on this principle, impact dryers have hitherto been
employed. Advantages of grate-kiln systems include:
- a controlled feed rate
- no flushing of materials into the kiln
- no segregation of raw materials due to differential shapes and densities
- avoidance of fluidization of the materials
- minimal dusting
- production of uniform clinker
- low energy requirement (70% of that required for modern long wet kiln), and
- ability to use higher-alkali feeds than many other processing techniques.
2.2.3 Semi-dry process
In the semi-dry process, nodules or pellets (approximately 12% water) formed from raw
meal with the aid of water are used. The traveling grate preheater kiln continues to be
available as a technically well developed pyro-processing unit. Kilns of this type, however,
suffer from some disadvantages inherent in the system, such as:
- relatively high initial cost and operating expenses associated with kiln outputs,
- specific quality requirements of the raw materials (grate process requires nodules to
be consistent in size and composition which is often very difficult to achieve),
- relatively high overall heat consumption (only the exhaust air from the cooler is
available for drying the materials during grinding),
- restrictions as to the use of low-grade fuels, and
- inability to apply precalcination.
Because of these drawbacks, this system has lost the weight it once possessed. However it
is reported that several of the newer installations in the United States do employ grate-kiln
methods (Sell, 1992). Depending upon the local conditions, in certain situations, they are
deemed preferable to preheater systems.
2.2.4 Dry process
A long kiln similar to that used in the wet process can also be used for a dry process. Dry
process consumes significantly less energy and can often handle particulate emission
problems more easily. Moreover, there are dry processing techniques far superior to the dry
kiln which already consumes less energy than the wet process.
Newer cement plants use the dry process in which the raw material is fed to the kiln as dry
powder. In the most recently erected plants, preheater and precalciner units have been
added to improve the thermal efficiency of the process by using hot kiln gases to pre-heat
and pre-calcine the feed before it enters the kiln. The preferable dry processing method is
by a suspension preheater system as shown in Figure 2.4. The finely ground dry raw
materials are fed into the preheater at the top, counter-current to the air flow. This air flow
originates in the cooler and thus has been heated by traversing through the cooler and also
a short rotary kiln section before being ducted to the preheater. Hence, it is sufficiently hot
to not only preheat, but also partially calcine the incoming materials. The physical
arrangement of a series of cyclones on the preheater is such that the hot air and the feed
can have intimate contact in a series of stages for maximum heat transfer and optimum
efficiency. The addition of a flash calciner, a stationary furnace interposed between the rotary
kiln and the suspension preheater, increases the amount of calcination that occurs within
the preheater, thus increasing the potential capacity of the rotary kiln. When the raw mill
has passed all the stages, it is heated up to 800°C and is extensively calcined before entering
the kiln. The temperature of the hot gas drops to 300°C from 1000°C.
The hot particulate feed, after passing through the preheater and the flash calciner, enters a
short rotary kiln where it undergoes clinkerization. The rational behind accomplishing only
this last stage of the processing within the kiln is better economy, particularly in terms of
energy conservation. In addition, most of the dust generated can be retained within the
preheater, cutting back the dust problems to a great extent.
Shaft kilns (Figure 2.5) constitute another dry processing technique, used to some extent in
Europe. Shaft kilns have lower thermal and power requirements per ton of clinker
produced than those of rotary kilns and are comparable to the preheater systems. Their
major disadvantages are the small capacity and a less uniform product, primarily as a result
of tunneling of the gases through the load.
Fig. 2.4 Diagram of a shaft kiln
Fig. 2.5 Diagram of grate-kiln process

3. ENERGY ISSSUES IN THE CEMENT INDUSTRY
3.1 Typical Energy Consumption Patterns
The cement manufacturing processes consume two types of primary energy: thermal
energy provided by coal, natural gas or oil, and mechanical energy converted from
electricity. The thermal energy accounts for about 87% of the total primary energy and is
mainly used in clinker production. Typical thermal energy and electricity consumptions of
cement manufacturing processes are given in Table 3.1.
Table 3.1. Specific thermal energy and electricity consumption for cement
Process Thermal Energy (GJ/ton) Electricity (kWh/ton)
Wet Process 5.02-5.43 70-125
Semi-wet Process 3.15-3.86 70-125
Dry Process 2.88-3.40 110-125
Semi-dry Process 3.10-3.50 110-125
The secondary energy sources used in cement production are kiln exhaust gas and hot air
from clinker cooler. A process flow diagram showing the various sources of energy used in
the cement manufacturing process is given in Figures 3.1a & 3.1b.
Secondary heat contained in the hot kiln exhaust gas is utilized primarily in pre-drying and
preheating the raw materials before their introduction into the kiln and raw mill. The waste
heat contained in the exhaust air from the clinker cooler too serves to preheat combustion
air and also to dry and preheat the raw materials before they enter the raw mill and kiln.
The two most energy-intensive phases in cement manufacturing are clinker production and
grinding. The clinker production process consumes mainly thermal energy in the form of
coal, oil or gas, while grinding consumes mainly electrical energy.
Typical specific energy consumption values for different cement manufacturing processes
are shown in Figure 3.2.
For the best available technology of dry process production with cyclone preheater and
precalciner, the specific energy consumption is 3.05 MJ/kg of clinker. However, some
cement mills in developing countries are still utilizing the wet process with obsolete
technologies and consuming up to 8 MJ/kg of clinker.
Energy Issues in the Cement Industry 11
* T he dotte d lin e re pres ents We t Pro ces s on ly
Fig. 3.1a. Flow diagram s of a typical dry process cement plant

* Th e dot ted l ine re pres ents Wet Proc ess only
Fig 3.1b.Flow diagram of a typical wet process cement plant

7
7.5%
6
6.5%
10.1%
5
MJ/kg of Cement
10.5%
8.9% 11%
4 9.3%
82% 11%
3
75.5% 60%
55%
2
1
23% 20.2%
4% 5.5%
0
Wet process Semi-wet process Dry process Semi-dry process
Raw materials preparation Clinker production Finishing Others
Figure 3.2. Typical specific energy consumption for cement manufacturing
3.2 Energy Efficiency Measures
The utilization of as much secondary energy sources as possible and the reduction of the
primary purchased energy are the objectives of energy conservation measures in the cement
industry. These measures can be classified according to the level of energy savings and
types of investments involved as follows.
3.2.1 Short term measures
Some of the basic energy saving measures that can be readily implemented in the short
term without major investments are:
- inspection to encourage conservation activity
- training program for operating energy intensive equipment such as crusher,
grinding mill, pneumatic separator, vibrating screen, etc.
- replacement of worn-out parts of crusher and grinding machines
- controlling the slurry water at optimum level (for wet process)
( reduction of moisture content by 5% can save 338 MJ/ton of clinker)
- controlling the combustion air
(10% reduction in excess air can save 34-85 MJ/ton of clinker)
- controlling the composition of raw materials
(the fluctuation encountered in the composition of the raw materials fed to a
cement kiln is generally compensated by an over-baking which leads to energy
losses)
- plugging of all air leakage
- ensuring the uninterrupted operation of the kiln

- power factor improvement of electric motors
- turning off motors and heaters when not in use.
- insulation enhancement of kiln
Energy savings of the order of 10-15% can be achieved by adopting these short term
measures in developing countries.
3.2.2 Medium term measures
These include switching to new and more efficient technologies as well as recovery of
materials and waste heat with moderate capital expenditures.
3.2.2.1 Measures on processed materials and products
(i) Installation of dust collection system

The high velocity gases passing through the kiln carry along a large portion of dust, thus
losing materials as well as energy due to the extra raw material that has to be processed for
the same amount of output. Each percentage of material loss will consume additional
energy of about 42 MJ/ton of clinker. Larger size dust particles can be removed by
cyclones and smaller size dust can be removed by electrostatic precipitators, bag filters or
wet scrubbers.
(ii) Diversification of cement products

The blending of certain materials like granulated slag, fly ash and pozzolans with the
cement makes it possible to produce more cement from the same amount of clinker, and as
a result, the fuel consumption per ton of cement can be reduced. About 20% of clinker can
be replaced by fly ash and up to 25% by blast furnace slag without changing the character
of the ordinary Portland cement as a general purpose cement.
3.2.2.2 Changes and modifications in sub-processes
(i) Reduction of water content of slurry

The water content of slurry can be reduced by any the following means:
- addition of chemicals of slurry thinners
- using proper filters so that slurry is dewatered mechanically
- preheating the slurry by utilizing the secondary energy sources
(each percentage of water reduction in the slurry will increase the kiln capacity by
about 1.5% and reduce the energy consumption by 68 MJ/ton of clinker)
(ii) Installation of dual firing system

The reaction at the kiln takes place at two stages, firstly at a lower temperature range of
800-900°C (which is called calcination) and then at a higher temperature range of 1300-
1500°C (termed as burning). Low grade fuels can be used in the lower temperature range
combustion so that fuels with higher calorific values can be replaced. Depending on the
system, 20-25% of the total fuel can be replaced by low grade fuel being utilized for the
calcination phase.
(iii) Change in clinker grinding system: vertical roller mills to replace tube and ball
mills
Upgradation of equipment such as jaw-crusher to gyratory crusher, ball mill to vertical
roller mill (VRM), worm gears to helical and spiral gears, etc., can increase the efficiency of
power transmission system and reduce specific power consumption.
In roller mills, raw materials are dried during pulverization using waste heat from the kiln
and size reduction is effected by roller or comparable grinding elements traveling over the
circular bed of material which is then subjected to a preliminary classifying action by a
stream of air sweeping through the mill. The grinding efficiency of VRM is more than
twice the value for ball mill in coarse size reduction up to a size of 0.5 mm. Thus the power
consumption of VRM is 35% less than the ball mill. Up to 25% electricity may be saved by
replacing ball mills with roller mills. In new plants, roller mills are recommended to be used
instead of ball mills. The specific electricity consumption of different systems are given in
Table 3.2.
Table 3.2. Specific electricity consumption of cement grinding systems

Grinding System Electricity (kWh/ton)
Open system with ball mills 55
Closed system with ball mills and a separator for recycling 47
Closed system with pre-grinding of clinker into an energy efficient 41
roller mill with recirculation
Closed system based on roller press, a ball mill and separator 39
Closed system only based on a roller press and separator 28
(iv) New rotary kiln

New rotary kiln plant with 4-stage HUMBOLDT preheater and wet preparation can result
in higher efficiency and performance and energy saving of around 15-20%.
(v) Operating the mill in closed loop instead of open loop

The screening and size reduction operation can be either open or closed circuit circuit as
shown in Figure 3.3. After screening, the mixture is ground in the raw mill. There is a 5 to
7% increase in the output and a corresponding reduction in specific energy consumption.
feed fresh feed
Reduction
Reduction
oversize
Classification
fine products
fine products
(i) Open-circuit (ii) Closed-circuit
Figure 3.3. Processes of size reduction
3.2.2.3 Recovery of waste heat
The waste heat available in the form of secondary energy sources is shown in Figure 3.4
with typical temperature ranges.
Preheater
exhaust gas (280-600 °C)
Preheater Preheater
intermediate
gas (500-800°C)
Hot air from cooler (Secondary air)

Calcinator (700-900°C)
Exhaust air from cooler

(150-400 °C)
Kiln exit gas Kiln Clinker
(Bypass gas) Cooler Clinker
(1000-1200 °C) Products
Figure 3.4. Availability of waste heat at different temperature levels
The exhaust gases from preheater, calcinator and kiln, and the exhaust air from the cooler
can be used for the following purposes:
- to dry the raw materials (applicable for blast furnace slag, coal, etc.)
- to by-pass to precalcinator
- to generate steam (36-108 MJ/ton clinker), and
- to generate electricity using Organic Rankine Cycle (ORC)
For a cement factory of 1000 ton/day of clinker capacity, the amount of waste heat
recoverable from various streams can be:
- by-pass gas: 120-241 MJ/ton of clinker
- cyclone preheater exhaust gas: 388-457 MJ/ton of clinker
- clinker cooler exhaust gas: 345-457 MJ/ton of clinker.
3.2.3 Long term measures
Different long term energy efficiency measures concerning major modifications in the
production process to increase the efficiency of the industry are discussed below.
3.2.3.1 Conversion from wet to dry process
Conversion of wet process to dry process can lead to better energy efficiency and an
increase in clinker output. The conversion may be either full or partial depending upon the
characteristics of the available raw materials. The estimated energy savings due to the
process changes are given in Table 3.3.
Table 3.3. Energy saving due to process changes (MJ/kg clinker)

Action Taken Initial Process New Process Energy Saving
Replace Wet Dry with preheater 1.8-5.0
Convert Wet Dry with preheater 1.8-4.0
Convert Wet Dry 0.8-1.6
Replace Wet Semi-wet with step-type preheater up to 3.0
Convert Wet Semi-wet with step-type preheater up to 2.5
Replace Wet Wet with spray dryer up to 2.5
Convert Wet Wet with spray dryer up to 2.0
Replace Dry Dry with preheater 0.9-2.0
Convert Dry Dry with preheater 0.9-1.5
Note: - Investment cost of about US$ 10 million for 440 tpd wet kiln to 550 tpd, 4-
stage preheater conversion (estimated rate of return: 17%).
- Investment cost of about US$ 95 million for 1500 tpd wet kiln to 4300 tpd
4-stage preheater/pre-calciner conversion (estimated rate of return 20%).
3.2.3.2 Cogeneration
Cogeneration would be attractive for fuel saving and better energy utilization in connection
with the conversion of a kiln from wet to dry process. The temperature of the kiln exhaust
gases is increased from 180-260°C for the wet kiln to around 550-760 °C for the dry kiln so
that steam power generation system is possible with waste heat recovery boilers. Electricity
generation of the order of 50-100 kWh/ton of clinker may be feasible. Cogeneration can
lead to the following benefits:
- facilitate uninterrupted kiln operation
- better fuel efficiency
- lower consumption of refractories
- better clinker quality
- higher kiln utilization
For a cement factory of 1000 ton/day of clinker capacity, the amount of waste heat
recoverable from various streams can be:
- by-pass gas: 120-241 MJ/ton of clinker
- cyclone preheater exhaust gas: 388-457 MJ/ton of clinker
- clinker cooler exhaust gas: 345-457 MJ/ton of clinker
3.2.3.3 Computer-controlled system
In the cement industry, all processes are like a chain, one operation linked to another. The
moisture content of slurry will affect the quality of clinker produced. The amount of fuel
fed to the firing system of the kiln must be proportional to the quantity of slurry fed to the
kiln. If the residence time of mixture in the kiln is maintained at optimum, energy losses
due to overbaking can be avoided. Therefore, it is necessary to control and monitor each
function of the processes involved to ensure that the system is operating at optimum
condition: i.e., minimal energy consumption, maximal output, minimal waste and longest
life of equipment.
A fully automated monitoring and control system developed by Mitsubishi (MICS),

comprising all stages of the process up to the storage of cement, is given in Table 3.4.
3.3 New Energy Efficient Technologies for Cement Manufacturing
In fact, the kiln process technology of cement industry can be said to be at quite a mature
stage. However, due to the nature of gradual development of technologies, some
modifications are still going on. Nowadays, the main area of process improvement is the
grinding of clinker and various designs have been emerging. Automation of the cement
manufacturing and computerization are also the current interests of cement manufacturers.
It is worthwhile to highlight the kiln processes which are undergoing modifications in order
to improve the energy efficiency and environmental soundness of the cement industry.
Table 3.4. Operating ranges, tasks and possibilities of applications of MICS

--------------------------------------------------------------------------------------------------------------
Operating range Tasks and functions of MICS
--------------------------------------------------------------------------------------------------------------
Raw material - blending bed data acquisition and processing
blending bed - controlling the blending of several components
--------------------------------------------------------------------------------------------------------------
Raw mill - raw mill monitoring
- controlling start-up and mill performance
- monitoring the blending silo
- monitoring the conditioning tower and electrostatic precipitator
--------------------------------------------------------------------------------------------------------------
Rotary kiln - kiln monitoring
- kiln control during start-up
- automation kiln control
- automatic measurement of kiln shell temperatures
- calciner monitoring
--------------------------------------------------------------------------------------------------------------
Coal grinding mill - coal mill monitoring
--------------------------------------------------------------------------------------------------------------
Cement Grinding mill - cement mill monitoring
--------------------------------------------------------------------------------------------------------------
Quality control - x-ray fluorescence analysis data processing
- calibrating the analyzers
- controlling the raw material proportioning
- adjusting the raw meal composition
- checking the cement quality
--------------------------------------------------------------------------------------------------------------
Electricity supply - monitoring the electric current and
power consumption
--------------------------------------------------------------------------------------------------------------
Supervision and - daily operational reports on individual sections
documentation of plant
- daily, weekly and monthly reports on
plant performance
- maintaining optimum operation of kiln,
raw mill, cement mill and coal mill
3.3.1 Suspension preheating technology
The suspension system attached to the kiln consists of up to six cyclones (usually four or
five). The mixture of raw material is fed into the top stage which gradually moves through
the cyclones until it enters the rotary kiln. The hot kiln exit gases simultaneously move in
the opposite direction and the highly turbulent mixing action between the feed and gases
promotes efficient heat exchange, sufficient to induce 40-50% calcination of the raw feed
by the time it enters the rotary kiln. A large amount of secondary heat is recovered which
helps to lower the specific primary energy consumption to around 3.15 MJ/kg of clinker.
3.3.2 Suspension preheating/precalcination technology
This system consists of a four stage suspension preheater, a furnace for precalcination and
a rotary kiln. The preheated mixture is precalcinated in the furnace before entering the kiln.
As a result, the raw mix is substantially calcined (up to a maximum of 85-90%) by the time
it enters the kiln. The specific energy consumption is about 3.15 MJ/kg of clinker and the
advantage is up to two-third of the total fuel requirements can be replaced by low grade
fuels. The flow diagram of suspension preheating/precalcination system is shown in Figure
3.5.
Induced draft fan

Raw
material
Material flow
Gas flow
Precalcination
furnace Secondary air duct
Burners
Kiln burner
Kiln Product
Cooler
Figure 3.5. Flow diagram of suspension preheating/precalcination system

3.4 Concluding Remarks
Since the cement industry is an energy intensive high-temperature-process, attention should

be given to the recovery of waste heat from the various exhaust streams. The housekeeping
measures can lead to lower energy consumption as well as proper functioning of processes.
The modification and replacement of sub-processes by adapting advanced technologies can
also save significant amount of energy.
The low grade fuel substitution in cement industry is found to be beneficial both at the
macro and micro levels. The fuel substitution needs strategic planning at the plant
management level as well as institutional support from the national authorities.
Cogeneration and computerization are also the improvements which should be

incorporated along with process conversion. In most industrialized countries, the wet
process has been completely eliminated. The conversion of wet to dry process is the
necessary improvement for developing countries. Therefore, medium and long term goals
should be set to take gradual action in this direction.
4. ENVIRONMENTAL POLLUTION AND MANAGEMENT
4.1 Sources and Characteristics of Pollutants
4.1.1 Water pollution
The largest part of the water used in cement manufacturing is essentially non polluting.
Process water is evaporated and most cooling water is not contaminated. The water
pollution problems originating from cement plants are generally directly related to dust
collection and/or dust disposal. The main sources are:
- raw material washing and beneficiation - produces high pH and alkalinity, total
dissolved and suspended solids
- process water - only in the event of spillage
- dust control - uses wet scrubbers to collect kiln dust from effluent gases.
- dust leaching - dry dust is mixed in a slurry and placed in a clarifier for settling,
the under flow of which is returned to the kiln. The overflow containing high
pH, alkalinity, suspended solids, dissolved solids, potassium and sulfate is
discharged. This constitutes the most severe water pollution problem in the
industry.
- dust disposal - collected dust is mixed into slurry and fed into a pond for solid
settling. Settled solids are not recovered and the overflow (leachate) is
discharged.
Only in exceptional cases, seepage water from dumps or stockpiles will have to be
considered. The process water used in cement manufacturing is required for conditioning
the exit gases or for the treatment of the raw meal in wet-process and grate preheater kilns.
As this water evaporates into the atmosphere, it is therefore not discharged as waste water.
4.1.2 Air pollution
Among the pollution problems associated with cement industry, air pollution is
undoubtedly the most significant one. Making 1 ton of cement requires the grinding of
about 2.5 tons of raw materials, intermediate products and solid fuels to a dust-like
fineness. Furthermore, even with heat-saving methods, about 100-110 kg of coal equivalent
(with a flame temperature of over 1500oC) is needed per ton of cement. Depending on the
process employed and the degree of sophistication of a cement plant, the manufacture of 1
kg of cement gives rise to between 6 and 14 m3 of exhaust air and gas. These quantities of
air and gas have to be cleaned before being discharged into the atmosphere. Besides the
particulate emissions, these gaseous pollutants play an important part in the air pollution.
The gases from the kilns are generally identified as CO, CO2 and nitrogen oxides. Oxides
of sulfur are either absent or present only as a trace quantity depending on the sulfur
content of the coal used and also because sulfur oxides are absorbed in the kiln during the
clinkering process. Hydrocarbons and other organic identities in the exit gases are absent if
coal is used as the fuel.
Environmental Pollution and Management 23
4.1.2.1 Particulates
While there are various sources of dust generation in a cement plant, the kiln generates the
largest quantities of dust and gases. It is well known that the nature and quantity of dust
and gases from kilns depend on the characteristics of raw materials, fuel, process, burning
conditions, kiln dimensions, system used, etc., which in turn govern the choice of the dust
collection system and its efficiency. The largest air pollutants in cement plants are the
particulate emissions, which consist of carbonates, silicates, aluminates, fluorides and alkali
halides, emitted through gasses at temperature of 120-350oC. The chemical characteristics
of the pollutants reflect the raw-mix composition and fuel quality. The use of lower grade
raw materials leads to generation of kiln dust richer in SiO2 and alkali halides. The use of
lower grade limestone also leads to relatively higher quantities of particulate matter and the
particles in this case are relatively small.
4.1.2.2 Gaseous Substances
Beside the airborne emissions (dusts), every combustion process gives rise to gaseous
emission. The nature and quantity of the gases produced are specifically bound up with the
process in question and depend on the fuels, the combustion atmosphere and the
temperature. In firing systems involving direct contact between combustion gases and solid
feed material, the initial materials employed are moreover to be rated among the principal
influencing factors. The exit gases from cement kilns consist mainly of nitrogen oxides,
carbon dioxide, oxygen and water vapor. In addition, they may contain small amounts of
sulfur dioxide, nitrogen oxides, carbon monoxide and organic hydrocarbons. For product
quality and process economy, the burning of cement clinker normally requires an oxidizing
atmosphere and a temperature of over 1500oC in the kiln, so that the exit gases contain
only harmless amounts of carbon monoxide and hydrocarbons, if at all. Gaseous chlorine
and fluorine compounds are not emitted, because they are combined with the alkaline kiln
feed. Highly volatile compounds may eventually be released independently of burning
process.
(i) Sulfur dioxide

