ISeries,OSS I

. Code No. 56/1 q;)-g ";:i.

Roll No., im" -;T.

I, I' n

Candidates must write the Code on ' the title page of the answer-book.

" "Clframff Cf5Tg em ~. gf-Rl asl as- ~. T'O, ·~~~l "

I ,1·1

• Please check that this question paper contains 12 printed pages.

• Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate.

• Please check that this question paper contains 30 questions,

~

• Please write down the Serial Number of the question before

attempting, it.

• 15 minutes time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the student will read the question paper only and will not . write any answer .on the answer script during this period:

• '~~ Cfi"{ ~ fcn ~ :;rr;r-"Q;f if ~ 1['8" 12 % I,

• ~-"Q;f it ~ ~ ;tt :am ~ 'n!:.c€rs ~ cfit ~ 3m-grkiChI ~ :p5f-"T8" -q-{ fu"& I

• ~ ~ Cfi"{ '8 fcn ~ "5R1-"Q;f if 30 >TT-1 ~ I

• ~ ~ (fIT amk1@'1J. ~ ~ ~ ~. JJ:R qrr ~ '~ Wni

• ~ ~- -q;f cfit' ~ ~ ~ 15 fi:Rz ~ "BlFT m -rr:rr ~ I >rv-1- ~ ~ fc:RRuT ~ if 10.15 ~ M '~I 10 .. 15 ~ it 10.30 ~ d"Cb rn:f ~ "5R1-1f;f cfit ~ am: ~ ~~.~ ~ & m-~ 'R ~ 3m ~ ft1@r,

.~ ,

CHEMIS.TRY(Theory)

'< til £t~; Fcln$ll ~ (;fl. (6::1 R1 d5)

Time allowed: 3 hours

Maximum Marks: 70

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General Instructions ..

, (i) All questions are compulsory.

(ii) Marks for each. question are indicated against it.

(iii) Questions number 1 to 8 are very short-answer questions and carry 1 mark each.

(iu) Questions number 9 to 18 are short-answer questions and carry 2 marks each.

(u) Questions number 19 to 27 are also short-answer questions and carry 3 marks each.

(vi) Questions number 28 to 30 are long-answer questions and carry

5 marks each. .

(vii) Use Log Tables, if necessary. Use of calculators is not allowed.-

(iJ

(ii)

(iii)

(iv)

(v)

(vi)

(vii)

N'iit rn 31f.:rcrr4 ~ I

~ JTF{ ~ ~ 3fq; ri:wfr!: 7TTl: t I

m-7i&lT 1 it 8 aq:; 31frr ~-~ JTF{ ~' /- ~ :w.=r ~ ffrr!: 1 3fq; r I !TFf-riwH 9 it 18 rrcn (1eT-~ !TFf &' { ~ !FFT ~ ftm: 2 atcn ~' I

~ ,

J(.R'-riwH 19 it 27 rrcn '1# ~~~ !FFT ~ I ~ !f.'R it ftm: ,3 afq;',~' {

!TFf~ tfw:rr 28 it 80 c{W-~ !f.'R tf I ~ !f.'R it ff1r( 5 3iCfi~ I 31/C/$2/Cfidlj&H {#lr ~ CfiT m cit I 4C'1H2~)' it~, <it 31j1Jfrr ~. #1

1. What type of interactions hold the molecules together in a polar

.molecular solid ? 1

~ ~ ~ 3m 'if ~~ it 1ffil=R ~ ~ if ~ 'WfiR cit ql{JARCfl fullrr

~ ~? ' '

2. What is meant by 'limiting molar conductivity' ? '~ 111m 'q I C1 Cfl d I J cp:rr iffit ~ ?

1

3. Fluorine does not exhibit any positive oxidation state. Why? _~aW <itt ~ 3iT"ffiICfl.{OI ~ ~ ~ "Cfl«ft I 'cp:IT )

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2

4. Give the IUPAC name of the following compound:

HaC~ /CHa

_ H

H/ <:>

, /~

CH, Br

3

f:rq ~ q;:r ~.~-qr.~.m. (IUPAC)~ ~,~ ~ :

