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Table Of Contents

PART I. PROPERTIES OF DMSO
Recovery from Aqueous Solutions
PART II SOLVENCY CHARACTERISTICS OF DMSO
PART III REACTIONS OF DMSO
1. Oxidation of DMSO
2. Reduction of DMSO
3. Reaction with Metals
4. Reaction with Strong Bases - Dimsyl Ion
5. Reaction with Acid Halides
6. Reaction with Acid Anhydrides
7. Halogenation of DMSO
8. Reaction with Phenols and Aniline
9. Alcohol Oxidation with DMSO
10. Kornblum Reaction
PART IV. DMSO AS A REACTION SOLVENT
A. DISPLACEMENT REACTIONS IN DMSO
1. Acetylide Ion
2. Alkoxide Ion
4. Amines
5. Ammonia
6. Azide Ion
7. Carbanions
8. Carboxylate Ion
9. Cyanate Ion
12. Hydroxide Ion
13. Mercaptide (or Thiophenoxide) Ion
15. Phenoxide Ion
16. Sulfide (or Hydrosulfide) and Thiosulfate Ions
17. Thiocyanate Ion
B. BASES AND BASE-CATALYZED REACTIONS IN DMSO
Basicities in DMSO
Proton Removal
TABLE XI Acidities in DMSO
ELIMINATION REACTIONS
1. Cope Elimination
3. Dehalogenation
4. Dehydrohalogenation
5. Nitrogen Elimination
6. Sulfenate Elimination
7. Sulfonate Elimination
8. Water Elimination-dehydration
ISOMERIZATION REACTIONS
1. Acetylene Isomerization
2. Allyl Group Isomerization
3. Diene, Triene Isomerization
4. Olefin Isomerization
5. Racemization
CONDENSATION REACTIONS
OXIDATION REACTIONS
REDUCTION REACTIONS
1. Reduction of Alkyl Halides and Sulfonates
2. Reduction of Carbonyl Compounds
3. Reduction of nitroaromatics
4. Reduction of C=C Systems
SOLVOLYTIC REACTIONS
1. Hydrolysis
c) Amide hydrolysis
2. Alcoholysis, Aminolysis
3. Transesterification (Ester Interchange)
1. Polymerization and Spinning Solvent
2. Extraction Solvent
3. Solvent for Electrolytic Reactions
4. Cellulose Solvent
5. Pesticide Solvent
6. Cleanup Solvent
7. Sulfiding Agent
8. Integrated Circuits
1. Toxicity and Handling Precautions
2. Comparative Toxicity of Commercial Solvents
TABLE XII Single-Dose Toxicity (Rats) of Some Common Solvents
TABLE XIII Single-Dose Toxicities to Mice of 4M Solutions
3. Chemicals and Reactions to be Avoided with DMSO
PART VII BIBLIOGRAPHY
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DMSO LIBRO FELIZ

DMSO LIBRO FELIZ

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Published by: silke000 on Nov 03, 2010
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11/29/2012

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