Sulfur is introduced with the raw materials and fuels in the cement burning process. The
sulfur compounds in the fuel first of all form SO2. If the raw materials contain pyrite or
organic sulfides, some of these sulfides will oxidize to SO2 at temperatures as low as 450-
600oC, corresponding to the top stages in a preheater. Here, the absorption of SO2 is
extremely low, and a substantial part passes out of the kiln system. In these cases, therefore,
the kiln exit gases will always contain SO2. The sulfur dioxide formed by dissociation and
combustion reacts chiefly with alkalis of the raw materials, giving rise to the formation of
alkali sulfate which is incorporated in the clinker or the dust and thus discharged from the
kiln system. In addition, sulfur dioxide reacts with calcium oxide from the calcimined raw
meal to give calcium sulfate in an oxidizing kiln atmosphere. This reaction is not confined
to the kiln itself, but continues in the conditioning tower and grinding/drying plant, in
which the fresh reactive surface area formed in the grinding process strongly promotes this
reaction in the presence of water vapor. If sulfuric or organically combined sulfur is present
and the excess air is insufficient, SO2 may be released even at relatively low temperatures
from the preheater of the kiln plant. The emission of SO2 can, however, be reduced by
passing the gas through a grinding/drying mill to a conditioning tower. The cement
burning process and grinding process are thus function as ideal desulfurising systems in
which well in excess of 90 percent of SO2 is retained. That is why it is generally possible to
use fuels with high sulfur content in the cement industry without harmful consequences to
the environment. The introduction of a minimum amount of sulfur for combining the raw
material alkalis as sulfate is indeed desirable to achieve better product quality.
(ii) Nitrogen oxides

NO formation takes place by means of two mechanisms. By the first mechanism, the
thermal NO is formed in the kiln burning zone from the content of nitrogen in the
atmosphere. The quantity is determined mainly by temperature and excess oxygen. By the
second mechanism, the fuel NO is formed. In this instance, the content of volatiles and
nitrogen in the fuel, as well as excess oxygen are the deciding factors. The fuel NO
formation is of secondary importance in the burning zone as the temperature at this point
is so high that considerable thermal NO is formed anyway. With secondary firing, as in
precalciners, the fuel NO is of importance. The emissions of nitrogen oxides from the
cement manufacturing process are much more difficult to reduce. For reasons of quality,
the cement kiln has to be operated with high combustion temperatures and excess air;
under these conditions the nitrogen oxide formed is more particularly the thermal NO. Gas
measurements carried out in various parts of the world have revealed widely differing
amounts of NOx emission from cement kilns, ranging from about 150 to over 1000 ppm
(Kroboth et al. 1987). As opposed to what had been found with SO2 emission, there was
no ascertainable elimination of NOx in conditioning tower or grinding/drying plants
associated with the kilns. The reduced concentrations of NOx measured in those
installations was entirely due to dilution with process air. A large number of short-term and
long-term investigations have meanwhile revealed that the following factors are of
qualitative importance to nitrogen oxide formation during the clinker burning process: the
fuel used, the design and operation of precalcining system or the secondary firing methods
employed, the characteristic properties of secondary fuels, the burnability of the feed
material, the flame temperature, the flame shape, the burner or its setting, and the excess air
factor. The variations in the NOx content of the cleaned gas discharged from a kiln plant,
as determined in long-term measurements, are plotted in Figures 4.1.a and 4.1.b. During
the course of the day as represented in Figure 4.1.a the kiln functioned trouble-free,
producing clinker with between 0.7 and 1.2 percent of free lime. The NOx emission
behavior of the same kiln over a long period is shown in Figure 4.1.b.
Fig. 4.1a. Daily variation of NO emissions of a rotary kiln
Fig. 4.1b. Daily variation of NO emissions of a rotary kiln (over a long period)
4.1.3 Solid waste
The major solid waste from cement industry is the dust collected from the air pollution
control equipment. In addition, used refractories are also to be disposed of.
4.2 Current Pollution Abatement Strategy and Technologies
4.2.1 Air pollution control
Pollution abatement in cement industry involves mainly prevention of air and water
protection. By early 1980’s the average specific heat consumption for cement manufacture
steadily decreased due to the change over to energy-saving preheater kilns and to waste
heat utilization techniques. In contrast with the heat consumption, the specific electric
power consumption slightly increased. This is due, among other factors, to the newly built
coal grinding plants and to the increasingly stringent requirements to be fulfilled by
environmental protection. Thus, these factors should be considered when deciding the
environmental standards.
The overall dust emission values can be steadily reduced with the aid of advances in
dedusting technology and of process engineering changes. It has been proved that the dust
emission levels can be reduced not only during normal plant operation, but more
particularly also during start-up and shut-down (Kroboth et al, 1987). For example, in the
case of grate pre-heater kilns, the auxiliary chimney as a source of emission has been
eliminated. Instead, while the grate is stopped, the hot kiln exit gases are so conditioned
with added air and water that even during heating-up and cooling-down of the kiln they can
be dedusted in the kiln’s dust collecting unit. A remarkable decrease in dust emissions in
the vicinity of cement plant can be attained by elimination of the so-called diffuse dust
sources. For this, enclosed buildings and silos for clinker storage have to be build up.
4.2.1.1 Dust collecting devices
It is the physical characteristics, such as total dust load, particle size distribution, bulk
density, electrical resistivity and gas volume which normally determine the selection of
suitable and efficient collection system, as some of these characteristics limit the power
input and collection efficiency. Dedusting equipment in the form of filtering or of
electrostatic precipitating units to reduce dust emission is employed in the cement industry.
Inertia-force separators are now used only for pre-cleaning purposes, e.g., for protection of
fans, or are integrally incorporated in the filter or precipitator systems. Formerly, cyclone
collectors were considered adequate for both kiln stack and cooler stack (principal
particulate emission sources) because they prevented nuisance dust-fall conditions. Now,
however, opacity and discharge weight require more efficient collection equipment. Fabric
filters are generally used for the dedusting of primary crushing operations, materials
handling, raw meal blending and silo discharge operations, whereas grinding and drying
installations (including those for coal) are dedusted with electrostatic precipitators or with
fabric filters. The latter appear to be better suited to cope with transitional and upset
conditions because their functioning is independent of the conditioning of the dust-laden
gases.
For this reason, it is preferable to use fabric filters in every practicable case. Experience in
the cement industry shows that electrostatic precipitators and fabric filters of equally
advanced technical development and suitable design perform equally well with regard to
dust collection efficiency, but not with regard to their behavior in coping with special dusts,
high temperatures and varying conditions of plant operation. In view of these
considerations, electrostatic precipitators have been adopted world-wide for cleaning the
kiln exit gas, whereas for cleaning the air discharged from clinker coolers the dedusting
equipment currently used comprises granular bed filters, fabric filters or electrostatic
precipitators. The gaseous discharge from a dry process kiln contains insufficient moisture
for satisfactory ESP operation unless it has been used to dry the raw material. Its
temperature may be too high, in which case the gases must first be cooled by air dilution,
radiation from cooling loops, or humidification. After humidification, dry process kiln
gases can be controlled by ESP. Bag collectors may be preferred if the gas cooling has been
accomplished by air dilution (which increases the gas volume requiring treatment) or by
radiation. For wet process kilns, the ESP has general acceptance. There are, moreover,
clinker cooling systems which do not produce exhaust air, namely, rotary coolers and
planetary coolers. Furthermore, grate coolers embodying the so-called duo-therm operating
system with intermediate cooling, which do not discharge exhaust air into the atmosphere
either, have proved their suitability. The emission of heavy metals can be kept to very low
values by means of high-efficiency dust collecting equipment and suitable process control.
(i) Cyclone separators

Cyclone separators (mechanical precipitation) utilize a centrifugal force generated by a
spinning gas stream to separate the particulate matter from the carrier gas (Rao, 1994). It
can be used at high temperature and is suitable where coarse particles are present.
Particulates are removed from kiln gases by electrostatic precipitators or fabric bag
collectors, either of which may be preceded by cyclone collectors. Scrubbers have had very
little applications because of the problems in handling particulates which react with water.
(ii) Fabric filters

Because of the modest dimensions, better maintenance possibilities, greater reliability and
lower capital cost, fabric filter systems operating with compressed air (reverse-pulse)
cleaning have gained wide acceptance. Filters with low-pressure or reverse-flow cleaning
are now seldom used.
While fabric filters have no rivals in the dedusting of air from materials handling
equipment, bins and silos, they have, in experience so far gained, not proved satisfactory in
conjunction with kiln plants because of the peak temperatures that occur, the special
properties of kiln dusts and the critical conditions associated with start-up and change-over
operations. Fabric filters have indeed been used, in a very few cases, for cleaning the gases
from heat-economizing preheater kilns. With these kiln systems difficulties arise mainly on
account of the very sticky fine dust particles which rapidly choke the filter fabric, resulting
in high resistance, heavy power consumption and reduced throughput rates. The air
pressure used for filter cleaning is limited by the stresses that the fabric can resist.
Investigations show that the rate of wear rises with increasing air pressure in reverse-pulse
cleaning. Furthermore, for reasons of cleaning and manipulation there are limits to the size
of the filter bags. For these reasons, the fabric filters used in conjunction with big kilns,
with well in excess of 100,000 cubic meters of exit gas to be treated per hour, comprise
thousands of individual bags. On account of this, capital cost and expenditure on repairs
are high. Besides, such filters are difficult to monitor in continuos operation. It is virtually
impossible, with such large numbers of bags, to pinpoint a defective bag and change it
promptly.
(iii) Electrostatic precipitator

The fundamental principle of electrostatic precipitation has remained unchanged for many
years. In matters of detail, however, there have been important developments, in recent
years. As a result, not only has the precipitation in continuos operation been improved, but
also the operational reliability under abnormal service conditions.
Changes in precipitator design, such as greater duct width (wider collector electrode
spacing) and new shapes and materials for the discharge electrodes and collector electrodes,
have resulted in a lowering of cleaned gas dust contents and yielded advantages in terms of
capital cost and maintenance and repair expenses. The technological optimization of the
dust-laden gas admission and conditioning procedures by means of control systems and
process computers, the use of microprocessors for precipitator voltage control and
rapping, and the use of pulse generators have helped to achieve better dedusting during
transitional operating conditions.
The most difficult dedusting conditions in the cement industry often occur in connection
with cyclone preheater kilns. The standard solution for such a kiln, which is usually
operated with exit gas utilization, consists in cleaning the exit gas in an electrostatic
precipitator preceded by a conditioning tower. Since operation with conditioning towers
requires much maintenance, especially with unfavorable dust resistivity, when exit gas
temperatures of 130oC and lower have to be attained, solutions have been devised
comprising separate precipitators for the kiln and mill. In order to reduce cost it has been
endeavored in some cases, by making use of pulse generators, to manage with only one
precipitator despite the absence of a cooling tower (Kroboth et al., 1987). ESPs are
sensitive to gas charecteristics (such as temperature) and to voltage variation. Baghouse is
generally regarded as more reliable in this respect. The overall costs of the two systems are
similar; the choice of system will depend on the flue gas charecteristics and local
considerations.
4.2.1.2 Gaseous emission control
Careful control of excess air in both kiln and calciner is necessary to keep the SO2 and NO
concentration at minimum. To achieve low NO concentration, a high precalciner and low
burning zone temperature should be used. If the kiln feed contains pyrites, SO2 emission is
unavoidable. If the required limits for SO2 and NO concentrations cannot be achieved
within the actual production process, other documented methods must be used, e.g. the
NH3 injection in preheater bottom to remove NO, and lime or limestone scrubbing to
remove SO2, as is practiced in thermal power plants.
The required particulate removal from the kiln and clinker cooler exhausts is 99.9% of all
particulates and 95.5% of particulates that are less than 10 microns in size (PM10). These
removal efficiencies are to be achieved at least 95% of the time that the plant is operating.
In operational terms, these requirements correspond to an emission level of 50 mg/Nm3
particulates under full load conditions. This level is based on values that are routinely
achieved in well run plants (World Bank, 1995).
The following points summarize the key production and control practices that will lead to
compliance with emission requirements:
- give reference to the dry process,
- adopt the following pollution prevention measures to minimize air emissions:
- install equipment covers for crushing, grinding and milling operations,
- use adjustable conveyors to minimize drop distances,
- wet down intermediate and finished product storage files,
- use low NOx burners with optimum level of excess air,
- use low sulfur fuels in the kiln.
- operate control systems to achieve the required emission levels.
4.2.2 Water pollution control
In general, the environmental protection problems associated with water are minor ones in
the cement industry. However, statuary requirements restricting the extraction of water
from available sources or requiring separate treatment of cooling and surface water may
involve substantial capital expenditure (Kroboth et al., 1987). For leaching, the main
treatment and control method involves segregation of dust-contact streams and
neutralization with stack gases followed by sedimentation with recycling and reuse of
wastewater. Devices employed include:
- cooling towers or ponds to reduce the temperature of cooling process waters
- settling ponds to reduce the concentration of suspended solids
- contaminant ponds to dispose of waste kiln dust
- clarifiers to separate solids in dust-leaching operations.
Pollution of waterways caused by storage piles runoff and dust contamination can be
reduced by locating storage piles where storm waters would be contained, paving areas
used by vehicles and frequently building ditches around the plant area draining to a holding
sump.
As stated earlier, very few operations in the manufacturing of cement add pollutants to the
water used. For the most part, with the exception of leaching systems, pollution results
from practices that allow materials to come in contact with water. Pollutant levels can be
greatly reduced or even eliminated by instituting “good house keeping” practice or more
extensive reuse and recycling of contaminated waters.
4.2.3 Solid waste disposal
The treatment and use of the waste materials arising from the production process of the
cement industry generally presents no problems. The dust particles can be added to the
intermediate and end products without impairing their quality and without any
disadvantages to the environment. Problems may arise in special case, however, when
substantial quantities of kiln dust containing heavy metals have to be eliminated and can be
deposited on special waste dumps only after undergoing appropriate treatment.
Furthermore, waste disposal problems are to be expected at cement plants which, in order
to produce low-alkali clinker, are obliged constantly to discard large quantities of kiln dust
and bypass dust. The controlled dumping of such dusts, as is still allowed in some
countries, is bound to increasingly attract the attention of nature conservationists. The
market for this dust (as, for example, fertilizers) are limited, though for some soils it can be
very beneficial. In some recent tests, cement dust has been fed to cattle as a grain
supplement, and the cattle appear to thrive (Sell, 1992). Some has also been used as a filler
in road beds, and as an aggregate in the production of cement blocks. Regardless of these
possible markets, however, the majority must be disposed of in landfill sites.
4.2.3.1 Landfill
Cement dust landfills are not of the “sanitary landfill” type. Usually, they are just old
quarries or similar areas. The relative non-reactivity of these dusts does not demand dirt
cover or similar precautions. The sheer volume of these wastes renders many such
techniques impractical (Sell, 1992). Landfill procedures are costly in numerous respects.
The dust has had a significant monetary and energy investment in its production,
investments that would literally be thrown away if the dust were disposed of. Suitable
locations for landfill sites near plants are getting more scarce as the quantities of waste
grow. Many sites have environmental problems, such as leaching of alkalis from the dust
during rainstorms. The dust is of a very low density, and thus some sites can also be very
dangerous: a person or animal who would accidentally fall into an area recently filled would
sink and soon suffocate, in some locations.
4.3 Other Environmental Considerations in Cement Industry
4.3.1 Noise pollution
Noise sources which have a considerable effect on the overall noise emission are
distributed throughout the plant: the quarry with its mobile machines and crushers which
operates only in day time, the cement grinding plants, the rotary kiln with its grate or
planetary cooler, the gas discharge outlet and vehicular traffic in the cement plant.
With regard to noise control measures in the plant, a distinction is to be drawn between
primary and secondary measures. Primary measures are applied at the machines or other
sources of noise themselves. These are essentially design arrangements, e.g., relating to
teeth of gear systems, fan blades, etc., which can be applied only in new or replacement of
machinery. Suppliers’ guarantees relating to noise emission are now a normal requirement
associated with any order for equipment.
It is furthermore advisable to opt for relatively quiet working methods, e.g., the use of
electric motors instead of internal combustion engines, water-cooled instead of air-cooled
engines, low heights of fall of materials being stockpiled, adequate cushioning material to
reduce impact and rushing noises, and avoidance of locating several noise machines in
close proximity to one another.
Secondary measures such as sound attenuators (silencers), acoustic enclosures, acoustic

walls, etc., reduce sound propagation, as do appropriate structural measures. They are more
particularly suitable for subsequent improvements. Drawbacks associated with their use,
besides extra operating expense due to pressure loss or the need for forced heat dissipation,
may include inconvenience in operating, maintaining and repairing the machinery affected
by these acoustic arrangements. In connection with all such measures, the cost factor which
progressively increases with the degree of sound level reduction achieved, should be
critically examined.
4.3.2 Reduction of ground vibrations
As with noise, problems with adjacent residents may also arise in connection with ground
vibrations in cases where the distance between residential buildings and the cement works
or the quarry diminishes. Vibrations are generated by shock-like or impact-like actions such
as blasting, combination of materials by drop-weights, discharge of clinker from silos,
periodic excitation due to roller mills or out-of-balance rotors. The geological condition of
the subsoil is an important factor governing the propagation of body waves as well as the
frequency composition of the vibrations.
In the absence of precise information on geological conditions, on account of the large
number of factors involved, it is not possible to predict vibration nuisance - as contrasted
with noise nuisance - at some considerable distance from the source. With blasting, the
intensity of the vibration emission can to some extent be controlled by the technique
employed (number and spacing of blast holes, amount of explosive fired, depth of holes,
sequenced delay-action firing), and propagation by the direction in which quarrying
advances.
4.3.3 Raw material resources and site restoration
Quarrying the raw materials needed for cement manufacture involves intervention in
nature and the landscape. Because people have developed a higher awareness to
environmental and nature conservation, it has in many developed countries become
increasingly difficult to extend existing quarries or indeed to start new ones. All the same,
conservation and the need to secure raw material resources must not be regarded as two
exclusive aims. Contrary to the popular opinion, the natural reserves of limestone, marl,
chalk and sand are not inexhaustible, particularly in relation to the sitting of cement plants.
To make arrangements for the long-term supply of mineral raw materials in the requisite
quantities and at acceptable cost is an important economic necessity. Besides the demands
of the natural conservation the demands of maintaining a supply of raw materials must
therefore always be given due consideration.
The cement industry strives to compensate for the unavoidable intervention in the nature
and the landscape by appropriate action to ensure landscape preservation and site
restoration. In deciding how the site is to be restored and what its subsequent utilization
will be, there are many viewpoints to be considered. The natural features of the quarry are
especially important. The quarrying operations should be so conducted that the mineral
deposits can be utilized as fully as possible. Based on this principle, it can be analyzed what
potential there exists for subsequent utilization and for what purposes the sites can be
practicably and meaningfully used in each particular case. Some of the possible utilization
paths are:
- agricultural and forestry;
- industrial use;
- municipal use;
- traffic and transportation;
- leisure and recreational use.
Besides utilization for specific purposes, planned natural restoration has been gaining in
importance in recent years. For this purpose, worked-out quarry sites are intentionally
“given over to nature” within the planning context, so that suitable habits for animal and
plant life (biotopes) can develop. These may be pools or ponds and marshy areas or tips,
slopes and escarpments, as well as edge zones, offering undisturbed living conditions for
many species of plants and animals.
4.3.4 Utilization of waste as raw material and fuel in cement industry
Because of the special features of the cement burning process - the strongly alkaline feed
material, kiln charge and kiln dust, oxidizing kiln atmosphere, temperature distribution in
the burning system, and the intimate contact between the solids and gases in the kiln - it is
possible, on the one hand, to employ waste materials as fuel and, on the other hand, to add
waste materials to the raw mix or the cement. The cement industry can thus make an
important contribution to the disposal of wastes arising from other sectors of industry.
The use of waste materials as “junk fuel” (waste-derived fuel) in the clinker burning process
is subject to limits due to requirements of environmental compatibility, product quality, and
economy in relation to primary fuels.
Such materials may be fired in a finely ground condition or in lump form. The feed-in
points for these fuels are the main firing system in the precalciner or the riser duct of the
cyclone preheater, the kiln inlet or the hot gas compartment of a grate preheater kiln, or as
an inter-ground admixture to the kiln feed meal.
The kiln inlet (feed end) can be used for this purpose only in plants equipped with
preheaters. The waste-derived fuels fed into the system at this point are mostly in the form
of coarse lumps. They may consist of scrap motor tires, rubber shreds, shredded
household refuse, compacted refuse, or textile and wood wastes. However, finely divided
waste materials such as acid sludge, low-grade coal and oil shale may also be fed in here.
As numerous measurements have shown, with proper process control the firing of these
waste-derived fuels does not cause any increase in emission of environmentally relevant
pollutants. Emission of dioxins and furans have received special attention because they
have been identified in the stack gases from number of solid waste incinerators. However,
survey of test results from trial burns at cement kilns indicates that emissions of dioxins
and furans from these facilities are not significant. When dioxins and furans have been
observed, they appear to be three orders of magnitude less than those reported for
municipal incinerators. Moreover, there is no change in dioxin or furan emissions due to
the use of waste-derived fuels. If waste materials with a high sulfur or chloride content are
used as fuels, attention must be paid not only to the quality of the clinker and cement
produced, but also more particularly to the process engineering requirements of kiln
control. It is advantageous to carry out an emission prognosis to ascertain what quantities
of waste-derived fuels can permissibly be used.
The waste-derived fuels currently used in USA and European cement plants are primarily
waste oils and spent organic solvents from the following industries: paint and coatings,
auto and truck assembly, solvent reclamation, ink and printing, cosmetics, toy, medical and
electronics. The following environmental and economical benefits can be achieved when
wastes are destroyed in a cement kiln:
- combustion gas temperature and residence time in kilns are much greater than
those encountered in commercial incinerators. The sustained high combustion
gas temperatures, combined with intense turbulence ensure efficient destruction
of even stable organic compounds. The gas in the burning zone of a kiln reaches
2000oC for a period of approximately three seconds, while an incinerator
achieves its maximum temperature for about half that time.
- the kiln contents are alkaline and can trap hydrogen chloride formed during
combustion of chlorinated wastes. Most of sulfur oxides are similarly trapped as
calcium sulfate.
- ash resulting from incombustible material such as metals in waste becomes

