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Solution Iit Jee

Solution Iit Jee

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Published by bishuu
IIT
IIT

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Published by: bishuu on Dec 14, 2010
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07/23/2013

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2
PIE EDUCATION
,
Corporate Office: 44A/2,
Sarvapriya Vihar, New Delhi - 16. Ph: 011–41828585. Fax: 011
− 
26520144
 Head Office
− 
 AXIS 117/N/581, Kakadeo Kanpur 
− 
Visit us : www.pieeducation.com
 
IIT-JEE 2010 SOLUTION
- 2
 
 
PIE IIT JEE PAPER I & II (SOLUTION 2010)
S
OLUTIONS TO
IIT–JEE
 
2010
 
(P
APER
1)
PART
1 : CHEMISTRY
SECTION
I
Straight Objective Type
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B),(C) and (D), out of which
ONLY ONE
is correct.
1.
In the reaction
HBr 
 
OCH
3
the product are(A)
BrOCH
3
and
2
H (B)
Br and
3
CHB (C)
Br and
3
CHOH (D)
OHand
3
CHB 1.
(D)
 
HBr Br 
 
OCH
3
OCH
3
H
:Br 
 
OH
3
CHB
+
 
2.
Plots showing the variation of the rate constant (k) with temperature (T) are given below.The plot that follows Arrhenius equation is(A)
T
 (B)
T
 (C)
T
 (D)
T
 2.
(A)
 From Arrhenius equation:
Ea/RT
KAe
=
, K will increase exponentially with temperature.Hence (A).
 
3
PIE EDUCATION
,
Corporate Office: 44A/2,
Sarvapriya Vihar, New Delhi - 16. Ph: 011–41828585. Fax: 011
− 
26520144
 Head Office
− 
 AXIS 117/N/581, Kakadeo Kanpur 
− 
Visit us : www.pieeducation.com
 
IIT-JEE 2010 SOLUTION
- 3
 
 
PIE IIT JEE PAPER I & II (SOLUTION 2010)
3.
The species which by definition has ZERO standard molar enthalpy of formation at 298 K is(A) Br 
2
(g) (B) Cl
2
(g)(C) H
2
O(g) (D) CH
4
(g)3.
(B)
 The standard molar enthalpy of formation of an element is zero at 298K. Br 
2
although anelement, exists in the liquid state at 298K. Hence (B)
4.
The ionization isomer of [Cr(H
2
O)
4
Cl(NO
2
)]Cl is(A) [Cr(H
2
O)
4
(O
2
 N)]Cl
2
(B) [Cr(H
2
O)
4
Cl
2
](NO
2
)(C) [Cr(H
2
O)
4
Cl(ONO)]Cl (D) [Cr(H
2
O)
4
Cl
2
(NO
2
)]H
2
O4.
(B)
 [Cr(H
2
O)
4
Cl(NO
2
)]Cl
 ⎯→
[Cr(H
2
O)
4
Cl(NO
2
)]
+
+ Cl
 – 
 [Cr(H
2
O)
4
Cl
2
]NO
2
 
 ⎯→
[Cr(H
2
O)Cl
2
]
+
+ NO
2 – 
 
5.
The correct structure of ethylenediaminetetraacetic acid (EDTA) is(A)
 NCHCHNCH
2
CH
2
CH
2
CH
2
HOOCHOOCCOOHCOOH
 (B)
 NCH
2
CH
2
 NCOOHCOOHHOOCHOOC
 (C)
 NCH
2
CH
2
 NCH
2
CH
2
CH
2
CH
2
HOOCHOOCCOOHCOOH
(D)
 NCHCH NHCH
2
HCH
2
HOOCCOOHCH
2
HOOCCH
2
COOH
5.
(C)
 EDTA is
 NCH
2
CH
2
 NCH
2
CH
2
CH
2
CH
2
HOOCHOOCCOOHCOOH
 Hence (C)
6.
The bond energy (in kcal mol
 –1
) of C – C single bond is approximately(A) 1 (B) 10(C) 100 (D) 10006.
(C)
 The bond energy of C – C single bond is
100 kcals mol
 –1
. Hence (C).Other data are absurd.
7.
The synthesis of 3-octyne is achieved by adding a bromoalkane into a mixture of sodiumamide and an alkyne. The bromoalkane and alkyne respectively are(A) BrCH
2
CH
2
CH
2
CH
2
CH
3
and CH
3
CH
2
C
CH(B) BrCH
2
CH
2
CH
3
and CH
3
CH
2
CH
2
C
CH(C) BrCH
2
CH
2
CH
2
CH
2
CH
3
and CH
3
C
CH(D) BrCH
2
CH
2
CH
2
CH
3
and CH
3
CH
2
C
CH7.
(D)
 CH
3
 –CH
2
 –C
C – H
322223
 – CHCHCHCHB NaNH32 NHNaB
CHCHCC:Na
δ+ δ
− − − −
 
 

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