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SP (KN/KN) S34069/2 ©CIE 2003
[Turn over
CAMBRIDGE INTERNATIONAL EXAMINATIONSGeneral Certificate of EducationAdvanced Subsidiary Level and Advanced Level
CHEMISTRY
9701/01
Paper 1 Multiple ChoiceMay/June 2003
1 hour
Additional Materials:Data BookletMultiple Choice Answer SheetSoft clean eraserSoft pencil (type B or HBis recommended)
READ THESE INSTRUCTIONS FIRST
Write in soft pencil.Do not use staples, paper clips, highlighters, glue or correction fluid.Write your name, Centre number and candidate number on the answer sheet in the spaces providedunless this has been done for you.There are forty questions on this paper. Answer
all
questions. For each question there are four possibleanswers,
A
,
B
,
C
, and
D
.Choose the
one
you consider correct and record your choice in
soft pencil
on the separate answer sheet.
Read the instructions on the Answer Sheet very carefully.
Each correct answer will score one mark. A mark will not be deducted for a wrong answer.Any rough working should be done in this booklet.
 
2
9701/1/M/J/03
Section A
For each question there are four possible answers,
A
,
B
,
C
, and
D
. Choose the
one
you consider to becorrect.
1
The use of the Data Booklet is relevant to this question.
What is the number of molecules in 500 cm
3
of oxygen under room conditions?
A
1.25 x 10
22
B
1.34 x 10
22
C
3.0 x 10
22
D
3.0 x 10
26
2
In the preparation of soft margarine, glyceryl trieleostearateis suitably hydrogenated so that, on average, one of its side-chains is converted into theCH
3
(CH
2
)
4
CH=CHCH
2
CH=CH(CH
2
)
7
CO
2
residue and two side-chains are converted into theCH
3
(CH
2
)
7
CH=CH(CH
2
)
7
CO
2
residue.How many moles of hydrogen are required to convert one mole of glyceryl trieleostearate into thesoft margarine?
A
4
B
5
C
6
D
9
3
Which isotope of an element in the third period of the Periodic Table contains the same number ofneutrons as S?
A
Na
B
Mg
C
Si
D
P
4
The successive ionisation energies, in kJmol
–1
, of an element
X
are given below.870 1800 3000 3600 5800 7000 13200What is
X
?
A
33
As
B
40
Zr
C
52
Te
D
53
I
31152814241223113216
CH
3
(CH
2
)
3
CHCHCHCHCHCH(CH
2
)
7
CO
2
CH
2
CH
3
(CH
2
)
3
CHCHCHCHCHCH(CH
2
)
7
CO
2
CHCH
3
(CH
2
)
3
CHCHCHCHCHCH(CH
2
)
7
CO
2
CH
2
 
3
9701/1/M/J/03
[Turn over5
Which of the following solids has a simple molecular lattice?
A
magnesium oxide
B
sodium
C
silicon(
IV
) oxide
D
sulphur
6
Measured values of the pressure, volume and temperature of a known mass of a gaseouscompound are to be substituted into the equation
pV = nRT 
in order to calculate the relative molecular mass,
M 
r
, of the compound.Which conditions of pressure and temperature would give the most accurate value of
M 
r
?
7
Gaseous phosphorus pentachloride can be decomposed into gaseous phosphorus trichloride andchlorine by heating. The table below gives the bond energies.What is the enthalpy change in the decomposition of PC
l 
5
to PC
l 
3
and C
l 
2
?
A
–420kJmol
–1
B
–90kJmol
–1
C
+90kJmol
–1
D
+420kJmol
–1
pressuretemperature
A
highhigh
B
highlow
C
lowhigh
D
lowlowbondbond energy/kJmol
–1
P-C
l 
(in both chlorides)330C
l 
-C
l 
240
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