incorporated in the clinker, eliminating disposal problems.
- there is no significant change in emissions from cement kilns when waste-

derived fuels are used, and new emissions from the operation of an incinerator
are not added to the atmosphere when waste-derived fuels are used to replace
fossil fuel in an existing cement kiln.
- replacement of imported fuel or conservation of non-renewable resources by

waste-derived fuels for coal, coke and natural gas.
- a reduction in manufacturing costs through the recovery of the energy value of

wastes which would otherwise be lost. Waste fuels typically have a heat value of
24 GJ/t which is somewhat less than coal but are available at a fraction of the
cost.
In connection with the conversion of coal-fired power stations to environmentally

innocuous firing methods rapidly increasing quantities of fly-ash and gypsum are becoming
available from the flue gas desulfurization treatment now applied in many parts of the
world. Due to the lack of adequate dumping spaces and also because of their content of
various environmentally relevant substances that can be washed or leached out, the disposal
of these materials is encountering major difficulties. Under certain conditions the cement
industry can contribute to solving these problems. Thus, in a number of countries the
requirement applicable to fly-ash and flue gas gypsum and to their use in cement
manufacture have been embodied in national codes and standards.
4.4 Concluding Remarks
Since air pollution is a major concern, priority in the cement industry is to minimize the
increase in ambient particulate levels by reducing the mass load emitted from the stacks,
from fugitive emissions, and from other sources. Collection and recycling of dust in kiln
gases is required to improve the efficiency of the operation and to reduce the atmospheric
emissions. NOx levels should be controlled by adjustment of the kiln burner and use of an
optimum level of excess air. For control of fugitive particulate emissions, ventilation system
should be used in conjunction with hoods and enclosures covering transfer points. Drop
distances should be minimized by use of adjustable conveyors. Mechanical systems such as
cyclones trap the larger particulates in kiln gases and act as preconditioner for downstream
collection devices. Electrostatic precipitators and fabric filter system are the principal
options for collection and control of fine particulates.
Storage and waste areas should be wetted-down to reduce dust generation from these
sources. Appropriate storm-water and run-off control system should be provided to
minimize the quantities of suspended materials carried off-site. Alkali dust removed from
the kiln gases is normally disposed of as solid waste, but it may be possible to reuse a
portion for agricultural liming.
5. CROSS-COUNTRY COMPARISON OF THE CEMENT SECTOR
5.1 Introduction
The cement demand has been increasing in the developing countries along with the rapid
development of infrastructure. In the favor of abundant resources, the developing
countries have been producing cement without taking much care of the process energy
consumption. As a capital intensive industry, the main difference between the industrialized
economies and developing countries is the average size of the mills. The small mills
predominate in developing countries with 1.5 to 2 times higher specific energy
consumption in comparison with the industrialized countries. Besides the scale of the mills,
there are various other factors which lead to the inefficiency of energy use in the cement
industry.
Production of cement involves a lot of grinding of raw materials, intermediate products

and fuel to pulverized form, and generates air pollutants. As the industry in this region still
operate with obsolete technologies, the wet process dominates as the process technology in
some of the countries, which creates water pollution in addition to the air pollution
problems. As for the case of energy, mill size also plays a role in the inefficiency of
pollution abatement
This paper presents a comparative study of the cement industries in China, India, the
Philippines and Sri Lanka to point out the major causes of energy inefficiency and pollution
problems, and to identify the improvements and potential application of energy efficient
and environmentally sound technologies.
5.2 Overview of the Industry
5.2.1 Role in the national economy
In 1989, the Indian cement industry accounted for 1.8% of total output of manufacturing
economy and 0.23% of the gross domestic product.
5.2.2 Share in total energy consumption
In 1990, energy consumption of Chinese cement industry accounted for 6.6% of the total
industrial energy consumption and 3.5% of total national energy consumption.
In 1990, Indian cement industry had a share of over 10% of the industrial sector’s coal
consumption and over 6% of the industrial sector’s electricity consumption.
Profile of the Cement Industry in Asian Industrializing Countries 37
In 1992, the energy consumption of the cement industry represented 16.73% of industrial
sector’s energy consumption and 4.95% of total national energy consumption in the
Philippines.
5.2.3 Production trend

Among the countries under study, China is the world’s largest cement producer. Both
China and India are cement exporting countries. The trends of cement production in the
countries under this study are shown in Figure 5.1.
400
350
Cement (Million Tons)
300
250
200 China
India
150
100
50
0
1980 1985 1986 1987 1988 1989 1990 1991 1992 1993
Years
Philippines' Cement Production Sri Lanka's Cement Production

10 1
8
Million Tons
0.8
Million Tons
6 0.6
4
0.4
2
0.2
0
0
1980 1985 1991 1992 1993
1970 1980 1990 1992
Years Years
Figure 5.1. Trends of cement production
From the figure, it can be seen that the cement production of China has been increasing
very rapidly since 1990. The average growth rate of cement production was about 11%
from 1985 to 1993 and 20.6% from 1990 to 1993.
The production of Indian cement industry has been gradually increasing and the average
growth rate has been about 7.25% from 1985 to 1993.
In the Philippines, the cement production in 1993 was more than 2.5 times that in 1985.
The production is expected to grow at the rate of 5.6% annually up to year 2000.
In Sri Lanka, the cement is produced from the cement plants as well as clinker grinding
mills which use imported clinker as input material. The production of cement has been
significantly increasing at an average growth rate of 6.04% since 1980 along with the
increase in imported clinker. The production trends of clinker and cement in Sri Lanka are
compared in Figure 5.2 to assess the role of imported clinker in cement industry.
1000
Clinker
Cement
800
Thousand Tons
600
400
200
0
1970 1980 1990 1992
Figure 5.2. Trends of clinker and cement production in Sri Lanka
5.2.4 Mills and capacities
The cement industry of China is characterized by a number of small mills with manual or
mechanized shaft kilns. In 1992, there were totally 6,177 mills of which, only 79 were large
and medium size mills with capacity exceeding 0.3 million tons per year.
In 1989, there were 558 factories in Indian cement industry including both cement mills
and clinker grinding mills. In 1992, 97 mills produced both clinker and cement, 2 mills
produced only clinker and the rest were clinker grinding mills.
The breakdown of cement mills which produce both clinker and cement by plant capacity,
is given in Figure 5.3 for China and India. The average capacity of mills in China is too
small. Although the average capacity of Indian cement mills is larger than that of Chinese
mills, it is still small in comparison with the developed countries. About 87% of Indian
mills are under the annual plant capacity of 1 million tons of cement. However, In Japan,
over 88% of the mills have the plant capacity of more than 1 million tons of cement per
year and over 50% of the plants are mills with plant annual output exceeding 2 million
tons of cement.
There are 18 cement plants in the Philippines with a total capacity of 7.4 and 9.5 million
tons of clinker and cement per year respectively, leading to an average plant capacity of
about 5.5 million tons of cement per year.
India
China
1.28% 46.4% 2.1%
7.2%
4%
98.72%
40.2%
>0.3 <0.3
2-2.5 1.5-2 1-1.5 0.5-1 <0.5
Figure 5.3. Breakdown of mills in China and India by capacity

(million tons of cement/year)
There are 5 cement mills in Sri Lanka, two of which are clinker grinding factories
producing 409 and 891 million tons of clinker and cement respectively in 1992.
The plant utilization factors for China, India and the Philippines are compared in Figure
5.4. The low utilization factors are mainly due to old equipment employed.
90
86
85 83
Utilization (%)
80 79
76
75
70
65
China * India Philippines Sri Lanka
* 1991 data
Figure 5.4. Plant utilization factors in 1993
In China, the number of small mills (<0.3 million tons of cement/year) has been increasing
very rapidly since 1970 until 1987. The trends of share of small mills in total production is
given in Figure 5.5. Although the cement production has been significantly increasing since
1990 (Figure 5.1), the share of small mill remained constant. Therefore, it can be said that
there has been a slowdown in the growth of small mills at the cost of medium and large-
size plants.
90
80
% of Total Production
70
60
50
40
30
20
10
0
1970 1980 1985 1986 1987 1988 1989 1990 1991
Figure 5.5. Share of small mills in Chinese cement production
In India, the small units in private sector and large mills in public sector have been growing
in parallel. The shares of private sector and public sector in total cement production are
given in Table 5.1.
Table 5.1. Shares of private and public sectors in India (% of total production)
1977 1983 1991 1992
Private Sector 90.08 83.90 89.80 89.60
Public Sector 9.92 16.10 10.20 10.40
5.3 Characteristics of the Parameters affecting Energy Efficiency
The major parameters which affect the specific energy consumption of the cement industry
are:
- Control on raw material mixing
- Process mix (dry, wet, semi)
- Degree of precalcination
- Level of waste heat recovery
- Product mix, etc.
The specific energy consumption of the cement industries in selected countries are shown
in Figure 5.6.
It can be seen that the specific energy consumption of Chinese cement industry is nearly
twice as much that of former west Germany. The trends of specific energy consumption in
selected countries are shown in Figure 5.7.
5
MJ/kg of Cement
0
China Philippines Japan
Figure 5.6. Specific energy consumption of cement industry
6
MJ/kg of Cement
0
1980 1985 1986 1987 1988 1989 1990 1991 1992 1993
China India Philippine Japan
Figure 5.7. Trends of specific energy consumption
The curve of specific energy consumption of Chinese cement industry is quite flat.
Although the specific energy consumption of Indian industry has been decreasing, it has
become slower in the recent years and still remain higher than that of developed countries.
To understand the major causes of inefficiency in cement industries of the countries under
this study, some parameters which have influences on the energy consumption are
compared.
5.3.1 Process-mix
The cement production process-mix is one of the important parameters affecting energy
efficiency of the industry since wet process consumes about 1.5 times more energy than the
dry process. Although the manual and mechanized shaft kilns have been completely
eliminated in industrialized countries, they are still used in developing countries, especially
in China. The wet process is also no longer in use in the industrialized countries. The
shares of cement production processes are given in Table 5.2.
Table 5.2. Total cement production and share of processes (%) in 1993
China India Philippines Sri Lanka Japan
Dry Process 9 82 51 100 100
Semi Processes n.a 2 9 0 0
Wet Process n.a 16 40 0 0
Manual/Mechanized 80 0 0 0 0
Shaft Kilns
Total Production 367.88 57.96 7.96 0.89* 88.25*
(Million Tons)
* 1992 data (source: ESCAP)
The share of advanced dry process in China is considerably low, leading to inefficiency of
energy use in the cement industry. One of the major achievements of Indian cement
industry is continuous increase in the share of dry process. However, the specific energy
consumption of Indian cement industry is still high. One reason for the high specific
energy consumption could be the use of low-grade fuel in the kiln. The trends of different
processes in Indian cement industry are given in Table 5.3.
Table 5.3. Trends of shares of cement production processes in India

Processes 1960 1970 1980 1992-93
Dry 1.1 21.5 32.7 82.0
Semi 4.5 9.0 5.7 2.0
Wet 94.4 69.5 61.6 16.0
5.3.2 Average kiln size
Clinker production in kiln is a high-temperature process and about 55-85% of total energy
input is consumed in this process. The recovery of waste heat from the exhaust stream of
kilns is an influential factor on specific energy consumption of the cement industry. The
recovery of waste heat would be more economic in case of large-size kilns. The average size
of rotary kilns are compared in Figure 5.8.
1200
1000
'000 Tons of Clinker/yr 1000
800
600
400
240
200
90
0
China India Japan
Figure 5.8. Average capacity of rotary kilns
The vertical kilns are no longer in use in Japan. The average size of vertical kilns is 30
thousand tons of clinker per kiln per year in both China and India.
5.3.3 Energy consumption by type
The specific consumption of two types of energy sources, thermal energy and electricity,
are given in Table 5.4 for selected countries by different processes.
Table 5.4. Specific thermal and electrical energy consumption

China India Philippines Sri Lanka Japan
Thermal Energy (MJ/kg Clinker)
Dry Process 4.85 3.8-4.4 4.2 4.35 3.0
Wet Process 6.04 5.9-6.8 7.5 - -
Mechanized Shaft Kiln Process 4.90 n.a - - -
Electricity (kWh/ton cement) 110 120-130 130 130 96
Although the dry process predominates in Indian cement industry, the higher specific
thermal energy consumption of dry process would be one of the major causes of high
overall specific energy consumption. The specific electricity consumption of developing
countries is significantly higher than that of industrialized countries. In fact, the higher
electricity consumption is due to the inefficient grinding of raw materials and clinker.
5.3.4 Awareness on energy conservation
Some of the energy conservation measures which have already taken place are summarized
in the Table 5.5.
The table shows that, some advanced technologies have already been implemented in the
developing countries. However, the dissemination rate of these technologies is quite low in
comparison with the industrialized countries.
Table 5.5. Energy conservation measures already undertaken

Country Energy Conservation Measures
China - Closing and converting manual vertical kilns to mechanized kilns
- Premix control of raw materials and fuel
- Raw material ingredient and uniformity control
- Improving raw material grinding facilities
- Conversion of wet process kilns to semi or dry process kilns with
suspension preheating systems
- Introduction of precalciner facilities
- Computer controlled kiln operation
- Improving clinker grinding facilities
India - Installation of raw material composition control equipment
- Improving the raw materials and clinker grinding
- Computer controlled fuel feeding
- Installation of high efficiency burners
- Installation of secondary firing system
- Waste heat recovery through cogeneration boilers
- Improving house-keeping measures
- Dust recycling system
- Power factor improvements
- Combustion control
- Installation of logic controller for sequential starting and process
optimization
- Introduction of precalciner facilities
- Installation of high pressure roller mills
Philippine - Fuel switching from bunker oil to coal
s - Conversion of direct to indirect firing system
- Rehabilitation of small capacity kilns to achieve rated output
- Installation of precalciner
- Rehabilitation of clinker cooler
Sri Lanka - Insulation improvement and house-keeping
5.4 Characteristics of the Parameters Affecting Pollution Abatement Measures
In new , environmental concerns are for air pollutants such as dust, SOx and NOx. The
cement industry being very capital intensive, many plants continue to use the old wet
process. As a result, water pollution is also a major concern in those industries. Apart from
water pollution from raw material preparation, use of wet scrubbers in many plants also
add additional water pollutants. But the wet scrubbers allow to reduce the presence of NOx
and SOx in exhaust air.
5.4.1 Causes of the pollution problems
In general very limited attention is paid to abate pollution in these countries. The causes for
the pollution are attributed to the following:
- Poor quality of raw material
- Sulfur rich and coal based fuel usage for energy need
- Huge number of small scale industries
- Capital intensive equipment for pollution abatement/process modification
- Non availability of spare parts for pollution abatement equipment in local market
- Lack of awareness of the economical benefits achieved through pollution
abatement
5.4.2 Current pollution control strategies
As seen from the process mix from Table 5.2, China and the Philippines should have
serious pollution related to both air and water due to the less share of dry process in total
production. But in case of India and Sri Lanka, the major concern is air pollution because
of the predominance of dry process in the total production. Following are the reported
activities related to pollution abatement in the countries under study.
5.4.2.1 Pollution control strategies in China
During the period of 1991 to 1993, while the number of units increased by 21%:
- Wastewater discharge increased only by 10%
- Wastewater discharged directly to natural water bodies increased to 72% from
69%
- Wastewater reaching regulatory standards increased from 67% to 69%
- Dust discharge decreased to 0.9% from 1.14% of total cement production
- Waste gas purification rate increased to 76% from 67%
- Percentage of SO2 removal increased to 7% from 5%
- Percentage of dust removal increased to 78% from 76%
According to a study carried out in 1993, new generation suspension preheater kilns emit
less dust, NOx and SOx than other conventional kilns. A case study was carried out in 1993
to realize the feasibility of pollution abatement and energy conservation by converting wet
process to dry process.
5.4.2.2 Pollution control strategies in India
Different emission standards were set up considering the location and capacity of the
plants. To meet these emission standards, advanced dust collection systems such as
electrostatic precipitator and fabric filters are used. Following were identified as some
constraints for pollution abatement:
- Poor quality of coal
- Non availability of the spare parts for pollution control equipment
- Non availability of trained man power
- Problems in installing new dust collectors due to layout constraints
- The ash content of coal varies from 22-45 %, leading to high concentration of CO
emission which in turn creates the danger of explosion in ESPs
- Frequent voltage fluctuations and unscheduled power cuts affect ESP operation.
5.4.2.3 Pollution control strategies in the Philippines
Environmental protection regulation was published in 1978, which includes air quality,
water quality and noise level control. Regulations in the Philippines are not stringent as
those in Taiwan and Japan. About 24% of the production units in the industry have no
dust collector. Absence of dust collectors is very common in crusher and raw material drier
sections. In early 80’s all cement plants were converted to coal firing system.
5.4.2.4 Pollution control strategies in Sri Lanka
All mills are provided with ESPs and fabric filters for removal and recycling arrangements
for dust but no stand-by units are available. So during maintenance of the equipment, dust
is discharged into the atmosphere without any control.
5.4.3 Comparison of effluent and emission characteristics
A comparison of water consumption and quantity and characteristics of wastewater with

German standards is made in Table 5.6. In most cases, data are not available even though it
is an important polluting industry. Especially India and Sri Lanka do not have any data
related to water pollution. It can be attributed to diminishing trend of wet process in India
and non availability of wet process in Sri Lanka.
A similar comparison for air emission is shown in Table 5.7. Even though data are available
related to air pollution, comparison is not possible in most cases because of the different
basis. Though dust emission standards in India and Philippine are very close to each other,
they are ten times higher than the German regulatory standards.
Table 5.6. Quantity and characteristics of wastewater released

Parameters Germany * China India Philippines Sri Lanka
Water consumption
(ton/ton cement produced)
Wastewater discharged
(ton/ton cement produced)
pH 6-8.5
Suspended solids (mg/l) 100 75
Settleable solids (ml/l) 0.3
DS (mg/l)
BOD5 (mg/l)
COD (mg/l) 150
Oil and Grease (mg/l)
Total N (mg/l)
Cyanide (mg/l)
Heavy metals (mg/l)
- Cr 0.3
Wastewater reuse rate (%)
Treatment rate of wastewater (%) 76
Proportion reaching discharge 68.6
standards (%)
Hydro carbons (mg/l) 10
* The German regulatory standard for lime, sand and stone related industries
Table 5.7. Quantity and characteristics of air pollutants released

Parameters Germany* China India Philippines Sri Lanka
Dust discharged (TSP) (mg/m3) 30 25-30** 150-400 300
SO2 (mg/m3) 100 1.81** 732 4100
NOx (mg/m3) 500 260-1800# 3000
CO (mg/m3) 100
Organics (mg/m3)
Heavy metals (mg/m3)
Treatment rate of waste gas (%)
Rate of treated waste gas discharged
which meet standards (%)
* The German regulatory standard for lime, sand and stone related industries
** in kg/ton cement produced
# depending on the type of kiln in ppm
5.5 Potential for Energy Efficiency Improvements
5.5.1 Measures on the structure of the industry
One of the major energy conservation measures in Japan was the closing of small and
medium sized low productivity plants. As a capital intensive industry, the closure of all
small plants and installation of large mills is not a feasible solution for developing
countries. However, the future expansion of mills should be done in a planned manner.
The growth of inefficient small mills should be restricted, especially in China, to achieve
the lower specific energy consumption of the industry. Since the cement industry requires
great amount of raw materials, the transportation cost and geographical condition of a
particular country would greatly influence the selection of a mill capacity. The future mills
should be equipped with energy efficient technologies.
The privatization of some inefficient public mills could also help to improve the energy
efficiency of the cement industry in developing countries.
5.5.2 Potential of energy conservation measures
The present standard of a modern energy efficient cement plant in developed countries
consists of the following process technologies:
- raw meal preparation using roller presses and/or vertical mills with high efficiency
separators and with dryer system based on heat recovery from the cyclone tower.
- clinker burning in a short rotary kiln with 5-6 stages preheater cyclone towers and
precalciner. Clinker heat should be recovered as secondary and tertiary preheated
combustion air for the kiln and the precalciner respectively.
- cooling of clinker in a grate cooler.
- grinding of clinker in a modern semi-finish or finish system consisting of roller
presses, high efficiency separator and a final ball mill.
As horizontal technologies, the use of low grade fuel, higher level of waste heat recovery
and cogeneration can be seen in a modern cement mill.
Therefore, the potential of energy savings can be estimated by assuming that all the
facilities would be upgraded to the best available technologies mentioned above. However,
the applications of new and energy efficient technologies are site specific and detail
feasibility studies should be carried out on a case by case basis.
The potential of major energy conservation measures for the countries under this study are
given in Table 5.8.
Table 5.8. Potential of energy conservation measures #

Energy Conservation Measures China India Philippines Sri Lanka
Short Term Measures
- Management practices **** *** *** ***
- Control of slurry water content **** ** *** -
- Combustion air control **** *** *** ***
- Control on composition of raw materials *** *** *** ***
- Insulation improvement of kilns *** *** *** **
- Power factor improvement **** *** *** ****
Medium Term Measures
- Dust recycling system **** *** *** ****
- Reduction of water content of slurry ** **** *** -
- Installation of dual firing system **** *** **** ****
- Retrofitting mechanized kilns **** - - -
- Introduction of suspension preheater and **** **** **** ****
precalciner
- Installation of high pressure roller mills **** **** **** ****
- Waste heat recovery **** **** **** ****
Long Term Measures
- Conversion of wet to dry process with *** ** **** -
suspension preheater systems
- Cogeneration *** **** **** **
- Computerization **** **** **** ****
# Note: For each energy conservation measure, the relative scope of application is shown
by the number of asterisks. For instance, conversion of wet to dry process has a higher
scope in Philippines where the share of wet process is 40% of total production than in
India where it is only 16%.
5.6 Potential for Pollution Abatement
For an energy intensive industry with basically coal as the main energy source, any
reduction in energy consumption itself is a pollution abatement measure. Apart from that,
recovery and recycling of dust reduces not only the pollution load on the environment, but
also the specific energy consumption. Some of the potential pollution abatement measures
are listed in Table 5.9. Though the measures mentioned in the table can contribute to
pollution abatement, some of them also contribute to specific energy reduction. The
measures are however listed only in case when they contribute directly to pollution
abatement.
Table 5.9. Potential for pollution abatement measures #

