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PCS Phos Acid Manual

PCS Phos Acid Manual

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Manejo del acido fosforico
Manejo del acido fosforico

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Categories:Topics, Art & Design
Published by: Victor Javier Chavarria Vasquez on Nov 10, 2010
Copyright:Attribution Non-commercial

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08/03/2013

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IMPORTANT NOTICE
All information, technical advice and recommendations provided herein or by PCS Sales personnel is intended for use by persons hav-ing skill and knowledge in the handling of industrial chemicals, and no such information shall be deemed as a representation or war-ranty with respect to the Product or Products discussed. Product information and handling procedures are based on our past experi-ence and common practice in the industry. We believe all information given herein and by PCS Sales personnel is accurate and offersuch information in good faith, BUT WITHOUT GUARANTEE OR OBLIGATION AS TO THE ACCURACYOR SUFFICIENCYTHEREOF AND WITHOUT ANYWARRANTYOF MERCHANTABILITYOR FITNESS FOR APARTICULAR PURPOSE. User is sole-ly responsible for determining the suitability of use in each particular situation. PCS Sales specifically DISCLAIMS ANYLIABILITYWHATSOEVER FOR THE USE OF SUCH INFORMATION, including without limitation any recommendations which user mayattempt to apply or may construe as permission to use the Product in a manner that would infringe any patent, license or copyright.
1101 Skokie Blvd., Northbrook, IL 60062
 
T
ABLEOF
C
ONTENTS
Introduction . . . . . . . . . . . . . . . . . . . . . . . .1
General Description . . . . . . . . . . . . . . . . . . . . . . . . . .1Structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1Specifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . .2Availability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Bulk Storage and Handling . . . . . . . . . . . . .3
Storage Considerations . . . . . . . . . . . . . . . . . . . . . . .3Construction Materials . . . . . . . . . . . . . . . . . . . . . . .3
Health and Safety Information . . . . . . . . . .6
Fire, Explosion and Health Hazard Data . . . . . . . .6Toxicological Information . . . . . . . . . . . . . . . . . . . . .6Personal Protective Equipment ................6
Emergency Information . . . . . . . . . . . . . . . .7
Spill Containment . . . . . . . . . . . . . . . . . . . . . . . . . . .7Emergency First Aid Procedures ...............7Transportation Emergencies . . . . . . . . . . . . . . . . . . .7
Applications . . . . . . . . . . . . . . . . . . . . . . .8
Chemical Production . . . . . . . . . . . . . . . . . . . . . . . . .8Food and Beverages . . . . . . . . . . . . . . . . . . . . . . . . . .8Metal Treating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9Refractories and Ceramics . . . . . . . . . . . . . . . . . . . .11Miscellaneous ...............................11
Basic Properties . . . . . . . . . . . . . . . . . . . . .12
Boiling Points . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12Freezing Points . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12Conversion Factors . . . . . . . . . . . . . . . . . . . . . . . . . .13Corrosion Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13Specific Heat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .15Titration Curve . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .15Density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16Dissociation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17Electrical Conductivity . . . . . . . . . . . . . . . . . . . . . . .17Enthalpy
Concentration . . . . . . . . . . . . . . . . . . . .17Heat of Formation,Free Energy of Formation, Entropy . . . . . . . . . . .18Latent Heat of Vaporization . . . . . . . . . . . . . . . . . . .18Refractive Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18Relative Sourness . . . . . . . . . . . . . . . . . . . . . . . . . . . .19Vapor Pressure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19Vapor Composition . . . . . . . . . . . . . . . . . . . . . . . . . .20Viscosity in Centipoise . . . . . . . . . . . . . . . . . . . . . . .21Kinematic Viscosity ofPhosphoric Acid Solutions . . . . . . . . . . . . . . . . . .22
Analytical Methods . . . . . . . . . . . . . . . . . .23
Determination of H
3
PO
4
 bySpecific Gravity . . . . . . . . . . . . . . . . . . . . . . . . . . . .23Determination of H
3
PO
4
 byMolybdovanadate Method . . . . . . . . . . . . . . . . . .25Determination of H
3
PO
4
 byThymolphthalein Titration . . . . . . . . . . . . . . . . . .26
Endnotes . . . . . . . . . . . . . . . . . . . . . . . . . .27PCS Sales and Service . . . . . . . . . . . . . . . .28

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