Emissions and Combustion
Two significant oxides of Nitrogen caused by combustion are nitricoxide (NO) and nitrogen oxide (NO
2
) commonly referred to as NO
x
inenvironmental matters pertaining air quality. They affect the environ-ment through production of acid rain and smog resulting in defoliation,direct and indirect deleterious effect on health, and reduction of the ozonelayer (greenhouse effect). The majority of NO
x
emissions are caused bycombustion of fossil fuels. Combustion of coal, oil and gas in stationarydevices such as power stations and in transportation movers such astrains and trucks generate about 40% of total world NO
x
emissions. Elec-tric generating stations are estimated to produce about 25% of this total,only part of which is due to using coal as fuel. From this, a conclusion can be drawn that emissions of N
2
O are mostly from natural sources (i.e.forest fires) and not human activity- but the latter has been increasingover the last several decades.Considering past and present environmental damage, and sug-gested future trends, governments are now recognizing the need forcontrols resulting in NO
x
reduction. In 1970 and again in 1977 the UnitedStates Congress legislation—Clean Air Act—enacted standards for newconstruction of power plants requiring the installation of pollution con-trols that result in “the lowest achievable emission rate” or “the bestavailable control technology” depending on whether the area did notmeet federal standards or where the area is meeting federal standards.Standards may differ from state-to-state, but generally “best availablecontrol technology” for new coal plants is:•selective catalytic reduction (SCR) which will achieve an emission of 15 pounds (NO
x
) per MMBtu of coal burned•scrubbers for SO
2
which will achieve emission rates of less than .3pounds per MMBtu of coal burnedRegulations in general at present do not require older coal plants tomeet these current standards. These plants could emit over .5 pounds of NO
x
per MMBtu and 6 pounds of SO
2
per MMBtu of coal burned.
Other Air Pollutants
The incomplete combustion of fossil fuel may also produce signifi-cant amounts of carbon monoxide. Again, under certain conditions,
©2002 by The Fairmont Press. All rights reserved.