Pollution Abatement Measures China India Philip Sri Lanka
-pines
Short Term Measures
- Management practices **** *** **** ****
- Good house keeping **** *** *** ***
- Operating at optimized parameters **** *** *** ***
- Full capacity utilization *** *** *** ***
- Rigorous implementation of environmental regulations *** *** *** ***
- Excess air control in combustion **** *** *** ***
- Control water content at optimum for wet process *** * ** -
Medium Term Measures
- Use of low sulfur fuel *** *** *** ***
- Conversion of wet process to dry process **** ** *** -
- Add suspension preheater and precalciner to dry process **** *** *** -
- Dust recycling system *** *** *** -
- Elimination of wet scrubbers *** *** *** -
- Add ESPs and fabric filters to dust collection system *** *** *** -
- Use of dual firing system *** *** *** ***
Long Term Measures
-Use only dry process with suspension preheater and precalciner
system *** ** *** -
- Elimination of small scale plants **** *** *** **
- Improved process control by expert system and sensitive NOx
analyzer **** **** **** ****
# Note: For each pollution abatement measure, the relative scope of application is shown
by the number of asterisks as in Table 5.8.
5.7 Conclusion
The potential of energy saving in the cement industry is considerably high in the
developing countries where the small mills and outdated technologies dominate. Even in
European countries, the theoretical saving estimated was about 13% of the current total
consumption in the cement industry.
The conversion of wet to dry process, closure of inefficient small mills, higher
dissemination of preheating and precalcination technologies and improving the grinding
facilities of raw materials and clinker could result in significant energy savings in developing
countries. The substitution of low grade fuel, increased level of waste heat recovery and
cogeneration also provide major energy saving opportunities. One of the major barriers to
harness the new energy efficient technologies is the lack of data at both micro and macro
levels. Therefore, installation of measuring equipment in production processes and regular
acquisition and updating of data would be the first step to improve the energy efficiency of
the cement industry.
As far as the national authorities are concerned, the required cooperative actions to
improve energy efficiency in cement industry are the followings: provide information about
projects where new energy efficient technologies have been implemented successfully;
create a better condition for technology transfer from industrialized countries and set up
dissemination strategies for each efficient technology.
6. PROFILE OF THE CEMENT INDUSTRY IN SELECTED ASIAN

COUNTRIES
This section evaluates the current status and technological trajectory of the cement industries in
four Asian countries, namely China, India, the Philippines and Sri Lanka.
6.1 COUNTRY REPORT: CHINA
6.1.1 Introduction
China is a developing country with a huge population. In recent years, China’s economy and the
people’s living standard have increased very rapidly. The high economic growth caused a high
demand for energy and the primary energy consumption increased by 85% from 1985 to 1993,
with an average annual growth rate of 4.9%. The building material industry is known as a big
energy consumer and its total energy consumption has amounted to 119 million tce, representing
over 10% of the total energy consumption of China in 1990. The energy consumption by cement
manufacturing is about 35% of the building material industry. It has high energy intensity per unit
product and low energy efficiency of equipment. The discharge of waste gas, residues and water
is 910,500 million m3, 3.09 million tons (Mt) and 252.56 Mt, respectively. It is very important to
improve production technologies and aggrandize energy efficiency for the reduction of
environmental pollution.
6.1.2 Technological trajectory of China’s cement industry
China’s first cement plant was built in 1889 just 18 years after the first Portland cement plant of
the USA started its operations. The manual shaft kiln was adopted in the plant. By the 1930s,
most existing plants with waste heat recovery generation kilns moved in from Japan, and by the
1950s, the wet process (identified with the technological development of the world at that time)
had been adopted in most cement plants. A small number of cement plants adopted the Libor
kilns, also considered to be an advanced technology. Meanwhile, the country started to
manufacture complete sets of wet process equipment for export to other countries. It is said that
by the end of the first Five-Year planning period, China was at par with the developed countries
in terms of technology in the cement industry.
In the international level, the technology for suspension preheating (SP) kilns was being
perfected. Two difficult problems, the adaptability of strong basic material and the recovery of
waste dust, had been solved with the new technology. SP kilns with high thermal efficiency was
developed and the first large SP kiln which produced 1800 tons clinker per day was built up in
1965. This had a larger capacity than the long wet kiln developed in 1970. From then on, the dry
process has been adopted in the production of cement, and due to the keen competition in the
cement industry in the 1970s, the mechanized shaft kilns in the developed countries were finally
eliminated.
Profile of the Cement Industry in China 53
As opposed to the technological trends of cement production in the first world, China had been
developing small cement plants with shaft kilns since the second Five-Year Plan, and most of
these were manually-operated shaft kilns. The technological gap between the advanced nations of
the world and China became increasingly wider.
Brought about by this situation, the Chinese government has done a lot both in the development
of the building material industry and improvement of energy efficiency since the 1980s. After
1985, China has become the biggest cement producing country in the world. From the following
tables one can follow the development trajectory of the country’s cement industry and its
characteristics.
6.1.2.1 Higher growth rate of production
Tables 6.1.1 and 6.1.2 show the GDP and cement production growth rates, respectively. The
cement production grew at an average rate of about 11% from 1985 to 1993, higher than that of
the GDP (about 9.2%).
Table 6.1.1. The index and growth rate of GDP from 1978 to 1993 in China
Year GDP Index GDP growth rate (%) Year GDP Index GDP growth rate (%)
1978 100.0 1988 251.3 11.4
1979 107.6 7.6 1989 262.2 4.3
1980 116.0 7.8 1990 272.4 3.9
1985 187.4 12.9 1991 294.2 8.0
1986 203.3 8.5 1992 334.2 13.6
1987 225.6 11.0 1993 379.0 13.4
Source: Statistical Yearbook of China, 1994 (The growth rate is calculated from the
index)
Table 6.1.2. Cement production (Mt)

Year Production Growth rate (%) Year Production Growth rate (%)
1960 15.65 1987 186.25 12.06
1965 16.34 4.4 1988 210.14 12.83
1970 25.75 57.6 1989 210.29 0.07
1975 46.26 79.7 1990 209.71 -0.3
1980 79.86 72.6 1991 252.61 20.46
1985 159.55 99.8 1992 308.22 22.01
1986 166.06 4.08 1993 367.88 19.36
Source: Statistical Yearbook of China, 1994
6.1.2.2 Rapid increase of small size cement plants
Because of the high demand for cement, many small size cement plants have been built through
township and village enterprises. By the end of 1991, a total of 6177 enterprises had cement
production licenses. There are only 66 large-medium size plants. Small size plants have lesser
investments and have short construction periods. Consequently, they have low product grades
and productivity. Table 6.1.3 shows the mix of production in the cement industry.
6.1.2.3 Production satisfies the internal demand
In the middle of the 1980’s, China had to spend a large amount of money to import cement to
satisfy the internal demand. Now, China has become a net exporter of cement, although the
consumption level of cement per capita is very low compared with other developed countries.
Figure 6.1.1 and Tables 6.1.4 and 6.1.5 show the per capita cement consumption of China.
Table 6.1.3. Cement production mix

Year Installed Total cement Production by large- Proportion of Production
capacity production medium size plant large-medium size of clinker
(Mt) (Mt) (Mt) plant (%) (Mt)
1960 15.65 11.01 70.35
1965 18.65 16.34 11.06 67.69
1970 33.98 25.75 15.17 58.91
1975 57.52 46.26 19.09 41.27
1980 86.80 79.86 25.58 32.03
1985 153.43 159.55 32.35 20.28
1986 177.20 166.06 32.35 19.48
1987 204.67 186.25 33.89 18.20
1988 232.24 210.14
1989 252.64 210.29 35.45 16.87
1990 268.89 209.71 39.86 19.01 154.9
1991 293.95 252.61 42.50 16.82 186.5
1992 308.22 85.99 27.90
1993 367.88 86.91 24.36
Sources: Statistical Yearbook of China, 1994
Statistical Yearbook of Building Material Industry 1991,1992
6.1.2.4 Better product quality and low energy intensity
Table 6.1.6 shows the trajectory of the main techno-economic indicators of the cement industry.
The heat intensity of clinker has declined due to successful achievements in energy conservation.
The energy intensity, however, is still quite high and there is a large potential for improvement.
350
300
250
kg/capita
200
150
100
50
0
60
65
70
75
80
85
86
87
88
89
90
91
92
93
19
19
19
19
19
19
19
19
19
19
19
19
19
19
Year
Figure 6.1.1. Cement consumption per capita
Table 6.1.4. Cement resource balance table of China

Year Cement Import Export National Consumption
production (Mt) (Mt) consumption (kg/capita)
(Mt) (Mt)
1960 15.65
1965 16.34 0.31 1.02 15.63 22
1970 25.75 0.08 0.43 26.42 32
1975 46.26 0.43 0.91 45.78 50
1980 79.86 1.32 1.00 80.18 81
1985 159.55 3.66 0.14 163.07 154
1986 166.06 3.55 0.19 169.42 158
1987 186.25 2.11 0.17 188.19 172
1988 210.14 1.52 0.15 211.51 191
1989 210.29 1.23 0.44 211.08 187
1990 209.71 0.4 6.83 203.28 178
1991 252.61 0 10.74 241.87 209
1992 308.22 0 6.45 301.77 258
1993 367.88 0 2.45 365.43 308
Source: Statistical Yearbook of Industrial Economy of China, 1993
Table 6.1.5. Comparison of cement consumption per capita (1990)

Country Cement consumption per capita (kg)
Italy 749
Spanish 744
Former West Germany 429
Former USSR 470

France 448
Denmark 256
China 178
Table 6.1.6. Main techno-economic indicators of the cement industry

Year As percent Grade Running Heat intensity Integrated
of product of ratio of rotary of clinker electricity
up to cement kiln (kgoe/ton) intensity of
standard (%) cement
(%) (kWh/ton)
1960 402 74.93 278.2
1965 99.99 483 84.50 221.8
1970 99.80 479 81.20 223.1 91.20
1975 99.80 483 76.82 215.9 95.86
1980 99.99 448 85.27 206.54 96.65
1985 99.99 604 84.07 201.10 103.93
1986 99.99 611 81.34 198.15 105.59
1987 100 618 80.77 193.30 106.23
1988 100 614 78.40 191.20 107.31
1989 99.99 605 78.77 188.3 108.67
1990 100 604 79.49 185.4 109.93
1991 99.99 605 79.61 183.5 110.53
1992 100 610 81.57 178.3 110.30
Source: Statistical Yearbook of Industrial Economy of China, 1993
6.1.2.5 Coal as the main fuel
Figure 6.1.2 and Tables 6.1.7 and 6.1.8 show the energy consumption and the mix of the cement
industry in China. It can be seen that coal is the main fuel used in the industry, and this causes
severe environmental pollution.
Table 6.1.7. Energy consumption of cement industry in 1985 and 1990

Indicator 1985 1990
Specific Coal Consumption (kgoe/ton cement) 116.3
for large and medium size plant 109.9
for small size plant 106.4
Specific Electricity Consumption (kWh/ton cement)
for large and medium size plant 103.56 110
for small size plant 100 100
Coal Consumption (ktoe) 16864.5 22452.6

Electricity Consumption (G Wh) 14667 21370
for large and medium size plant 4390
for small size plant 16985
Total Energy Consumption (kgoe) (1) 20950.7 28496.0
Source: State Administration of Building Material Industry of China, 1992
% 7%
90%
S o ild fu e l L iq u id fu e l E le c tr ic ity
Figure 6.1.2. Final energy mix of cement industry in 1990
Table 6.1.8. Final energy consumption and its mix in cement industry (1990)
Fuel type Energy consumption Mix (%)
(ktoe)
Total 21185.5 100
Solid fuel 19210.8 90.68
Liquid fuel 534.1 2.52
Heat 13.3 0.06
Electricity(1) 1427.3 6.74
Source: Energy Balance Table in 1990 (Note: 1 kWh = 3600 kJ = 0.086 kgoe)
It should be mentioned that a statistical system has been built since the 1980s. It is difficult,
however, to get historical data for the cement industry. In spite of that, the technological
trajectory of the cement industry in China can still be seen.
6.1.3 Evolution of energy efficiency in the cement industry
Table 6.1.9 shows the energy intensity of cement manufacturing in selected countries.
Table 6.1.9. Comparison of specific energy consumption with developed countries

Country Year Heat intensity Electricity Integrated energy
(kgoe/ton intensity intensity
clinker) (kWh/ton (kgoe/ton cement)
cement)
1980 84.2 124 94.9
1985 77.5 114 87.3
Japan 1988 70.9 103 79.8
1990 70.4 102.2 79.1
1991 70.2 102.6 79.0
Former 1980 76.9 104 85.8
West 1988 72.4 109 81.8
Germany 1990 62.7 104 71.7
China (for 1980 144.3 96.65 146.2
large and 1985 140.0 103.9 145.6
medium 1988 133.9 107.3 140.0
size plant) 1990 129.8 109.9 140.7
The reasons for the low energy efficiency can be identified in the following aspects:
• Outdated production process in enterprises

Figure 6.1.3 shows the process mix of large and medium-size cement plants. The water content
of mixing raw material is about 24-28% in the rotary kiln wet process, but it is only 7-14% in the
dry process. A large amount of heat must be used for evaporating water, so the energy intensity
of wet process is 30% higher than the dry process (Table 6.1.10). In some developed countries
like Japan and the former West Germany, the wet process has already been eliminated in favor
of the dry process.
100%
90%
80% 40
46.4 46.9 47
70%
60% Dry & Semi-dry Process
50% W et Process
40%
30% 60
53.6 53.1 53
20%
10%
0%
1970 1975 1980 1990
Figure 6.1.3. Process mix of large-medium size plant of the cement industry
Table 6.1.10. Energy intensity of main large and medium cement plants of China
Year 1980 1985 1990
Heat intensity of clinker (kgoe/ton)
Dry process 153.0 134.2 115.1
Semi-dry process 119.6 119.1 111.2
Wet process 149.6 148.4 143.3
Electricity intensity of cement
(kWh/ton) 89.5 105.4 115.2
Dry process 115.3 119.5 121.3
Semi-dry process 95.6 99.4 103.9
Wet process
Source: Energy Statistical Yearbook of China, 1991
• Low Efficiency of Equipment

Table 6.1.11 shows the thermal efficiency of the different kinds of kilns in China compared to
developed countries.
• Unreasonable Mix of Equipment

Table 6.1.12 shows the mix of kilns in China. There are about 5500 shaft kilns in small cement
plants, and their output makes up 80% of China’s total output. Most of them have low energy
efficiency and produce lower grade cement. The output of advanced dry process kilns is just
8.9% of the total. Table 6.1.13 shows the comparison of technological indicators between two
kinds of kilns in 1991.
Table 6.1.11. Thermal efficiency of kilns in 1990 (%)

Kiln type Average level for Advanced level of world
China
Wet rotary kiln for large- 27.6 31
medium size plant
New suspension preheater (NSP 41.7 52.4
kiln) for large-medium size plant
Shaft kiln for large-medium size 36.8 60.9
plant
Semi-dry kiln for large-medium 35 48.3
size plant
Mechanized shaft kiln for small 35.4 47.3
size plant
• Unbalanced Technology Development

Because of the differences in management level and labor quality, there is a large gap of energy
efficiency among the different plants as shown in Tables 6.1.14 and 6.1.15
Table 6.1.12. Mix of kilns in 1990

Kiln type Numbe Percent of
r production (%)
Large & medium size plant:

Wet rotary kiln 108 9.72
Waste heat recovery for electricity kiln 35 2.22
Preheater kiln 12 0.84
New suspension preheater(NSP kiln) 13 3.15
Libor kiln 14 3.07
Small size plant:
Mechanized shaft kiln 3241 60.74
Small size rotary kiln 489 9.54
Manual operation shaft kiln >2000 10.72
• Small Scale Equipment

Due to the economies of scale, the use of advanced technologies to improve energy efficiency
may not be beneficial to the small scale firms. Table 6.1.16 shows the difference of capacity per
kiln between China and Japan.
Table 6.1.13. Comparison of technological indicators between two kinds of kilns in 1991
(capacity > 88 k ton/kiln)
Revolving kiln for Vertical kiln for Average
Large-medium size Medium-small size
plant plant
Qualified ratio of product (%) 99.99 99.99 99.99
Clinker grade (#) 595 569 580
Cement grade (#) 476 428 449
Energy use (toe/ton cement) 143.7 114.0 127.0
Coal use in clinker making (toe/ton clinker) 132.3 103.5 116.0
Electricity use (kWh/ton cement) 111.78 91.17 99.96
Kiln number (sets) 435 1438
Production per hour (ton/hour) 5705.2 7744.0
Running ratio (%) 85.04 68.97
Productivity (ton/employee) 211.47 161.79 180.21
Source: Statistical Reference of National Building Material Industry, 1991
Table 6.1.14. Specific energy use of different kilns in China (kgoe/ton clinker)
Kiln type Average level Advanced level Gap
Wet rotary kiln 152.2 145.4 6.8
Waste heat recovery generator 174.5 139.0 35
kiln
Shaft-preheater kiln 160.7 153.9 6.8
Cyclone preheater 186.1 157.7 28.4
Suspension preheater kiln 188.21 162.72 25.48
Inner hollow kiln 293.45 230.64 62.81
Libor kiln 211.05 188.81 22.24
Mechanized kiln 199.81 142.65 57.16
Semi-mechanized kiln 229.71 147.58 82.13
Manual operation kiln 283.48 208.70 74.78
6.1.4 Environmental externalities of technological development
An investigation of industrial pollution in 1985 identified 13 industrial sub-sectors as major

sources of pollution, with individual waste discharges of over 100 Bm3. The rate of total waste
gas emissions amounted to 6128.32 Bm3/year, or 88.4% of the national total waste gas emissions
(Table 6.1.18). Among these industrial sectors, the building materials industry ranks second after
the power generation sector in terms of waste gas emissions and emission per unit of gross
output.
Table 6.1.15. Energy efficiency status in 1991
Maximum Average Minimum
Specific energy use for large and medium size 189.7 119.0 98.7
plant (kgoe/ton cement)
Electricity use for large and medium size plant 135 109.94 86
(kWh/ton cement)
Specific coal use for clinker (kgoe/ton clinker) 170.1 112.0 77.0
Source: Energy Conservation Reference SPC, China, 1993
Table 6.1.16. Comparison of capacity per kiln

Year China Japan
Number of kilns (set) 1985 97
1987 2871 96
1990 3912 81
Capacity (k ton) 1985 97322
1987 204670 97221
1990 268890 87808
Average capacity per kiln 1985 1003
(k ton) 1987 71 1013
1990 69 1084
Source: Cement No. 1, 1993
Table 6.1.18. Waste gas emission from industrial sectors (1985)

Waste gas emission Emission per
Sector (billion m3/year) % of unit gross
From From fuel national output
proces burning Total total (m3/yuan)
s
Electric power, steam and hot water 27.2 1592.5 1619.7 23.36 67.47
production and supply
Building material industry 681.4 496.5 1177.9 16.98 35.54
Smelting & pressing of ferrous metals 429.6 408.1 837.7 12.08 14.55
Chemical industry 336.8 350.5 687.3 9.91 12.33
Coal mining and processing 263.0 132.4 395.4 5.70 21.75
Others n/a n/a 1410.32 20.33 -
Industry sub-total 6128.32 88.40 n/a
National total 2710.2 4224.8 6934.90 9.33
Source: National Industrial Pollution Source Investigation, Evaluation and Research, 1990
The main pollutants discharged by cement plants are dust, toxic gases, waste water and noise of
which, dust and toxic gases have the greatest impact on the quality of the atmosphere. From
Tables 6.1.19 to 6.1.21, which show the various environmental pollutants of the cement industry
in 1991 and 1993, it can be seen that China has made an effort to reduce the emission of
environmental pollutants from the cement industry in recent years.
Table 6.1.19. Discharge and treatment of waste water by cement industry

Year 1991 1993
Number of Enterprises(unit) 1994 2418
Total Industrial Waste Water Discharged (k ton) 228420 252560
of which:
Discharged Directly to Rivers, Lakes and Reservoirs (kton) 156880 181920
% of total industrial waste water discharged 68.68 72.0
Discharged Directly to Sea (k ton) 370 320
Discharged Directly to Treatment Plant (k ton) 600 90
Industrial Waste Water Reaching Discharge Standards (k ton) 153930 173260
Proportion of Reaching Discharge Standards (% ) 67.4 68.6
From 1991 to 1993, an increasing proportions of waste water is discharged directly to the lakes,
rivers and reservoirs and a decreasing amount goes to industrial treatment plants. There has been
an increase in the proportions of waste water discharges being able to reach industry standards.
As shown in Table 6.1.20, the total quantity of dust discharged from the cement manufacturing
process accounts for about 1.14 and0.9 % (for 1991 and 1993, respectively) of the total cement
production in the same years (refer to Table 6.1.3 for total production of cement). It is estimated
that the dust discharge for large and medium size plants accounts for 2% of their production as
compared to 3.5% in small size plants. This is attributed to the adoption of advanced abatement
technologies in the larger plants. In some developed countries, this figure has been cut down
below 0.01%, and the discharged density has been controlled at 30 mg/m3. China’s discharge
control level, meanwhile, has just reached the 1960s’ level of the developed countries.
Figure 6.1.4 shows the comparison of waste gas emissions from fuel consumption and product
processes in 1991 and 1993, respectively. The large reduction in the proportion of waste gas
emission between the two-year period is due to the energy conservation programs and measures
adopted by the industry. It is worthy to note, however, that air pollution in the cement industry
is not of the coal-smoke type. This has important implications for energy efficiency
improvement and the application of pollution abatement technologies.
Table 6.1.20. Emission and treatment of waste gas by cement industry

