Determinación del Punto de equivalencia de una titulación potenciométrica por el método de la primera

derivada:

HCl

mL
derivada
NaO pH ΔmL primera derivada del pH
del pH
H
2.00 0.67 6
4.00 0.72 3.00 0.025
5
6.00 0.78 5.00 0.03
8.00 0.86 7.00 0.04 4
10.00 0.96 9.00 0.05
3
12.00 1.06 11.00 0.05
14.00 1.26 13.00 0.1 2
16.00 1.40 15.00 0.07
1
18.00 1.63 17.00 0.115
20.00 2.22 19.00 0.295 0
0 5 10 15 20 25
21.00 7.02 20.50 4.8
23.00 11.45 22.00 2.215
25.00 11.71 24.00 0.13 pH vs mL
27.00 11.79 26.00 0.04 14
29.00 11.85 28.00 0.03 12
pH de la disolución

31.00 11.85 30.00 0 10

8 7.02
33.00 11.89 32.00 0.02
35.00 11.92 34.00 0.015 6
37.00 11.95 36.00 0.015
4
2
39.00 11.96 38.00 0.005
0
40.00 11.98 39.50 0.02 0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00
Volumen de NaOH (mL)
HAc

mL
promedio
NaO pH ΔpH/ΔmL ΔpH/ΔmL
mL
H
5
0 2.19
4.5
1 2.91 0.5 0.72
4
2 3.34 1.5 0.43 3.5
3 3.59 2.5 0.25 3
4 3.8 3.5 0.21 2.5
5 3.94 4.5 0.14 2
6 4.08 5.5 0.14 1.5
7 4.22 6.5 0.14
1
0.5
8 4.33 7.5 0.11
0
9 4.44 8.5 0.11 0 5 10 15 20 25 30 35 40 45
10 4.55 9.5 0.11
11 4.66 10.5 0.11
12 4.78 11.5 0.12
13 4.89 12.5 0.11
14 5.03 13.5 0.14
15 5.15 14.5 0.12 pH vs mL
16 5.34 15.5 0.19 14
17 5.55 16.5 0.21 12 10.89
18 5.85 17.5 0.3 10
19 6.52 18.5 0.67 8
pH

20 10.89 19.5 4.37 6

21 11.35 20.5 0.46 4
22 11.54 21.5 0.19 2
23 11.64 22.5 0.1 0
0 5 10 15 20 25 30 35 40 45
24 11.72 23.5 0.08
mL de NaOH
25 11.77 24.5 0.05
26 11.81 25.5 0.04
27 11.85 26.5 0.04
NaOH
28 11.87 27.5 0.02
29 11.9 28.5 0.03
30 11.92 29.5 0.02
31 11.93 30.5 0.01
32 11.94 31.5 0.01
33 11.96 32.5 0.02
34 11.97 33.5 0.01
35 11.99 34.5 0.02
36 11.99 35.5 0
37 11.99 36.5 0
38 12.01 37.5 0.02
39 12.01 38.5 0
mL de promedio
pH ΔpH/ΔmL ΔpH/ΔmL
HAc mL
2 12.18 0.2
4 12.19 3 0.005 0
8 12.16 6 -0.0075 -0.2 0 2 4 6 8 10 12 14 16 18 20
10 12.12 9 -0.02 -0.4
12 12.02 11 -0.05 -0.6
14 11.91 13 -0.055 -0.8
16 11.66 15 -0.125 -1
18 10.85 17 -0.405
-1.2
20 8.73 19 -1.06
-1.4
22 5.92 21 -1.405
-1.6
24 5.46 23 -0.23
26 5.24 25 -0.11
28 5.06 27 -0.09 pH vs mL
30 4.94 29 -0.06 14
32 4.83 31 -0.055
12
34 4.76 33 -0.035
10
36 4.69 35 -0.035
8
38 4.64 37 -0.025 5.92
pH

6
40 4.59 39 -0.025
4
2
0
0 5 10 15 20 25 30 35 40 45
mL de HAc
NH3

mL de promedio
pH ΔpH/ΔmL
HCl mL ΔpH/ΔmL
1 10.13
0
2 9.88 1.5 -0.25
0 5 10 15 20 25
3 9.67 2.5 -0.21 -1
4 9.49 3.5 -0.18
5 9.31 4.5 -0.18 -2
6 9.08 5.5 -0.23
7 8.85 6.5 -0.23 -3
8 8.41 7.5 -0.44
-4
9 2.79 8.5 -5.62
10 1.82 9.5 -0.97 -5
11 1.58 10.5 -0.24
12 1.42 11.5 -0.16 -6
13 1.3 12.5 -0.12
14 1.23 13.5 -0.07
15 1.15 14.5 -0.08
16 1.1 15.5 -0.05
pH vs mL
17 1.06 16.5 -0.04
18 1.01 17.5 -0.05 12
19 0.98 18.5 -0.03 10
20 0.95 19.5 -0.03 8
21 0.92 20.5 -0.03 6
pH

4 2.79
2
0
0 5 10 15 20 25 30 35
mL HCl