Year 1991 1993
Total Volume of Waste Gas Emission (Million cu. m) 701600 910500
Waste Gas from Fuel 98000 119800
in which: Soot and Dust Removed 68800 88400

Removed Ratio (%) 70.2 73.8
Waste Gas in the Process of Production 603800 790600
in which: Gas Purified 404700 599800
Purified Ratio (%) 67.0 75.9
Proportion of Waste Gas from Fuel (%) 14.0 13.2
Proportion of Waste Gas from Process (%) 86.0 86.8
Industrial SO2 Discharged (ton) 560000 666703
Industrial SO2 Removed (ton) 30000 48373
SO2 Removed Ratio (%) 5.36 7.26
Industrial Soot Discharged (ton) 260000 392669
Industrial Soot Removed (ton) 470000 756125
Soot Removed Ratio (%) 64.38 65.82
Industrial Dust Discharged (ton) 2890000 3353936
Industrial Dust Removed (ton) 9220000 12193140
Dust Removed Ratio (%) 76.14 78.38
Table 6.1.21. Production, use and treatment of waste residue in cement making
Year 1991 1993
Industrial Waste Residue Produced ( k ton) 2030 3090
Industrial Waste Residue Used ( k ton) 1610 2650
Industrial Waste Residue Stored ( k ton) 80 40
Industrial Waste Residue Handled ( k ton) 390 390
Industrial Waste Residue Discharged ( k ton) 80 100
Industrial Waste Residue Discharged ratio (%) 3.94 3.24
Total Volume of Industrial Waste Residue Accumulated (k ton) 19120 19270
Areas of Industrial Residue Dumps (k sq. m) 730 390
Source: Statistical Yearbook of China, 1994.
from Fuel from Fuel

14% 13%
from from
Process Process
86% 87%
1991 1993
Figure 6.1.4. Proportion of waste gas emissions from fuel burning and processes
From a study conducted in 1993, the pollution emission rates for different kilns from 259 firms
were determined (Table 6.1.22). According to the type of kiln being employed, the quantity of
pollutants contained in the exhaust gases vary. Table 6.1.23 shows the composition of NOX in
exhausted gases from the different types of kilns.
Table 6.1.22. Pollution Emission Rates of Cement Kilns (1993)

Kiln type Pollution emission rate (kg/ton cement)
Range Average
NSP kiln 0.60~17.25 3.86
Preheater kiln 0.39~22.45 7.82
Inner hollow kiln with waste 1.02~96.81 15.00
heat recovery generation
Wet process kiln 1.13~18.21 10.64
Libor kiln 1.06~65.4 7.52
Mechanized shaft kiln 0.88~23.89 7.50
Table 6.1.23. NOx content in kiln-exhaust gases

Kiln type NOX content (ppm)
Inner hollow kiln 700
Pre-heater kiln 600-400
SP kiln 150
NSP kiln 100
Likewise, the absorption of sulfur from the production of cement differs for the different types
of kilns (Table 6.1.24). This is determined by the presence of CaO and its ability to absorb SO2
to form CaSO4 and CaSO3 when the temperature of the kiln reaches 800-1000oC. From the
table, SP kilns, preheater and Libor kilns have higher absorption rates of sulfur than the
conventional kilns used in cement production.
Table 6.1.24. Absorption rate of sulfur for different kilns

Kiln type Sulfur absorption rate (%)
SP kiln 98 - 100
Preheater kiln 95 - 100
Libor kiln 95 - 100
Shaft kiln 80 - 95
Wet process kiln 75 - 85
6.1.5 Potential for energy efficiency improvement and pollution abatement through
technological changes
In order to estimate the potential for energy efficiency improvement and pollution abatement
through technological changes, a case study was conducted on a large size plant in China. In
March 1980, 2 wet process kilns with dimensions of ∅ 2.7/3.1×95m were built up with an annual
clinker capacity of 170,000 tons. An equivalent of an annual cement capacity of 260,000 tons was
generated. Expansion on the two kilns was carried out in 1983 and 1986, to enlarge the
dimension of kilns to ∅ 3.3/2.7/3.1×95m. This led to an additional 46,000 tons of clinker,
equivalent to 50,000 tons of cement. Thus, 310,000 tons of cement was produced. In 1987, a 600
ton/day wet process kiln (No. 3) was built, with dimensions of ∅ 3.5×145m. This produced
193,000 tons of clinker per year, equivalent to 300,000 tons of cement. The total annual clinker
production generated by the enterprise was 410,000 tons, equivalent to 610,000 tons of cement.
In order to change the old technology and improve on energy conservation and environmental
protection measures, a two-step rehabilitation program has been made. This was based on the
rules of comprehensive planning and multiple-step implementation issued by the State
Administration of the Building Material Industry. The first-step rehabilitation adopted the hybrid
method: the mixture of raw material slurry and raw powder after being dried and crushed, is fed
together into a preheating system, for energy conservation and the balance of the main machines
and equipment capacities. The energy conservation technical rehabilitation project on kilns 1 and
2 started in March 1993, and was finished in October 1994. After rehabilitation, the kiln with the
two-step preheater and calciner was able to produce 1,000 tons of clinker per day, 300,000 tons
of clinker per year, or an equivalent to 450,000 tons of cement.
The energy conservation and environment protection technical rehabilitation project on kiln 3
will begin in 1996. One 2000 ton/day production line with a remarkably advanced technology for
energy conservation and environmental protection is adopted for the project. The dimension of
the kiln is ∅ 4×56m with a five-step preheater/ precalciner. It will result in an addition of
400,000 tons of clinker.
After the project is commissioned, heat consumption can be reduced from 144.2 kgoe to 73.1
kgoe per ton of clinker (a reduction of 49.2%), electricity consumption can be reduced from 108
kWh to 105 kWh per ton of cement, or a reduction of 3 kWh.
The dust emission can be reduced from 6.16 kg to 0.45 kg per ton of cement. NOx toxic gas
emissions can be reduced from 2.01 kg to 0.875 kg per ton of clinker, and sulfur dioxide
emissions can be reduced from 0.79 kg to 0.09 kg per ton of clinker.
Table 6.1.25 shows the comparison between three typical technologies of cement production. It
can be seen that energy conservation and pollution abatement can be realized through
technological change.
Table 6.1.25. Comparison of techno-economic indicators in selected kilns

Process Wet process Semi-dry process Dry process
Kiln type ∅3.5×145m long ∅3.5×54m with ∅4×56m with
kiln two-step preheater five-step preheater
and calciner and precalciner
Capacity
Clinker production (ton/day) 600 1000 2000
Cement production (kton/year) 240 360 716
Heat consumption (kJ/kg clinker) 6068 4389 3093
(kgoe/ton clinker) 145.6 105 73.5
Electricity use (kWh/ton cement) 108 109 105
Dust discharge (ton/year)
From raw material to kiln 357.5 324.7 268.02
From cement mill to packaging 373.5 373.5 74.25
Total 731 692.8 342.27
Discharge per ton of clinker (kg) 1.85 1.27 0.44
Discharge per ton of cement (kg) 3.04 1.92 0.48
Toxic gas emission
NOx (kg/day) 1209.6 1193.0 1750
(kg/ton clinker) 2.01 1.19 0.875
SO2 (kg/day) 474.48 328.56 180
(kg/ton clinker) 0.79 0.328 0.09
Update investment (kyuan RMB) 61885 132563
Average investment per ton of cement 171.9 185.1
(yuan RMB/ton cement)
Shaft kilns in small cement plants are the main energy consumers in China. The average energy
intensity of the cement clinker in mechanized shaft kilns is 115.5 kgoe/ton for the fuel and 99
kWh/ton for electricity. Another case study has been done to estimate the potential for energy
conservation of shaft kilns. Table 6.1.26 shows the results of a typical shaft kiln testing. By using
some effective measures such as pre-watering, pre-homogenizing, and so on, energy intensity can
be reduced from 108.9 kgoe to 87.7 kgoe per ton of clinker.
Table 6.1.27 shows a typical Libor kiln heat consumption. Besides the clinker reaction heat and
heat consumption for material water evaporation (items 1 & 2, respectively), heat expenditures
occur in the waste gas fan, stovepipe, kiln surface and cooler. Through effective measures, such
as the use of advanced thermal insulation material, seal technology for calcine system, etc., energy
intensity can be reduced from 138.70 kgoe to 113.74 kgoe per ton of clinker.
From the foregoing discussion, it is evident that the energy-savings potential of China’s cement
industry is quite considerable. The principal measures to consider are presented in Table 6.1.28
and as follows:
Table 6.1.26. Heat expenditures of shaft kiln

Expenditure item Heat expenditure As percent of total (%)
(kgoe/ton clinker)
1. Clinker reaction heat 36.74 33.74
2. Heat consumption for material water evaporation 16.92 15.54
3. Heat carried off by clinker cooler 3.48 3.2
4. Heat carried off by waste gas fan 12.18 11.18
5. Heat lost from stovepipe 2.22 2.04
6. Heat carried off by incomplete burning 29.34 26.95
7. Heat lost from surface of kiln 6.03 5.54
8. Heat carried off by cooling water 1.03 0.95
9. Others 0.94 0.86
Total 108.90 100
Table 6.1.27. Heat expenditures of libor kiln

Expenditure item Heat expenditure As percent of total
(kgoe/ton clinker) (%)
1. Clinker reaction heat 37.75 27.2
2. Heat consumption for material water evaporation 13.27 9.6
3. Heat carried off by clinker cooler 3.27 2.4
4. Heat carried off by waste gas fan 30.21 21.8
5. Heat lost from stovepipe 15.21 11.0
6. Heat carried off by CO emission 0.36 0.2
7. Heat lost from surface of kiln 15.38 11.1
8. Heat carried off by waste gas cooler 19.21 13.8
9. Heat carried off by fry ash 0.33 0.2
10. Heat consumption for fry ash water 2.06 1.5
evaporation and decomposition
11. Heat carried off by cool water 1.14 0.8
12. Others 0.59 0.4
Total 138.70 100
Table 6.1.28. Technical and economic analysis of integrated energy-saving measures for
China’s cement industry
Item Potential of Unit investment in
energy saving energy saving
(k toe) (yuan/toe)
Comprehensive innovation of mechanized 3577 551
shaft kilns
Substituting dry process for wet process 623 843
Substituting wet grind and dry roast for wet 441 871
process
Integrated innovation of wet process kilns 182 593

Renewal of inner hollow kilns 1855.7 1684
Innovation of kilns with vertical shaped 70 910
preheater
Innovation of labor kilns 98 1454
Innovation of grind machines 1620 1232
Total 11400
Source: Cheng Ming , 1993
(1) Comprehensive energy-conserving innovation on mechanized shaft kiln

Using a combination of measures such as pre-watering, raw material mixing, pre-homogenizing,
and integrated kiln reconstruction, can reduce energy intensity by 25%.
(2) Substituting the wet process with the dry process

Substituting the wet process with the dry process can considerably improve energy efficiency by
reducing the cement clinker energy intensity by about 50%.
(3) Substituting the wet process with wet grinding and dry burning
Based on the wet process, adding mechanical dewatering equipment can reduce the water content
in raw material, thus reducing the energy consumption and increasing output. According to the
data from demonstration projects, energy intensity can be decreased by 40%, and cement output
increased by 30%.
(4) Integrated renewal of the wet process kiln

The cement plants which have to use the wet process can still save about 20% of their energy
consumption by using various energy-saving measures and integrated renewal of the wet process
kiln.
(5) Renewal of inner hollow kiln

The inner hollow kiln is a small-scale, highly energy-intensive rotary kiln that needs to be either
upgraded or rejected. There are various types of small-scale rotary kilns in China, totaling about
400 units. Their renovation can save energy and increase cement output. Taking a plant as an
example of renovation, the average clinker output per hour for one kiln before renewal was 4.5
tons, and energy intensity was 286 kgce/ton. After renewal, the output per hour became 12.5
tons and the energy intensity of clinker was 136 kgce/ton.
6.1.6 Status of application of new technologies for energy efficiency improvement and
pollution abatement
From the point of view of energy efficiency improvement and pollution abatement, the dry
process is the best to adopt in cement manufacturing. Because of limited capital, however, it is
impossible to substitute wet kilns and shaft kilns by the NSP kilns, though the use of the shaft
kiln process and new dry process is expected to increase further in the future.
The situation of having various types of kilns in operation throughout China’s cement industry
poses a problem for energy efficiency improvement. Different kilns adopt different technologies,
and thus add to the complexity of energy studies and energy efficiency programs to be
implemented. An example is as follows: there were 84 wet kilns in large and medium size cement
plants in 1994. Most of these plants were not in the right condition to retrofit to NSP kilns. Only
those kilns with ∅3.5×145 m long can be substituted by the dry process. The other kinds of wet
kilns can only adopt wet grinding, dry roast technology and other specific energy conservation
technologies.
Table 6.1.29 shows the status of the application of new technologies for energy efficiency
improvement in large and medium size cement plants. It can be seen that tremendous efforts
must be made in technological innovations.
Table 6.1.29. Status of application of new technology for energy efficiency improvement
in the cement industry in 1993 (for large and medium size plants)
Kiln type Number % to total number of Capacity
kilns (ton clinker/hour)
Wet process kiln: 84 54.1 1606.96
∅3.5×145 m 34 28.5 846.7

Capacity < 20 ton/hour 43 18.7 554.89
20< Capacity<30 39 32.4 961.99
Capacity>30 2 3.0 90.08
Dry process kiln 33 35.5 1054.23
NSP kiln 9 23.1 687.25

Capacity<20 ton/hour 18 7.3 216.79
20<Capicity<100 12 13.0 386
Capacity>100 3 15.2 451.44
Semi-dry process kiln 9 10.4 308.51
Total 126 100 2969.7
Table 6.1.30 shows the energy savings measures for various cement processes.
There are over 4000 mechanized shaft kilns in small cement plants, from where 70% of the total
cement is produced. Most of these plants employ outdated technologies with low management
and energy efficiencies. As shown in the table, the innovation of mechanized shaft kilns have
large potentials for energy saving.
In May 1993, the State Environment Protection Bureau of China published a list of 3000 major
polluting firms in the country, of which 397 were cement plants, accounting for 13.2% of the
total number of firms. This shows that pollution from the cement industry is a serious problem
due to the serious impact on the environment.
6.1.7 Conclusions
From the above discussion, some main conclusions can be briefly summarized as follows:
- China is the biggest cement-producing country in the world, while the cement
industry holds an important position in the national economy.
- The cement industry is a highly energy-intensive and polluting industry.
- The energy intensity of cement manufacturing in China is 1.78 times higher as that of
Japan, and 1.96 higher than Germany. The energy-savings potential of China’s cement
industry is quite considerable.
- The industry is characterized by outdated technologies both in the production process
and equipment. New technologies have large market potentials in China.
Table 6.1.30. Energy saving measures for different cement production processes
Capacity Capacity Heat Heat Potential

New technology Kiln type Kiln before increase intensity intensity of energy
number retrofit after retrofit before after savings
(k ton (kton retrofit retrofit (k toe)
clinker/ clinker/ (kgoe/ton (kgoe/ton
year) year) clinker) clinker)
Wet process:
1. Substituting dry process for wet process ∅3.5×145 34 7000 5600 146.3 82.6 623
m wet long
kiln
2. Integrated innovation of wet process small 8000 280 147 119 182
kilns plants
3. Substituting wet grind and dry roast small 8000 3360 149.8 100.1 441
for wet process plants
Semi-dry process:
1. Innovation of Libor kilns Libor kiln small 5200 830 112 91 98
plants
Dry process:
1. Renewal of inner hollow kilns Inner 287 8400 14200 199.5 94.5 1855
hollow kiln (small
plants
incl.)
2. Innovation shaft-preheater kiln Shaft small 4000 2200 124.6 101.5 70
preheater plants
kiln
Mechanized shaft kilns:
1. Prewatering, raw material. mixing, Shaft kilns 4000 126000 37800 115.5 87.5 3577
prehomogenizing, integrated kiln
reconstruction, etc.
Profile of the Cement Industry in India 73
6.2 COUNTRY REPORT: INDIA
6.2.1 Introduction
The Indian cement industry is a highly energy-intensive and polluting industry, whose
production at present includes 13 varieties of cement, three of which comprise more than 95%
of the total production. Currently, the country exports cement to its neighboring countries, and
it has the advantage of being the resource base for the cement-importing countries in the region.
The industry, however, has not yet kept pace with the advances in science and technology taking
place in the world. It is saddled with old plants and machinery designed during those periods of
cheap energy, and while the growth of energy conservation efforts has gained momentum in the
developed countries, efforts in India are still at its infancy stage with more focus on
housekeeping measures.
The upheavals in the world energy market in the 1970s and the country’s gradual decontrol of
cement in the 1980s, however, have spurred some technology improvements in the industry.
While the industry is setting itself to meet the increasing demands for construction materials, it
has also responded to the global calls for environmental protection and consciousness through
the adoption of clean technologies at the plant level. Various constraints exist, however, and
again, India’s cement industry is characterized as infant in terms of the adoption of
environment-friendly and clean technologies.
This section aims to assess the status of technologies in the energy-intensive and polluting
cement industry by presenting the existing technological and environmental conditions in the
industry. The latter part identifies the potential areas of energy conservation and pollution
reduction in the industry with use of energy-efficient and environmentally sound technologies.
6.2.2 Technological trajectory of India’s cement industry
6.2.2.1 Current scenario
At present, the Indian cement industry produces thirteen varieties of cement, three of which
comprise more than 95% of the total production. These are ordinary Portland cement, Portland
pozzolana cement and Portland slag cement. This total production is derived from cement
plants whose number has been growing over all these years (Figure 6.2.1). As a high-value added
industry, it’s growth rate and contribution to the Indian economy is quite significant. It is
estimated that the newer cement plants that compare well to world standards in terms of
productivity and production costs, would be able to export about 5 million tons (Mt) per annum
by 1996-1997. Table 6.2.1 summarizes the performance of the cement industry from 1973 to
1989.
The technology for cement manufacture in the country has changed substantially during the past
three to four decades. While plants based on the wet process were established in the 1950s and
early 1960, those using the dry process have been set up thereafter. Dry process cement plants,
which are less energy- intensive, now account for over 90% of installed capacity. Precalcinator
technology has also been introduced in India, resulting in a significant decrease in the specific
energy consumption. Three indicators (value added - VA, thermal, and power) for the cement
industry are shown in Table 6.2.2.
600 558
500
400
No. of Plants
328
300 232
200 126
100
0
1973-74 1978-79 1983-84 1988-89
Figure 6.2.1. Growth in India’s cement factories
Table 6.2.1. Performance characteristics of the cement industry in India

All values in million 1973-1974 1978-1979 1983-1984 1988-1989
Number of factories 126 232 328 558
Fixed capital (Rs) 14 366 22 802 103 999 339 587
Fuels consumed (Rs) 5 358 12 921 39 125 112 485
Value of output (Rs) 21 361 46 318 150 676 331 885
Depreciation (Rs) 1 394 1 994 9 875 30 769
Net value added (Rs) 3 296 9 639 40 952 35 811
All values in Real growth rate % Share in the

million manufacturing
economy
1973-1979 1979-1984 1984-1989 1983-1984 1988-1989
Number of factories 12.99 7.17 11.21 0.26 0.83
Fixed capital (Rs) 0.19 24.83 19.64 0.99 3.81
Fuels consumed (Rs) 7.61 11.23 20.31 4.70 7.93
Value of output (Rs) 5.1 13.04 13.9 1.04 1.8
Depreciation (Rs) 1.35 4.31
Net value added (Rs) 11.78 20.54 2.4 0.98 1.55
Table 6.2.2. Indicators for the cement sub-sector

Year VA (Cement Indicator) Coal Indicator Electricity Indicator
1985-1986 100 100 100
1986-1987 100 101.31 96.95
1987-1988 98.56 92.79 90.91
1988-1989 132.43 89.32 87.50
1989-1990 121.13 79.96 78.33
1990-1991 123.20 83.63 81.93
1991-1992 NA 84.27 82.56
Electric power and coal are the major energy forms used in the cement industry, although some
plants use furnace oil and lignite as well. The cement industry accounts for over 10% of the
industrial sector's coal consumption, and over 6% of the sector's electricity consumption.
Although the overall energy intensity of the cement industry has declined during the past decade
or more (due largely to an increasing share of production from dry process-based cement
plants), energy consumption norms in India are significantly higher than international ones.
Table 6.2.3 gives the specific energy consumption for cement and the value added for non-
metallic mineral production of which cement comprises 60-65%.
Table 6.2.3. Value added and specific energy consumption for cement in India
Value-added for non- Specific Energy Consumption
Year metallic mineral
products Coal (kgoe/ton) Electricity
(Rs Million 1980/81 (kWh/ton)
price)
1970-71 20 74.1 NA NA
1980-1981 4 740 NA NA
1985-1986 9 700 100 104.75
1986-1987 9 220 102 101.56
1987-1988 10 580 93 95.23
1988-1989 11 420 90 92.66
1989-1990 11 750 80 82.06
1990-1991 11 950 84 85.82
1991-1992 NA 84 86.48
Cement production during 1990-91 at 48.86 Mt was 6.7% higher than the production of 45.79
Mt in the previous year (Table 6.2.4). The increase in production is entirely due to large scale
plants in the private sector while production by public sector cement plants declined to a share
of 6.2%.
Table 6.2.4. Cement production and energy consumption
Energy consumption in cement production
Year Million tons Electricity (GWh) Coal (‘000 tons) Fuel Oil (‘000 tons)
1970-71 14.3 NA NA NA
1980-1981 18.7 NA NA NA
1985-1986 33.1 3467.3 7900 54
1986-1987 36.6 3717 8850 NA
1987-1988 39.6 3717 8850 NA
1988-1989 44.8 4106.5 9550 NA
1989-1990 45.5 3758.2 8740 NA
1990-1991 48.9 4188.2 9740 NA
1991-1992 53.61 4644 10800 NA
Note: Figures of coal consumption are from the Department of Coal, India. Electricity
consumption is based on four time series data for which both the electricity and coal
consumption were available. Electricity consumption varied from 0.4 to 0.43 GWh
per ton of coal consumed. The estimates are for the years 1988-89 to 1990-91.
6.2.2.2 Structure of the cement industry
Trends in cement production

India's cement production increased from 3.29 million tons in 1951-52 to 57.96 million tons in
1993-94 (Table 6.2.5). The highest compound growth rate per annum was recorded during the
late fifties when output increased at an annual average rate of 11.6%.
During the early seventies, the average annual growth rate slowed down, reaching an all time low
of 3.7%. This downward trend was halted and reversed in the late seventies (1974-80) when the
average production increased at the rate of 7.2 % per annum. Good progress was made in the
early eighties; in real terms, this implied that output increased from 18.7 million tons in 1980 to
30 million tons in 1985. This upward trend continued and production reached 45 Mt by 1989-
90.
In essence, the decade of the seventies witnessed a slowing down in production. This adverse
trend was halted and reversed during the eighties. The performance in 1991-92 was indeed
remarkable; production increased by almost 4.5 million tons over the previous year’s record of
49 million tons.
Trends in capacity
The cement industry witnessed an increase in production at an average rate of 11.6% per annum
in the late fifties. Production increased from 4.8 million tons in 1955-56 to 7.97 million tons in
1960-61. The following year, a target for additional installed capacity was 16 million tons, though
the achieved production was only 9.3 million tons, or just 58% of the planned production. The
production performance was comparatively better during the subsequent years. In 1984-85,
against a target of 34.5 million tons, a production of 30.1 million tons was achieved. In 1989-90,
achievement was 45.41 million tons which exceeded the target of 45.0 million tons. Thereafter,
achievements have been in excess of 95% of the target.
Table 6.2.5. Cement industry trends in capacity, production, and capacity utilization
(Mt) (inclusive of mini-cement plants)
Year Installed Capacity Actual Production Capacity Utilization (%)
1950-1951 3.75 3.29 88
1960-1961 9.30 7.97 86
1968-1969 14.98 12.24 82
1980-1981 26.99 18.56 67
1990-1991 64.36 48.90 76
1991-1992 66.59 53.61 81
1992-1993 70.19 54.08 77
1993-1994 76.88 57.96 76
Source : Basic Data for Cement Industry (May 1995): Cement Manufacturers'
Association
The relation between installed capacity and production has shown an almost continuous
downward trend. During the initial years, capacity utilization fluctuated between 88% and 96%.
However, from 1956 onwards, capacity utilization declined, reaching an all time low of 67% in
the years 1980-81 and 1986-87. During the 60's, capacity utilization fluctuated between 83%-
90%, between 73-80% in the 1980's and finally, between 67% and 75% for the period of 1980-
90. The share of the public sector in India’s cement production is shown in Table 6.2.6.
Table 6.2.6. Distribution of capacity and production by ownership

1977 1983 1991 1992
C P C P C P C P
Share of Public Sector (%) 11.46 9.92 17.40 16.10 15.50 10.20 14.70 10.40
Share of Private Sector (%) 88.54 90.08 82.60 83.90 84.50 89.80 85.30 89.60
Total (Mt) 21.67 19.17 36.2 25.70 61.31 50.60 64.84 50.70
Source: Indian Cement Industry Statistics (relevant years). C: capacity and P: Production
In 1977, out of a total production of 19.17 million tons, the public sector accounted for
approximately 10%, the rest being produced by the private sector. The contribution of small
units in the private sector continues to remain marginal. Between 1970 and 1991, production
from the private sector increased by almost four times from 14 million tons to 65 million tons;
simultaneously, the public sector contribution increased from 6% to 10%. This largely reflects
the expansion of the Central Government-owned Cement Corporation of India.
Trends in Energy Intensity

The trend in average specific thermal and electrical energy consumption in Indian cement plants
over the period is given in Table 6.2.7.
Table 6.2.7. Trends in Specific Energy Consumption in Indian Cement Plants

Average specific energy consumption
Year Thermal energy (kgoe/ton clinker) Electrical energy (kWh/ton cement)
1960 166.5 122
1970 158.6 132
1980 139.6 133
1983 126.1 139
1985 121.0 131
1986 112.0 128
1989 101.5 128
1990 97.8 124
1991 96.2 120
Source: BICP Reports on Energy Audits
The industry has exhibited considerable reduction in specific thermal energy consumption over
the last three decades being at 166.5 kgoe/tonne of clinker in 1960 to 96.5 kcal/tonne in the
year 1991. This has been mainly attributed to the increasing adoption of dry process technology
which is more energy (thermal) efficient.
6.2.3 Evolution of energy efficiency in the Indian cement industry
6.2.3.1 Process technology profile
The Indian industry at present is a conglomerate of modern dry process plants and old wet
process plants. The changing process profile of the Indian cement industry during the last
decades is given in Table 6.2.8.
Table 6.2.8. Process profile of the Indian cement industry (% annual capacity)
Process 1960 1970 1980 1992-1993
Dry 1.1 21.5 32.7 82.00
Semi-dry 4.5 9.0 5.7 2.00
Wet 94.4 69.5 61.6 16.00
It is observed from Table 6.2.8 that in the total installed capacity of cement industry, the share of
wet process plants has decreased over the past three decades, from 94.4% in 1960 to 16% in
1992-93. The share of dry process plants increased from a mere 1.1% in 1960 to 82.0% in 1992-
93. This is in line with the international trend to set up new dry process units or convert wet
process to the more energy efficient dry process.
From 1992-93, 51 cement companies in the country consisted of 99 cement plants, with a total
of 176 cement kilns, 89 of which were based on the wet process, 84 based on the dry process,
and 3 on the semi-dry process. The vintage profile of kilns with respect to 54 cement units
studied is shown in Table 6.2.9.
Table 6.2.9. Vintage profile of kilns for 54 sample plants (as of January 1993)
Number of kilns % of kilns
Vintage Dry Semi-dry Wet Dry Semi-dry Wet
< 10 years 19 0 0 37 0 0
10 - 25 years 31 1 7 61 11 23
> 25 years 1 8 24 2 89 77
Total 51 9 31 100 100 100
Most of the wet and semi-dry kilns are of high vintage. About 77% of the wet and 89% of the
semi-dry kilns are more than 25 years old and none is below 10 years. It is also noticed that 14
kilns are more than 40 years old. In the case of dry process kilns, most of them are less than 25
years of age, 61% being between 10 and 25 years and 37% less than 10 years.
6.2.3.2 Plant Size
The size of a plant or kiln installed has a bearing on the cost of production as well as on specific
energy consumption. There have been increasing trend all over the world for adoption of higher
capacities. In Table 6.2.10, a comparison of plant size profile of the Indian cement industry has
been made with that of Japan.
Table 6.2.10. Comparison of Indian cement plant sizes with that of Japan
Plant size Japan (1987) India (1992)
(Installed
capacity) No. of plants % No. of plants %
Mt per annum
>3 11 26.2 0 0
2-3 4 9.5 0 0
2 - 2.5 8 19.5 2 2.1
1.5 - 2 7 16.7 7 7.2
1 - 1.5 7 16.7 4 4.1
0.5 - 1 4 9.5 39 40.2
up to 0.5 1 2.4 45 46.4
Total 42 100.0 97* 100.0
* Out of 99 cement plants in the country, 2 plants produce only clinker
Currently, the minimum economical size for a new cement plant in India is 1 MTPA (Million
tons per annum). In Japan, 88% of the plants are above 1 MTPA and more than 50% of these
are above 2 MTPA. Correspondingly, in Indian cement industry, 13.4% plants are above 1
MTPA and only 2 plants produce more than 20 MTPA. 84 out of the total 97 plants, i.e., 86.6%
of the plants in the industry are below 1 MTPA capacity.
The installed capacities of kilns have also varied widely in India. Among the 54 sample plants for
the study, the kiln capacity has ranged from as low as 120 tons per day (TPD) to a maximum of
4500 TPD. The size of the Indian plants to be considered economical in early 1950's was about
300 TPD. This was standardized at 600 TPD in the mid 1960's and a decade later, the new
plants to be established were standardized at 1200 TPD. The last decade, however, has shown a
trend towards higher capacity kilns. The capacity of the kilns set up during the years 1981 to
1990 have ranged between 1200 TPD and 3850 TPD. In 1991, the size of kiln commissioned
has gone up further at 4500 TPD capacity. Table 6.2.11 below gives the trend in setting up of
kiln sizes during the period 1981 to 1991 among the 54 sample plants.
Table 6.2.11. Size range and number of kilns commissioned (1981 to 1991)
Capacity ranges of kilns Kilns set-up during the period
(TPD)
No. of kilns % of kilns
< 1200 - -
1200 - 1500 9 34.6
1500 - 2000 3 11.5
2000 - 2500 2 7.7
3000 and above 12 46.2
Total 26 100.0
It is observed from the table that about 46% of the kilns set up during the period 1981 to 1991
were of 3000 or above TPD installed capacity.
6.2.3.3 Thermal Energy Consumption
Process-wise specific heat consumption characteristics for individual plants in 1987-88 and
1991-92 and the corresponding weighted average specific consumption for the sample industry
in each of the years are shown in the Table 6.2.12.
Table 6.2.12. Process-wise specific heat consumption (kgoe/ton clinker in 1987-1988

and 1991-1992) of Indian cement plants
Year Dry Semi-dry Wet All Plants
Max. 124.20 95.60 160.40 160.40
1987-1988 Min. 80.10 95.60 140.60 80.10
Wt. Ave. 91.47 95.60 148.30 96.30
Max. 105.70 95.30 161.40 161.40
1988-1989 Min. 81.00 85.30 139.40 81.00
Wt. Ave. 90.90 95.30 144.60 95.10
Max. 111.20 96.00 174.90 174.90
1989-1990 Min. 80.80 96.00 136.70 80.80
Wt. Ave. 90.60 96.00 144.80 93.70
Max. 109.10 96.40 151.70 151.70
1990-1991 Min. 81.50 96.40 135.20 81.50
Wt. Ave. 88.60 96.40 135.20 81.50
Max. 96.60 91.50 158.30 158.30
1991-1992 Min. 80.90 91.50 136.00 80.90
Wt. Ave. 85.63 91.50 142.00 87.90
No. of plants 15 1 4 20
investigated
Source: Bureau of Industrial Cost & Prices (BICP) Energy Audit Study of Cement Industry
In the case of the dry process, the weighted average specific heat consumption for the 15 sample
units has shown an improved trend during 1987-88 to 1991-92. The extent of improvement has
been 6.38% in kgoe/ton clinker. The minimum specific heat consumption in each of the years
has been more or less at the same level (between 80.1 to 81.5 kgoe/ton) whereas the maximum
level have come down by 22.2% during the same period (124.2 kgoe/ton in 1987-88 and 96.6
kgoe/ton in 1991-92). The difference between maximum-minimum annual figures has
narrowed down significantly from 55% in 1987-88 to 19.5% in 1991-92, indicating that many of
the units have improved efficiency in this area.
In the case of the wet process, the yearly weighted average specific heat consumption in the 4
sample units has shown an improvement of 5.8% during the year 87-88 to 90-91, but marginally
increased by 1.6% during 1990-91 to 1991-92.
In the case of semi-dry process, data could be obtained from one plant only. The specific heat
consumption had more or less stagnated (95.3 to 96.4 kgoe/ton) during the years 1987-88 to
1990-91. It however registered a 5.08% improvement in 1991-92 with respect to the previous
year.
On the whole, all processes taken together, the weighted average specific heat consumption of
20 plants decreased steadily during 1987-88 to 1991-92. As compared to the heat consumption
of 96.4 kgoe/ton clinker in 1987-88, this has reduced to 88 kgoe/ton in 1991-92, thus showing a
reduction of 8.68% in the specific heat consumption during the above period.
Improvement in specific heat consumption in cement plants from 1983 - 1984

Table 6.2.13 shows the process-wise weighted average specific heat consumption of the sample
plants during the years 1987-88 and 1991-92 compared with that of 1983-84.
Table 6.2.13. Improvement in the weighted average specific heat consumption of

cement plants during 1987-88 and 1991-92 over 1983-84
Weighted average specific heat % Improvement in heat
Process consumption (kgoe/ton clinker) consumption over 1983-1984
1983-1984 1987-1988 1991-1992 1987-1988 1991-1992
Dry 101.50 91.40 85.60 9.9 15.6
Semi-dry 103.90 95.60 91.50 8.0 11.9
Wet 180.00 148.30 142.00 17.6 21.1
Overall 119.30 96.30 87.90 19.2 26.2
It is observed that in all the three processes, i.e., dry, semi-dry and wet processes, there have
been significant improvements in the specific heat consumption during the period 1983-84 to
1991-92. The extent of reduction in this period has been 15.6% in the dry process, 11.9% in the
semi-dry and the 21.10% in the wet process. Overall, a decrease of 26.2% has been observed.
Apart from other reasons mentioned in the subsequent paragraphs, one reason for a low specific
heat consumption in 1991-92 relative to 1983-84, has been that many of the plants with wet or
semi-dry processes have switched over to the more energy efficient dry-process. In 1983-84, out
of 21 plants examined, 6 employed the dry process, 2 were semi-dry and 13 were wet-process
plants. In 1991-92, 15 were dry, 1 semi-dry and 4 were wet process plants among 20 plants. It is
seen that the switching over from the wet to dry process is the most effective measure to reduce
specific energy consumption.
The reduction in specific heat consumption in the case of all the three process over the years
(1983-84 to 1991-92) is attributed to various energy conservation measures adopted by
individual plants. These included better operational control and optimization (reducing false air
infiltration, efficient feeding systems, use of mineralizers and slurry thickeners, etc.); technology
upgrading (automation of process control and energy efficient equipment/system); and

improved energy management activities.
The current level of thermal energy consumption (pyro-processing) achieved by international

practice abroad is reported to be 71.0 kgoe/ton clinker. These are invariably for dry process
plants as there are hardly any wet process operations abroad. Therefore, there is potential for
further reduction in thermal energy consumption by the Indian industry.
Comparison with the international scenario (overall clinker and cement plants)
The weighted average specific energy consumption levels of USA, UK, Japan and India for
particular years are given below in Table 6.2.14.
Table 6.2.14. Comparison of specific energy consumptions of selected countries

Country Specific thermal energy Specific electrical energy
consumption (kgoe/ton clinker) consumption (kWh/ton cement)
USA (1990) 98.4 127.9
UK (1989) 111.6 122
Japan (1988) 71.0 103
India (1991-92) 88.0 120.64
Source: DSIR Report
The above data may not be strictly comparable due to the difference in reference years, but it is
indicative that compared to the best run plants (even during 1988) in Japan, specific
consumption in India averaged 30% more in clinker stage.
In the more recent period, some of the best performing plants abroad have reported their
thermal energy consumption in the range of 70-71 kgoe/ton clinker and power consumption
around 90 kWh/ton cement through adoption of energy efficient technologies and practices. In
the case of a Korean plant with cogeneration of power (17 kWh/ton cement) utilizing preheater
and cooler waste heat, the specific power consumption was reported to be 72 kWh/t of cement.
In comparison to modern dry process plants in Japan with a specific energy consumption of
representative cement plants in India, a scope for reduction of 17 kgoe/ton clinker and 17.64
kWh/ton cement exists in Indian plants and this corresponds to 19.3% thermal and 14.6% in
electrical energy reduction with reference to the present level.
Some of these technological advancements have also been adopted in some of the Indian
cement plants, resulting in higher energy efficiencies. In one of the recent 1 million ton per
annum dry process Indian cement plant, the energy consumption level in the year 1991-92 was
76.1 kgoe/ton clinker and 92 kWh/ton cement.
6.2.3.4 Electrical energy consumption
All the cement manufacturing processes, e.g., crushing, raw mill, pyro-processing, coal mill,
cement mill and packing sections consume electrical energy. Table 6.2.15 shows the specific
electrical energy consumption per ton of cement for individual plants during the years 1987-88
to 1991-92, and the process-wise weighted average from 1987-88 to 1991-92.
In the case of the dry process, the weighted average specific power consumption of 29 units
showed a decreasing trend since 1987-88. The specific power consumption has come down
from 136 kWh/t in 1987-88 to 122.1 kWh/t of cement in 1991-92. The updated data for the
year 1992-93 of the 11 dry process plants indicate that weighted average power consumption of
these plants is 109.7 kWh/t of cement. However, the individual plants showed a wide variation
in specific power consumption and ranged between 136.1 kWh/t to 187.5 kWh/t in 1987-88
and between 93.8 and 162.3 kWh/t of cement in 1991-92.
Table 6.2.15. Process-wise specific electrical energy consumption (weighted average) in

all plants for the year 1987-88 to 1991-92 (in kWh/t of cement)
Year Dry Semi-dry Wet All Plants
1987-1988 136.1 134.5 111.8 130.7
1988-1989 131.4 133.3 109.8 128.0
1989-1990 126.9 122.6 109.5 124.3
1990-1991 127.1 134.2 109.7 124.9
1991-1992 122.1 134.1 108.8 120.6
It is observed from the analysis that among the three processes, the wet process consumes the
least specific power. The weighted average specific power consumption in wet process has been
89.1% and 81.2% of the dry and semi-dry process, respectively, during the year 1991-92.
The weighted average specific power consumption of 10 wet process plants exhibited a
decreased consumption, i.e., 111.8 kWh/t of cement in 1987-88 and 108.8 kWh/t of cement in
1991-92. The reduction, however, has been marginal (2.63%). The variation of specific
consumption in different plants have not been as wide as in the dry process. It varied between
99.6 kWh/t and 133.7 kWh/t of cement in 1987-88 and between 93.8 kWh/t to 138 kWh/t in
1991-92.
In case of the semi-dry process plants, the weighted average specific power consumption of 2
units have been stagnant at around 134 kWh/t of cement during the above period (except for
the year 1989-90 which showed the lower consumption of 122.6 kWh/t). The specific power
consumption of both the individual units also remained more or less at the same level during the
above period.
The overall weighted average specific power consumption exhibited a steady decreasing trend.
As compared to the power consumption of 130.74 kWh/t cement in 1987-88, the reduction has
been 7.7% in 1991-92.
Improvement in the specific power consumption

Table 6.2.16 compares the cement process-wise weighted average specific power consumption
of sample plants during the years 1987-88 and 1991-92 with the consumption scenario in 1983-
84.
It is observed from Table 6.2.16 that in the case of dry process, there has been significant
improvements in the power consumption. The weighted average specific power consumption
has reduced from 155.0 kWh/t of cement in the year 1983-84 to 122.09 kWh/t in the year 1991-
92. The reduction in specific consumption has been 21.2% during the period.
In the case of the wet process, there has been only a marginal decrease in the power
consumption during the periods 1983-84 over 1991-92. The weighted average specific power
consumption which was 113.8 kWh/t of cement in 1983-84 has decreased by 4.4% during the
year 1991-92.
Table 6.2.16. Improvement in specific electricity consumption during

1987-88 and 1991-92 over 1983-84
Weighted average specific electrical % Improvement in electrical
Process energy consumption (kWh/t cement) energy consumption over 1983-
84
1983-84 1987-88 1991-92 1987-88 1991-92
Dry 155.0 136.1 122.1 12.21 21.1
Semi-dry 122.8 134.5 134.1 -9.59 -9.2
Wet 113.8 111.8 108.8 1.78 4.4
Overall 130.2 130.7 120.6 0.00 7.8
No. of plants Dry Semi-dry Wet Total

investigated
1983-1984 6 2 13 21
1987-88 & 1991-92 29 2 10 41
Note: The comparison can only be indicative since the number of plants considered, as well as
the process mix have not been the same in different periods (due to the fact that many
of the plants having wet process earlier have switched over to the dry process.)
Nevertheless, this shows that the total energy consumption has been reduced.
In case of semi-dry process, the specific power consumption is found to have increased. The
weighted average specific power consumption which was 122.76 kWh/t during the year 1983-84
has increased to 134 kWh/t during the year 1991-92, an increment of 9% over that in 1983-84.
This may not be of much significance since the figure is only for one semi-dry unit and the
contribution of all semi-dry process units is only about 2.0% of the total cement industry
capacity.
The weighted average specific power consumption of 21 sample plants studied during the entire
period of 1983-84 was 130.2 kWh/t cement, which shows a reduction of 7.8% when compared
to the weighted average specific power consumption of 41 plants during the year 1991-92. The
variation in specific power consumption in different units are mainly due to plant capacity
utilization variations, irregular supply of grid power, variation of the equipment capacity installed
among the units, partial loading of equipment, idle equipment, installation of energy efficient
equipment, etc. It is noteworthy that the weighted average specific power consumption in
precalciner kiln (17 nos.) was low at 119.4 kWh/t cement as compared to 128.74 kWh/t cement
in preheater kilns (12 nos.) for the year 1991-92. The reasons for this variation are the latter
kilns’ higher specific energy consumption and more stable operation of the kilns in the former.
6.2.3.5 Domestic Manufacture of Cement Machinery & Equipment
In the early 1980s, the designs for manufacturing large sized cement plants were not available in
the country, and this encouraged some of the Indian cement machinery manufacturers to go in
for collaboration efforts with foreign manufacturers. Through the experience gained over time,
the Indian machinery manufacturers are now able to manufacture cement machinery and
equipment, and to supply large size cement plants. Quite a large number of components and
systems which were earlier imported are also being manufactured indigenously. Some of the
items that continue to be imported in various sections of cement plants are shown in Table
6.2.17.
Table 6.2.17. Item imported for various sections in Indian cement plants
------------------------------------------------------------------------------------------------------------------------
Crushing Wear resistant liners for crushers, few mechanical components
of the crusher.
Raw mill Vertical roller mill systems mill drive.
Blending and kiln Feeding system for kiln (Dry Process)
Burning and cooling Parts of preheater, precalciner Coal
Coal Grinding Weighing and feeding systems.
Cement Grinding Special lubrication systems.
Automation & Control system Computerized process control/monitoring systems, on line

analyses, advance instrumentation, etc.
------------------------------------------------------------------------------------------------------------------------
6.2.4 Environmental Externalities
There is an increasing realization all over the world for the abatement of environmental
pollution. This is apparent from the stringent emission limits as stipulated by the several
governments world wide for compliance by the respective manufacturing industries. The
cement industry is one among the industries creating high pollution and is covered by such
regulations.
In India, the above aspects have gained considerable importance and momentum in line with the
rapidly progressing industrialization and modernization. The cement industry in particular has
set itself for a rapid progress to meet the ever increasing demand for construction materials. It is
therefore imperative to improve the environmental conditions in the existing plants and
projected plants of the cement industry.
Cement manufacturing may contribute significantly to air pollution in the vicinity of the work, as
large quantities of pulverized materials are handled at each stage of manufacturing, from the
crushing of raw materials to final packaging of cement. Such pollution results from the emission
of dust. In addition to above, a cement plant also produces noise and gaseous emissions, i.e.,
NOX and SO2. However, emission of gaseous pollutants like NOX and SO2 is generally very
less and is of minor importance.
Cement plants do not significantly contribute to the national and global pollution. The impact
of pollution due to cement plants on environment is local, i.e., it is generally limited to a distance
of 10 km maximum from its place of installation. The regulations issued in various countries
until now are all primarily intended to bring air pollution under control within the vicinity, as
well as inside the factory. The dominating environmental problem in the Indian cement plants is
the emission of dust to the atmosphere.
The production of cement, irrespective of the technique adopted (dry, semi-dry, and wet) results
in dust generation, and hence, pollution. However, dust generation is most intense in the dry
process. Taking into account the air pollution by the cement industry, emission standards have
been worked out for cement plants of different capacities by the Central Pollution Control
Board of India and are shown in Table 6.2.18.
Table 6.2.18. Emission standards in the cement industry of India

Emission standards for particulate matter
(mg/nm3)
Plant production Protected area Other areas
capacity
200 TPD or less 250 400
> 200 TPD 150 250
Source : Central Pollution Control Board
The sources of dust generated in cement industry are from the following operations:
- Crushing of raw materials
- Storage and pre-blending of raw material
- Grinding
- Blending and homogenization
- Pyro-processing
- Clinker storage and transport
- Cement grinding
- Cement storage
- Cement packing operations
- Conveying of raw materials and finished products
To produce one ton of cement means handling a combination of about 2-2.6 tons of raw-
materials, gypsum, coal, etc. Between 5-10% of these finely pulverized materials remain
suspended as dust in gas/air and have to be substantially removed before being discharged into
the atmosphere. Gas or air to be de-dusted, varies between 6 and 12 m3/kg cement production
depending upon the design of the plant.
6.2.5 Status of application of new technologies
6.2.5.1 Status of the development of technology in India
Processes and equipment

Many of the Indian cement plants have adopted energy efficient processes and equipment to a
certain extent, based on the experiences of development worldwide and after investigating their
appropriateness to domestic conditions. Some of the modern practices introduced are as
follows:
• Mobile crushers
Keeping in view the split locations of limestone deposits and the long conveying distances,
mobile crushers are being given preference in some of the new cement installations in India.
Brought about by its advantages over conventional systems, one plant is already operating with a
mobile crusher and a few installations are coming up in other plants.
• Gyratory crushers
A few plants are operating with gyratory crushers, though its acceptability is still limited mainly
due to capacity considerations.
• Vertical roller mills

In the 54 sample plants studied, the number of vertical roller mills installed in the Raw Meal
Grinding and Coal Mill Sections are given in Table 6.2.19.
Table 6.2.19. Adoption of vertical roller mills vis-à-vis ball mills

Section/Mill Dry Semi-dry Wet Mixed Total
Raw Meal Grinding
Ball mill 20 2 19 2 43
Vertical roller 10 - - - 10
Coal Mill
Ball mill 9 1 16 - 26
Vertical roller 6 - - - 6
From the table, it is seen that all the wet and semi dry process plants utilize ball mills only in the
raw meal grinding as well as in coal mill sections. In the case of the dry process plants, a number
of plants operate with vertical roller mills. In the raw meal grinding section, 33% of the plants
have vertical roller mills and in the coal mill section, 40% of the plants are operating with
vertical roller mills.
• Tandem mills
These mills have been well accepted and introduced in many Indian cement plants.
• High pressure grinding rolls (roller press)

Two plants have already installed roller presses for raw materials grinding after realizing the
benefits of increased productivity and reduction in energy consumption.
• Dust collecting equipment

The emission of dust particles causes loss of energy as well as loss in production, which
otherwise can be recycled through insufflation and re-utilized in cement manufacture. For kiln
flue gases, coal mill vent air and cement mill exit air Electro-Static Precipitators (ESPs) of latest
technology are being installed. For venting out the excess hot air from the cooler, high-
temperature ESPs are being considered. The introduction of these ESPs can result in conserving
energy during cement manufacture. For transfer points of conveying system, cassette-type bag
dust collectors have also been accepted in some of the plants.
• Precalcination technology and 5/6-stage suspension preheater

Many of the new installations have come up with precalciner kiln which have resulted in reduced
kiln dimensions. The use of precalcinator also enables the utilization of high ash coals which is a
significant advantage under the Indian conditions.
Similarly, installation of 5-stage preheater precalciner system has also led to pressure drops
which give a thermal energy saving of 30-40 kcal/kg clinker, thereby promoting energy
conservation. Further addition of the sixth stage can bring additional energy saving of 15-20
kcal/kg clinker.
The analysis of kilns set up during the period between 1981 and 1991 have shown that out of 27
dry process kilns installed during this period, 15 have incorporated precalcination technology, 8
are operating with 5 stage preheater ,and one plant has gone for 6th stage preheater. Low
pressure cyclones have also been well accepted in all the new installations.
Instrumentation, process control and computerization

With the increase in size of the cement units and consequently, the large magnitude of material
handling and movement, it has become essential to go in for a reasonable extent of automation
in the cement industry. Most of the modern dry process cement plants in the country are
presently equipped with advanced instrumentation and process control systems with either
micro-processor based control systems or complete computerized controls. Almost all one
million ton per annum cement plants in the country have gone for the use of micro
computer/computer for process monitoring and control, data acquisition, supervision and
management information system. Eight cement plants in India have installed computerized
expert systems for on-line kiln operations. The Indian cement industry has been able to develop
the necessary capability towards application engineering and maintenance of these sophisticated
automation systems and these are likely to find greater application in the future capacities. With
more than 50 organizations throughout the world supplying different types of automation
systems, the selection of the most appropriate automation and computerized control system
becomes a very difficult task. With this kind of a scenario, it is important that some kind of
standardization is attempted on the use of such automation system based on their operational
experience. Moreover, with the high technological status of the computer industry, both from
software and hardware angle in the country, greater efforts should be directed towards
indigenization of these systems. In addition to advanced process and operational control, the use
of infrared type shell temperature scanners have found wider application with the advent of high
capacity kilns. These computerized scanning systems are presently available with an integrated
software package for complete refractory management which can monitor and predict refractory
conditions resulting in substantial reduction of downtime due to refractory failures.
In addition to the wide use of computers for on-line process control in the cement industry,
computers have also found significant application in the area of quality control. The use of XRF
analyzers with on-line computers has helped in automating raw material preparation in order to
maintain uniform quality of raw meal feed to the kiln.
Recently, the use of Neutron Activation Technique has also been reported for both on-line bulk
analysis as well as off-line elemental analysis and these systems are available with real-time
computers which enable immediate corrective action.
Comprehensive computerization in the manufacturing process and conversion of existing plants

to modem control methods, by utilizing analytical instrumentation are on the move worldwide.
Computer-based systems have been installed to maintain control over the blending process in
many countries. The present maintenance practices in cement plants have shown that
considerable production time is lost due to unplanned and unscheduled maintenance stoppages.
The condition monitoring systems (CMS) now in vogue, predict problems likely to arise and
serve advance warning for timely and appropriate maintenance action. Computers can be
applied to CMS in data storage and trend analysis; machine/component condition diagnostics:
failure prediction, and reporting and linking to a planning system for maintenance action. The
use of advanced instrumentation systems and computers would be essential for the higher
capacity plants to be set up in the next few years and the adoption of these systems should be
encouraged in order to derive the advantages of higher productivity, lower cost of production,
increased plant availability and improved and consistent quality of product.
Expert systems
The advent of one-million-and-above ton capacity dry process plants has brought into focus
some new associated problems. A major problem is that of finding experts to cope with
abnormal situations in case of plant upsets, for which the presently available computer controls
are not of much use. Artificial intelligence (AI) and heuristic programming techniques offer a
way of solving these problems. Artificial intelligence based expert systems are expected to be
used to aid the plant personnel to recover from complicated and abnormal situations and thus
reduce both plant outages and personnel requirements.
Automatic kiln control systems based on expert and fuzzy systems have been successfully
implemented in the cement industry and about 8 such systems are now working in the Indian
cement industry. Expert systems have also found applications in automatic controls of closed
circuit ball mills. Efforts are reported in the area of raw mix control using expert systems. NCB
has developed an expert system for efficient operation of rotary kiln which is a linguistic rule
based system using fuzzy mathematics. NCB and DOE have jointly taken up steps for
implementation of the complete expert kiln control system in Indian cement plants.
In addition to the above, AI is likely to help in improving preventive maintenance schedules

with passage of time at a cement plant. Failure prediction, detection and analysis is likely to
become another major application of AI techniques in cement plants. The cement industry will
have to go in for application of AI techniques very soon in a big way.
6.2.5.2 Particulate Pollution and Abatement
Dust collection systems

One major pollution abatement method is through the use of dust collection systems in various
sections of the cement process plant.
• Crushing
Crushing is a preliminary operation used for size reduction of run of the quarry material of size
500-1000 to a size of 16 mm acceptable for raw metal grinding. Dust generation is about 5-15
gm/nm3 consisting of coarse particles. The type of dust collector includes cyclones, bag filter
and in some cases wet scrubbers. The main drawback of cyclone is its low collection efficiency
on small particles. As a result, it does not meet the standards stipulated by the state/central
pollution control boards. In order to meet the standards as prescribed, generally higher
efficiency dust collectors like fabric filters are used. Use of wet scrubbers may cause sludge
disposal problem and hence these are not installed.
• Raw Mill
Raw mill is used to grind raw materials to a size up to 10% retained on 170 mesh or 90 microns,
in order that it can be used as kiln feed. The normal dust generation in roller mill and ball mill
are 300-500 gm/nm3 and 25-60 gm/nm3 respectively. The ball mill power consumption is
higher, i.e., 22-30 kWh/t of product as compared to that of the roll mill which is 12-15 kWh/t
of product. Dust is collected in raw mills in which the combined drying and grinding using kiln
gases is adopted, by the electrostatic precipitator operating in combination with the conditioning
tower. Due to the very fine nature of dust, cyclones/multiclones are not used in this section as
final dust collectors.
• Kiln
The major source of particulate pollution in any cement factory are the kiln exhaust gases. In
case of wet process kilns, gas temperature is normally below 200oC and dew point is often high
above 70oC. The use of dust settling chamber/cyclone is not feasible as it cannot meet the
emission standards prescribed by the state/central pollution control board. In case of the semi-
dry process kilns, the gas outlet conditions are suitable for the installation of ESP. The
temperature of the exit gas from suspension preheater dry process kiln is about 330-360oC.
• Clinker cooler
The planetary cooler does not require dust collection since the cooler air is drained into the kiln
through tubes mounted on the periphery of the kiln outlet end. The temperature of the outlet
gas is about 200-220oC and the quantity of dust generation is of the order of 5-10 gm/nm3. Bag
filters for grate coolers are also in use having pulse jet polyester as a fabric material preceded by
heat exchanger.
• Coal mill
In the coal mill, gases are de-dusted either by installing bag filters or ESPs. Coal being highly
volatile in nature, causes problems like fire and explosions which may damage the air pollution
control equipment. The dust concentration of the exhaust gases from the coal mill is in the
range of 25-60 gm/nm3 and dust consists of very fine particles around 71% less than 5 microns
in size.
• Cement mill
Like raw material grinding, cement grinding is another process which generates considerable
amount of dust. It is estimated that 7-10% cement is normally lost due to uncontrolled emission
in cement mill. Apart from the pollution, it is financially critical to take effective steps to curb
this nuisance and recover the maximum amount of generated waste as possible. Dust
concentration after the cement mill is normally in the range of 60-150 gm/nm3 and consists of
very fine particles around 50% less than 5 microns in size. The exhaust temperature of gases
leaving the cement mill is about 80-100oC. In the case of internal water spray systems where
ventilated air is less and gas has higher humidity, ESP is found to be more suitable. For mills
with external water spray, either high ratio fabric filter or ESP can be used.
• Packing section
In packing house dust from the various generation points such as hoppers, handling points etc.,
is extracted through proper hoods and sent to a common dust collection unit. Dust
concentration in the exit air from the packing section is normally in the range of 20-30 gm/nm3
and particle size is around 65% less than 5 microns in size. Fabric filter is generally preferred as
a dust collector because its efficiency is very high even for very small particles.
Operational problems
The main operational problems in the use of fabric filters are:
- Variation in filtration velocity
- Gas temperature below the dew point of gas causing clogging of bags
- Variation in pressure drop
- Improper gas flow distribution in various compartments
- Cleaning system and its operations
- Flow control systems inlet ducting, fans, instrumentation, etc.
- Fire and explosion hazard
The recommended dust collectors for different sections in the cement plant are given in Table
6.2.20. The estimated value of dust collected per annum for a typical 3000 TPD cement plant is
also summarized.
Dust emissions and compliance with emission regulations

A number of factors are responsible for the high dust generation in the cement industry. These
factors classified as external constraints include poor quality of coal, power, non-availability of
spare parts, etc., and have to be tackled at the national level. The internal constraints are
essentially those associated with the improper selection of operation and maintenance of the
dust control equipment installed, problems in installing new dust collectors due to layout
constraints, non-availability of trained manpower, etc. These constraints, however, could be
rectified by the plant management.
Table 6.2.20. Dust collection for different sections in the cement plant
Section Dust Collector Quantity of Ave. cost of Estimated value of
dust dust (Rs/t) collected dust per
collected annum (million Rs)
(TPA)
Crusher Bag filter 2739 110 3.01

Raw mill Bag filter/ESP } 118305 } 230 } 272.10
Kiln Bag filter/ESP } } }
Clinker cooler ESP/Bag filter with 31505 960 302.45
heat exchanger
Coal mill Bag filter/ESP 4396 1170 51.43
Cement plant Bag filter/ESP 29971 1080 323.69
Packing plant Bag filter 13306 1105 147.03
External constraints
There is a wide variation in the quality of coal received by the cement plants for use in the
production process. The ash content of the coal varies from 22-45% and the calorific value from
3000-5000 kcal/kg coal. The variation in the coal used frequently leads to improper combustion
and control of air flow, resulting in high concentration of CO in the exit which in turn creates
the danger of an explosion in the ESP. Instances are not unknown in cement manufacture when
the CO concentration goes up to as high as 0.2-0.6% in the air as a result of high dust emissions.
For proper operations of the ESP equipment, there must be a continuous and regular supply of
power. Long duration of low voltage fluctuations and unscheduled power cuts adversely affect
the efficiency of precipitators in controlling and regulating emissions. These problems can be
gotten rid of when plants are equipped with captive power units of sufficient capacity so as to
enable ESP to perform effectively.
A common problem faced by the cement plants in controlling pollution is the non-availability of
spare parts. In the case of fabric filters, non-availability of filter media is a major constraint. In
the coal mills section of the plant, there should always be an ample stock of spare bags which is
not always possible because in the case of pulse jet filters, the bags have to be imported. Also,
fiber glass fabrics are not indigenously manufactured and have to be imported at a great expense.
Internal constraints
High dust emission in a cement plant is either due to the absence of efficient dust collectors or
due to the improper maintenance and operation. Most of the dust collectors have been reported
to be inefficiently operated. It has been found that 63% of ESPs installed in the kiln section emit
more than 250 mg/nm3 which is undesirable.
In the wet process of cement production, the de-dusting of kiln gases is a serious problem
because of its partially calcined nature. Reports of investigations indicate that the chemical
nature of dust generated by the wet process varies widely. There are various techniques presently
available for controlling kiln dust in the wet process of manufacture such as insufflation, scoop
method, mixing with slurry, nodulization and feeding in the kiln. The technique generally
adopted, however, depends on the nature of dust generated, plant layout, etc.
It is necessary to train manpower in the industry to maintain a clean environment. Programs can
be initiated with the objective of training personnel in the monitoring of dust emission-related
instrumentation and environmental improvement.
The state-wise distribution of major cement factories and their pollution control status is given
in Table 6.2.21.
Table 6.2.21. Pollution control status and state-wise distribution of cement factories in
India
State No. of Units Units Coupling Units No Action
Emission Closed
Standards
Andhra Pradesh 18 16 -
Assam 1 - 1
Bijar 6 1 2 2
Gujarat 10 7 1
Haryana 2 1 -
H.P. 2 1
J&K 1 1
Karnataka 8 6 1
Kerala 1 1
M.P. 14 10
Maharashtra 5 5 1
Maghalaya 1 1
Orissa 2 1
Rajasthan 10 7 1
Tamil Nadu 8 5
Uttar Pradesh 4 1
West Bengal 1 1
It is seen that the performance of cement plants in the states of Andhra Pradesh, Karnataka,
Madhya Pradesh, Gujarat, Rajasthan and Tamil Nadu has been commendable in the
implementation of pollution control measures. These States have also introduced effective time-
bound programs for the defaulting units.
Technologies available and their cost implications

It has generally been seen that the use of electro-static precipitators (ESP) on kilns have not
been very successful in controlling pollution, particularly in the dry season when there is
shortage of water. A number of alternatives are being considered and discussed below:
- The gas conditioning tower is eliminated from the circuit, and multi-plucking system
is used instead to ensure efficient operation of ESP.
- The use of glass bag filters has been attempted by various cement plants like M/S
Narmada Cement Works. However, the maintenance and upkeep of glass bag filters
is costly. These are also not being presently manufactured in the country and have to
be imported.
- Cement plants set up with foreign collaboration have been experimenting with gravel
bed filters for controlling pollution from the clinker cooler. However since the gravel
has to be imported, they are expensive and therefore have not been proven to be
popular so far.
- Despite the use of ESP for dusting kiln, high emission of CO gas have been detected
in the past. ESP has not been successful due to large fluctuations in the quality of
coal received. Cement plants have installed bed-blending systems to achieve a certain
level of homogenization of the coal received and limit the effect of variation in ash
content. The system is expensive, costing around Rs.100 to 150 million.
- The ability of ESP's to control pollution has been severely curtailed by frequent
failures in the supply of electricity as well as voltage fluctuations.
6.2.5.3 Status of Research and Development
Only a few manufacturing units have established in-house research and development (R&D)
facilities. In most of the units, R&D is confined to testing and quality control purposes only.
Out of the 54 sample units for study, only 3 units have given details of R & D projects done by
them. The nature of projects undertaken by R&D, specifically related to energy economics are as
follows :
- Evaluation of various techniques for moisture reduction in wet process plants for
achieving fuel economy
- Evaluation of grinding aids for improved clinker grinding and energy saving
- Use of mineralizers and fixtures in manufacture of clinker for fuel economy
- Study on using lignite as fuel
- Optimizing the process parameters for kiln and mills.
6.3 COUNTRY REPORT: PHILIPPINES
6.3.1 Introduction
The Philippine economy is projected to sustain its positive growth attained during the
previous years. In view of the government’s efforts to provide adequate supply of energy
into the mainstream of each and every users of energy, it is the government policy to
promote energy conservation and efficiency in the commercial, transport, industrial, and
household sectors.
One of the major imports that depletes foreign exchange of the country is oil. Due to the
projected continuing industrial growth of the country, the country’s primary energy
requirement is expected to reach 248 million barrels of oil equivalent in the year 2000 which
will be double the consumption in 1993.
As energy saved becomes a new energy resource, the thrust towards energy self-reliance
through the development and conservation of energy continues to be the major component
of the country’s national development efforts.
The cement industry is one of the highest energy-intensive industrial sectors. Hence, there
are various opportunities for energy savings. The industry has been in operation for more
than 30 years and has weathered all ups and downs. Now that the economy is gaining
momentum for progress, there is a great deal of enthusiasm among manufacturers to
increase their production relative to the market demand as well as an increasing concern for
production efficiency. This has created a growing awareness as to the effects of pollutants
emitted by the industry for over three decades now.
6.3.2 Technological trajectory of the Philippine cement industry
6.3.2.1 Production capacity
The Philippine cement industry is composed of eighteen cement plants with a total
combined annual output capacity of 7.4 and 9.7 million tons of clinker and cement,
respectively (see Table 6.3.1). These manufacturing firms are on an average 30 years old and
there are 32 kilns installed with an average age of 24 years.
Table 6.3.1. Sizes and capacity of the cement industry by process type
Process type No. of plants Capacity in million tons (Mt)
Clinker Cement
Dry 9 3.8 4.9
Semi-dry 2 0.8 0.9
Wet 7 2.8 3.9
Total 18 7.4 9.7
Source: IRS Study Report, 1991
In terms of cement capacity output, the dry process accounted for 51% of the combined
process output while the remaining were shared by semi-dry (9%) and wet process (40%)
Since 1981, PHILCEMCOR (a cement manufacturers association) has been re-rating the
industry’s output capacity of clinker production on a yearly basis. Table 6.3.2 shows the
utilization of the re-rated capacity which is high at 83% in 1989. The reason for re-rating the
industry’s capacity is that majority of the existing plants are too old to operate at their
original rated capacities. Re-rating them occasionally improves the current condition of the
equipment. No data is available for re-rated capacity in the finish mill section. In Table
6.3.3, the production mix of the Philippine cement industry by process type is compared
with that of Japan and Indonesia.
Table 6.3.2. Capacity utilization for clinker production (Mt)

Year Re-rated capacity Clinker production Utilization (%)
(Mt) (Mt)
1981 5.6 3.8 70
1982 5.6 4.2 75
1983 5.7 4.3 76
1984 5.8 3.5 60
1985 5.2 2.8 54
1986 5.8 3.0 51
1987 5.0 3.4 68
1988 5.9 4.7 80
1989 6.0 5.0 83
Table 6.3.3. Comparison of production-mix of cement processes in the Philippines,

Japan and Indonesia (%)
Process Philippines Japan Indonesia
Dry 50.8% 96.1% 96.7%
Semi-dry 34.7% 3.9% 0.7%
Wet 14.5% - 2.6%
Total 100.0% 100.0% 100.0%
On the basis of cement production, the industry registered an average production of 4.2
million metric tons from 1975 to 1980. The production output was short-lived, however,
when it dipped to about 3.5 million metric tons in 1985. However, it later increased in the
late 80’s and the early 90’s. In 1991, total production was about 7 million metric tons,
representing 74% of the total combined production capacity of the industry. In 1993, cement
production was 83% of the industry’s base plant capacity. Forecast indicates that the demand
will continue to grow at the rate of 5.6% annually up to the year 2000, reaching 12 million
metric tons.
6.3.2.2 Plant development
In the early 70’s, the cement industry being a highly energy intensive sector was faced with
serious technical as well as financial problems resulting primarily from escalating fuel costs
and devaluation of currency. In view of the economic slump and excess capacity situation
during the first half of the 1980’s, cement companies experienced difficulty in meeting their
loan obligation. Thus, government-owned financial institute bailed them out by
implementing a financial rehabilitation program which involved the conversion of the
company’s loan into equity.
One of the milestones of the Philippine cement industry is the issuance of the Letter of
Instruction no. 752 and 1094 in 1980, which states among others the switching of fuel from
bunker oil to coal in the existing plants. This was done in order to lessen the industry’s
dependence on crude oil as energy source. To put further relief to these manufacturing
companies from other financial obligations, the government on the same token, liberalized
importation of coal. To date, all cement manufacturing plants have converted to coal.
With the industry’s cement demand steadily climbing up since 1988, the government
launched the Cement Industry Rehabilitation program whose aim is to provide adequate
supply of cement in the local market. With the outdated processes and aging equipment,
without a major rehabilitation effort, it is possible that the current production may fail to
meet the demand in the coming years. Some developmental/rehabilitation projects adopted
by some of the cement firm are:
- installation of additional equipment;
- conversion from direct to indirect firing system;
- improvement of existing facility;
- rehabilitation of small capacity kilns to achieve rated output;
- conversion of semi-dry process to dry process;
- installation of precalciner to increase plant capacity; and
- rehabilitation of clinker cooler to increase kiln capacity.
6.3.3 Evolution of energy efficiency in the Philippine cement industry
There are three types of processes employed by the industry. These are the wet, dry and
semi-dry processes. The technologies employed in the Philippines are outdated, resulting in
high fuel and electricity consumption. For instance, the average heat consumption of the
industry is 1200 kcal/kg clinker, while the average specific power (electricity) consumption is
129 kWh/ton cement, much higher than that in the industrialized countries.
The Philippine cement industry is heavily dependent on the following types of energy
sources: coal, petcoke, bunker oil and electricity. For thermal usage, Table 6.3.4 shows that
shares of local coal was 52% and the remaining amount came from imported coal (22%),
petcoke (7%), fuel oil(18%) and others (1%).
Table 6.3.4. Share of fuel consumption (%)

Year Local coal Imported Petcoke Fuel oil Others
coal
1991 59.0 27.0 4.0 9.0 1.0
1992 50.7 17.3 8.8 22.5 0.7
1993 47.0 21.0 9.0 23.0 0.3
1994 52.0 22.0 7.0 18.0 1.0
Energy audits conducted by the Office of Energy Affairs for the “Sectors Study report for
the Cement Industry” in 1989 reported that in the wet process, energy input is relatively
much higher at 85% compared to the dry process which is only 75%. This is understandable
owing to the fact that in the wet process, water in the slurry accounts for 40% more of the
input energy (see Table 6.3.5).
Table 6.3.5. Energy usage in the cement industry

Total Energy Input (%)
Dry Wet
Mechanical Power Drive 24 12.1
Process Heating 74.5 85.4
Transport/Out-of Plant 0.5 1.2
Equipment
Lighting/Air Conditioning 1 1.3
Total 100 100
Source: Sectoral Study for the Cement Industry, 1989.
Table 6.3.6 shows that the wet process specific energy consumption is very high, ranging
from 141.03 to 188.05 kgoe/ton cement compared to the acceptable international standard
range which is 94.88 to 102.57 kgoe/ton cement. However, in the dry process the specific
energy consumption shows sign of potential for improvement. It attained the highest
specific energy consumption at 122.23 kgoe/ton-cement down to 103.43 kgoe/ton-cement
while the acceptable level was from 68.38-105.13 kgoe/ton-cement.
Table 6.3.6. Average specific energy use by process type in the Philippines
Process 1991 1992 1993 1994
Dry 112.83 122.23 103.43 68.38 - 105.13
Semi-dry 150.44 159.84 141.03 -
Wet 141.03 197.45 188.05 94.88 - 102.57
Average 135.05 159.84 144.45
From the study conducted in 1991 to 1993, the specific electrical power consumption of the
industry averages 130 kWh/ton cement. In comparison with its Asian neighbors, the
Philippine cement industry was lagging behind in efficiency improvement (see Table 6.3.7).
This indicates that the cement sector is operating quite inefficiently.
Table 6.3.7. Specific electrical energy consumption of the

Philippines in comparison with other Asian countries, 1993
SPC, kWh/ton cement
Thailand 85
Japan 96
Korea 107
Taiwan 108
Indonesia 114
Malaysia 114
Philippines 130
Source: PHILCEMCOR,1994
For the same period, the specific power consumption (SPC) by process type indicates that
the semi-dry process has an SPC of 157 kWh/ton cement, followed by the dry process at
142 kWh/ton cement and the wet process at 105 kWh/ton cement (see Table 6.3.8).
Table 6.3.8. Specific power use by process, in kWh/ton cement (1991-1993)

Wet Dry Semi-dry
Crushing 2.4 2.5 1.8
Raw milling 24.4 32.6 34.4
Burning 34.2 38.7 38.4
Finish milling 44.5 47.7 45.7
Packing 1.8 2.8 2.3
Services 5.4 5 5.6
Industry 105.2 142 156.8
Source: PHILCEMCOR, 1994.
Kiln is one of the major energy-intensive users of energy. The industry’s Kiln Specific
Energy Consumption (KSEC) averaged 103.62 kgoe/ton clinker.
6.3.4 Environmental externalities of the cement industry in the Philippines
6.3.4.1 Environmental standards for pollution control and abatement
The rules and regulations for environmental protection in the Philippines were published in
1978 by the National Pollution Commission. The said rules and regulations cover air quality
control, water quality control, noise level control and procedures for application.
In the regulation, the degree of pollution is classified into three categories based on the
degree of severity: the highly pollutive zone, the pollutive zone and the non-pollutive zone.
Air pollution is classified on the basis of value for air likely to cause the surrounding air
around a plant (500 meter radius) to contain the amount of substances specified in the
pollution control standards. Water pollution on the other hand, is classified on the basis of
value likely to contain the pollutive parameters of effluents specified in the control standard.
For comparison with other Asian countries, typical figures applicable to the same industry of
Japan and Taiwan are as follows:
a. Air quality
Particulate:
Philippines - 500 mg/scm for existing sources
- 300 mg/scm for new sources
Taiwan - 217 mg/scm for sources with exhaust gas volume of 500 scm/min
- 217 mg/scm for sources with exhaust gas volume of 300 scm/min
Japan - 100 mg/scm for sources of cement kiln
SOx:
Philippines - 1587 ppm
Taiwan - 500 ppm
Japan - based on individual plant installation and exhaust gas volume
NOx:
Philippines - 1587 ppm
Taiwan - 500 ppm for solid fuel sources
Japan - 350 ppm for sources with exhaust gas volume < 100,000 scm/min
The air quality standard in the Philippines is considered to be mild compared to other
countries. However, in consideration of the accumulated amount of pollutants by which the
environment may be much affected in the near future, the present air quality standards
should be changed to some extent.
b. Water quality
The present water quality standards include a lot of quality parameters to be monitored.
However, only a few quality parameters which are considered to be applicable to the cement
industry are shown below.
pH:
Philippines - 6.0 - 8.5 for class “D” water
Taiwan - 5.0 - 9.0
Japan - 6.0 - 8.5 for class “D” water
Temperature:
Philippines - 40OC
Taiwan - Max. rise shall not exceed 4OC
Japan - No provision
c. Suspended solids
Philippines - 75 mg/1 (75 ppm) for class “D” water
Taiwan - 300 ppm
Japan - 100 ppm for class “D” water
Almost all wastes from a cement plant is usually discharged from a water cooling pond. The
wastewater, therefore, is discharged substantially from the cement plant with no special
pollutants, except for a few suspended solids.
6.3.4.2 Pollution control equipment
Table 6.3.9 shows the type of dust collectors installed by the cement industry. Some 24
percent of the total number of production sections in the industry have no dust collector
equipment. A few dust collectors are installed in the crusher and raw material drier sections.
Most cement plant operators believe that these sections do not emit much dust. Actually, a
lot of fine particles is produced in these sections and some are discharged into the
atmosphere. Therefore dust collectors with high efficiency should be immediately installed
especially in the drier section.
Table 6.3.9. Distribution of dust collectors installed in the Philippine cement

industry (# of cement plants)
Application Electro-static Bag filter Multi- Single Number of
Area section precipitator cylone cylone installations
Crusher 1 4 0 2 10
Drier 4 2 0 10 -
Raw Mill 6 5 0 0 6
Kiln 10 2 1 3 1
Cooler 0 0 15 1 1
Cement Mill 2 4 0 1 -
Packing 0 17 0 0 -
House 19.3 37 14.3 5 24.4
Percent (%)
Source: IRS study for the cement sector, 1991.
6.3.5 Potential for energy efficiency improvement and pollution abatement through
technological change
The list of energy efficiency projects undertaken by the cement industry shows a varying
degree of application in stages. These include maintenance program to mid-range capital
investment such as combustion control and waste heat recovery system. Likewise, the long-
range program of coal conversion for cement plants which started in 1980 is completed.
From the study report on cement industry by the Office of Energy Affairs in 1989, there is
considerable scope for application of various energy efficiency technologies identified and
this is discussed below with the corresponding estimated energy savings.
Combustion Control
For kiln process operation, combustion control systems are indispensable for energy
efficient operations. From the survey conducted, flue gas analysis was prevalently used.
In some of the plants audited, combustion control system are likewise utilized. However, the
need for improvement in terms of additional controls and instrumentation has been
identified. The potential savings from the technology was estimated to reach 5113 kgoe
annually. This represents 0.2% of the industry’s total consumption for 1988.
Cogeneration System
Cogeneration is the simultaneous production of electricity and thermal energy from a single
energy source. In the case of dry process plants, the higher temperature levels permit
installation of the waste heat recovery boilers and turbo generators for in-plant generation.
The estimated potential saving for this type of technology is 20968 kgoe annually,
representing 0.8% of the industry’s 1988 level of energy consumption.
Process Conversion
In the case of the wet process plant, conversion to the dry process is a major step in
reducing fuel consumption while increasing production capacity. The potential saving was
estimated at 102,571 kgoe annually representing 4.2% of the industry’s 1988 level of
consumption.
Waste Heat Utilization

An example of the waste heat recovery employed in the industry is the use of hot air from
the clinker cooler to heat secondary air to kiln or for drying of raw feed materials. Proper
insulation of ducts and hot portions in the system are likewise employed. In line with this,
most plants use high quality refractories and better quality insulation to reduce heat losses.
Waste heat recovery from kiln system, however, has not been adopted yet. The estimated
saving for this type of the technology is 6898 kgoe annually, representing 0.3% of the 1988
energy consumption of the industry.
Coal and Waste Fuel Utilization

All cements plants have converted to coal firing system since the early 80’s. Although
problems of the consistency of coal quality and price are encountered, coal utilization is still
viewed as an acceptable energy conservation measure over other liquid fuels. Aside from
this, other resources such as rubber tires, rice-hulls, and other combustible wastes are also
being utilized. Of the 18 cement plants, four have utilized these waste fuels as
supplementary energy source.
A new technology using Suspension preheater with Precalciner (SPP) and vertical roller mill
is popular in the cement industry of many countries. This technology can reduce the present
heat and electricity consumption of the industry by as much as 50%
6.3.6 Status of Application of New Technologies
As of June 1990, there were thirteen cement firms adopting various rehabilitation and/or
improvement projects. The production output in 1990 increased by 50% in reference to the
1988 output after improvement/rehabilitation projects were completed. These projects are:
- Installation of kiln with a capacity of 2000 tons per day.
- Conversion of direct fired system to indirect fired systems
- Improvement/upgrading of existing facility to increase capacity from 1000 tons to
1750 ton/day/unit
- Total rehabilitation to achieve rated capacities of small kilns.
- Installation of Precalciner to increase plant capacity to 2,700 tons/day.
- Rehabilitation of clinker cooler to increase kiln output capacity to 1600 tons/day.
6.3.7 Concluding Remarks
There is a tremendous opportunity for improving the efficiency of energy utilization in the
cement industry not only because of its big share in the energy consumption but also
because the sector consists of relatively manageable number and sizes of energy-consuming
equipment facilities compared to the other sectors. Technologies to improve the efficiencies
at the end-user level have been identified, and to some extent, are already being appreciated
by the industry. Relieving the increasing burden of energy cost by achieving greater energy
efficiency will undoubtedly contribute significantly to lower production cost and enhanced
competitiveness of the industry.
BIBLIOGRAPHY
Sections 1-4
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Experiences”, Tokyo.
Bhattacharya, D., 1991. “Assessment of Energy Consumption Pattern Through Energy Analysis
of Cement Industry”, Energy Management, January-March, pp. 5-9.
Bonn, W., and Lang, Th., 1987. “Burning process (Kiln systems; material cycles; refractory
lining; coating problems)”, Process technology of cement manufacturing, Proceedings of VDZ-
kongress ‘85, Bauverlag GmbH, Berlin pp. 368 - 384.
Braig, H., 1987. “Measures for reducing the noise emission from a cement plant”, Process
technology of cement manufacturing, Proceedings of VDZ-kongress ‘85, Bauverlag GmbH,
Berlin pp. 625 - 628.
Bush, C.W., 1979. “The Decision for Cogeneration at Riverside Cement”, ICS Proceedings.
Canadian Portland Cement Association, 1989. “Resources recovery: the cement kiln solution”.
Dodson, V.H., 1990. “Concrete admixtures”, Structural engineering series, Van Nostrand
Reinhold, New York.
Fassbender, A. G., Mcgee, M. M. and Yanase, Y., 1983. “Energy Efficient Industrial
Technology in Europe and Japan”, Noyes Data Corporation, Park Ridge, New Jersey, U.S.
Fog, M.H. and Nadkarni, K.L., 1983. “Energy Efficiency and Fuel Substitution in the Cement
Industry with Emphasis on Developing Countries”, World Bank Technical Paper.
George, R.G., 1981. “Designing a Pyroprocessing System for Cement”, ICS Proceedings.
Gilliland, J., 1973. “Air pollution control in Portland cement industry”, Industrial air pollution
control, edited by Kenneth Noll and Joseph Duncan, Ann Arbor Science Publishers inc.,
Michigan, USA pp. 195 -202.
Gordon, M., 1986. “Cost Effective Energy Reduction in the Cement Sector”, Energy
Management Focus, Issue No. 7, p. 26-28.
Jhansen, V., Egeløv, A.H., and Eiriksson, A.O., 1987. “Emission of Nox and SO2 from cement
clinker burning”, Process technology of cement manufacturing, Proceedings of VDZ-kongress
‘85, Bauverlag GmbH, Berlin pp. 634 - 637.
Katsuki, M.H. and Yano, M., 1985. “Automatic Kiln Control with the Aid of a Process
Computer”, Process Technology of Cement Manufacturing, p. 548-552, Tokyo, Japan.
Kirchner, G., 1987. “Behavior of heavy metals during cement clinker burning”, Process
technology of cement manufacturing, Proceedings of VDZ-kongress ‘85, Bauverlag GmbH,
Berlin pp. 637 - 641.
Kreft, W. and Schütte, R., 1987. “Influence on nitrogen oxide emission of the operating
parameters of the cement burning process”, Process technology of cement manufacturing,
Proceedings of VDZ-kongress ‘85, Bauverlag GMBH, Berlin pp. 645 - 649.
Kroboth, K. and Xeller, H., 1987. “Developments in environmental protection in the cement”,
Process technology of cement manufacturing, Proceedings of VDZ-kongress ‘85, Bauverlag
GMBH, Berlin pp. 600 - 621.
Kuklis, A. and Mcintyer, G.T., “Adaptation of Automation in the Cement, Salt, and Iron
Industries in South-Central United State”.
Labahn, O. and Kohlhaas, B., 1983. “Cement Engineers’ Handbook”, 4th ed., Bauverlag
GmbH, Wiesbaden and Berlin.
Misgra, J.C., Srivastava, V.K., and Narang, K.C., 1979. “Characterization of kiln dust and exit
gases from cement plants”, Process technology of cement manufacturing, Proceedings of VDZ-
kongress ‘77, Bauverlag GMBH, Berlin pp. 550 -554.
Nemerow, N.L., 1978. “Industrial water pollution: origins, characteristics and treatment”,
Addison-Wesley Publishing Company Inc., Reading, Massachusetts, pp. 569 - 571.
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Lewis Publishers, Inc.
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Age International Limited, New Delhi. ISBN 81-224-0301-8
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cement plants”, Process technology of cement manufacturing, Proceedings of VDZ-kongress ‘85,
Bauverlag GMBH, Berlin pp. 668 - 671.
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Industrial Technologies in Asia, May 29 - 31, 1995, Manila, Philippine.
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Industries”, Energy Convers. Mgmt, Vol. 33, No. 12, pp. 1037-1078.
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December 1994.
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Wahyu, H, and Abudurrachman, A.,1993. “Energy Auditing in Large Industries- A Case Study
in Cement Industry”, Technical Report, AAECP/Energy Project Phase II, RDCAP LIPI Bandung.
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SECTION 5:
Economic and Social Commission for Asia and the Pacific (ESCAP), 1993. “Statistical
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Environmental Externalities of the cement Industry in India”, Ministry of Power, India, Paper
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Efficiency and Environmental Externalities of the cement Industry in Sri Lanka”, Paper presented
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Potential in the cement Industry”, Asian Institute of Technology, Bangkok, Thailand.
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SECTION 6.1
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SECTION 6.2
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Association (CMA), May 1995.
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Costs & Prices (BICP), Ministry of Industries, Government of India, March 1994.
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and National Council for Cement & Building Materials (NCCBM).
The Asian Institute of Technology (AIT) is an autonomous international academic institution
located in Bangkok, Thailand. It’s main mission is the promotion of technological changes
and their management for sustainable development in the Asia-Pacific region through high-
level education, research and outreach activities which integrate technology, planning and
management.
AIT carried out this Asian Regional Research Programme in Energy, Environment and Climate
(ARRPEEC), with the support of the Swedish International Development Cooperation Agency (Sida).
One of the projects under this program concerns the Development of Energy Efficient
and Environmentally Sound Industrial Technologies in Asia.
The objective of this specific project is to enhance the synergy among selected developing
countries in their efforts to adopt and propagate energy efficient and environmentally sound
technologies. The industrial sub-sectors identified for in-depth analysis are iron & steel,
cement, and pulp & paper. The project involves active participation of experts from
collaborating institutes from four Asian countries, namely China, India, the Philippines, and Sri
Lanka.
The technological trajectories, energy efficiency and environmental externalities of the pulp
and paper industry in the four Asian countries are presented in this document (Volume I).
Other related publications based on this research finding include:
Volume I Technology, Energy Efficiency and Environmental Externalities in the

Cement Industry
Volume II Technology, Energy Efficiency and Environmental Externalities in the

Iron & Steel Industry
Volume IV Regulatory Measures and Technological Changes in the Cement, Iron

& Steel, and Pulp & Paper Industries
An assessment of the implementation of energy efficient and environmentally sound

industrial technologies among the selected countries is presented in a separate “Cross-
Country Comparison” Report.
TE O F T E
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TECHNOLOGY, ENERGY EFFICIENCY

AND ENVIRONMENTAL EXTERNALITIES

School of Environment, Resources and Development

Raw Materials Raw Materials

Screening & Milling Electricity Dust Screening & Milling

Proportioning & Proportioning &

Heated Air Heated

Mixing with gypsum and Electricity Mixing with gypsum and

Finished Packaged Finished Packaged

School of Environment, Resources and Development

© Asian Institute of Technology, 1997

Edited by Brahmanand Mohanty

Published by School of Environment, Resources and Development

ISBN 974 - 8256 – 70--7

Printed in India by All India Press, Pondicherry.

The Asian Regional Research Programme on Energy, Environment and Climate

Faculty Members (Asian Institute of Technology - School of Environment,

Research Associates (Asian Institute of Technology - School of Environment,

National Research Institutes

BIBLIOGRAPHY ...................................................................................................................... 102

Rapid industrialization and infrastructure development in Asian developing countries has

The principal raw materials for cement manufacturing are:

The major processes involved in production are:

Table 2.1. Portland cement clinker compounds

Fig. 2.1. Steps in the manufacture of Portland cement

2.1 Cement Kiln

CaCO3 ⇑ CaO + CO2

Al2O3 + CaO ⇑ CaO.Al2O3 (mono-calcium aluminate)

2CaO.SiO2 + CaO ⇑ 3CaO.SiO2 (tri-calcium silicate)

2.2 Cement Kiln Processes

2.2.1 Wet process

Worldwide, a considerable proportion of cement clinker is still produced by the wet

Fig. 2.2. Diagram of a typical wet procvess rotary kiln

Fig. 2.3. Diagram of a typical preheater system

2.2.2 Semi-wet processes

2.2.3 Semi-dry process

2.2.4 Dry process

Fig. 2.4 Diagram of a shaft kiln

Fig. 2.5 Diagram of grate-kiln process

3. ENERGY ISSSUES IN THE CEMENT INDUSTRY

3.1 Typical Energy Consumption Patterns

* T he dotte d lin e re pres ents We t Pro ces s on ly

Fig. 3.1a. Flow diagram s of a typical dry process cement plant

* Th e dot ted l ine re pres ents Wet Proc ess only

Fig 3.1b.Flow diagram of a typical wet process cement plant

Raw materials preparation Clinker production Finishing Others

Figure 3.2. Typical specific energy consumption for cement manufacturing

3.2 Energy Efficiency Measures

3.2.1 Short term measures

- ensuring the uninterrupted operation of the kiln

3.2.2 Medium term measures

3.2.2.1 Measures on processed materials and products

(i) Installation of dust collection system

(ii) Diversification of cement products

3.2.2.2 Changes and modifications in sub-processes

(i) Reduction of water content of slurry

(ii) Installation of dual firing system

Table 3.2. Specific electricity consumption of cement grinding systems

(iv) New rotary kiln

(v) Operating the mill in closed loop instead of open loop

(i) Open-circuit (ii) Closed-circuit

Figure 3.3. Processes of size reduction

3.2.2.3 Recovery of waste heat