H3C~ ,/CHa

_' H

H/' <:> &~Br

3

1

5. Write the structure of the molecule of a compound whose' IUPAC name IS

I-pheuylpropan-z-ol 1

f:rq ~ rit 31UJ ~ ~ ~ ~.<iT.fr.~.m. (lUPAC) ~ ~ 1111

~~~ .

1 ~q, f.i t'1 ;f1 q + 2-31TI1

6. What is Tollen's reagent? Write one usefulness of this reagent. . 1

~ (Tollen) 31f~ CFlT #tm ~ ? ~ ~ rit ~ '(3Qlllfil,ctl ~

7. What is meant by 'reducing sugars"? 1

'~ ~' (reducing sugars) it cp:rr ~ \lfTctT ~ ')

8. What does the designation '6,6' mean in the name nylon-G. 6 ? 1

~-6, 6 -q '6,.6' cp:rr m ~ ~ ?

9. Define the terms, 'osmosis' and 'osmotic pressure'. What is the advantage of using osmotic pressure as compared to other colligative properties for the determination of molar masses of solutes in

solutions? ·2

'q{IB{OI' 3th: 'Q'{lfl{o\1 ~' ~ c@ 'qft~ ~ I ~ 310IB&I '1fOT~ rit ~

, ~ ~ ,~

-q Q{lf1{o\1 ~ ~ ~ q;r RH.·P-Hl -q ~ ~ ~ ~ ~b!J41'"l ~ ~ $ few:

cp:rr C1fl1 #tm~ ?

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10. Express the relation among the cell. constant, the resistance of'fhe solution in the cell and the conductivity of the solution. How is the

conductivity of a solution related to its molar conductivity ? 2

~ ~, im _if -~ Cfif~~ 31Tt ~ -.<it ill<.1Cfl·dl t ~. ~ ~~ ~

t 3it ~_ ~ I ~ ~ ~ <it ill C'i Cfldl ~ _~ ill(1Chdi it ~

cTffi ~ ?

11. Given that the standard electrode potentials (EO) of metals are:

K+ / K = ~ 2·93 V, Ag+ / Ag= 0·80 V, Cu2+ / Cu = 0·34 V,

_'

.'

Mg2+ / Mg = ~ 2·37 V, Cr3+ / Cr = ~ 0·74 V, Fe2+ /Fe .,: r: 0·44 V.

Arrange these metals in an increasing order of their reducing power. 2

OR

. Two h~lf-reactions of an electrochemical cell are given below ;

MnO~ (aq) + 8 H+ (aq) + 5 e - -4 Mn2+ (aq) + 4 H20 (l), - EO = + 1·51 V

802+ (aq) -4 8q4+ (aq) + 2 e-, EO = + 0·15 V.

Construct the redox reaction equation from the two half-reactions and calculate the cell potential from the standard potentials and predict if

the reaction is reactant or product favoured. 2

¥9 mg~ t JW!Cfi $z'1~lS fcMq. (EO) -~ ~ ~ :

K+ /K = - 2·93 V, Ag+ / Ag ::::. O·SO V, Cu2+ / Cu = 0·34 V,

Mg2+//Mg = ~ 2·37 V, Cr3+ / Cr = - 0·74 V, Fe2+/Fe = - 6,44 V.

VCfi ~-{tBI~f.lCfi itc1 Chl ~ 31tf-~ ~ ~ ll{ ~

MnO~ (aq) + 8 H+ (aq) + 5'e- -4 Mn2+ (aq) + 4 H20 (l), EO = + 1·51 V

8n2+ (aq) -4 8n4+ (aq) + 2 e", EO = + 0·15 V.

~ ?J a:r~-~~ ~ 3fftrR 'R ~ (3'lqilli~qil~) ~ q;r t1llICP~YI fu'furo: am ~ ~ it ~ ~ qRChftid ~ offim:Iffii- ~ ~ a:rf~ ~ -~ a:rercn- ~ ~_ m-rrr I

...._,,:J~'II ~e..

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12. Describe the following:

(i) Tyndall effect

(ii) Shape-selective catalysis

f.P:'i fc1 f@(1 'cnr quf--;, ~ :

(i) . ~ >MTCf

(h) 3Wjifu-C!{Ollr14Cfl ~

2

13. What is meant by coagulation of a colloidal solution ? Name any

method by which coagulation of lyophobic sols can be carried out. 2

cti1Ml~5"1 fcfwH ~. ~ it CfllT ~ ;Jffffi ~ ? 1%m ~ fcrf~ cnr ~ --~ ~ ~-fcrUm "ffic1 cnr ~ ~ ~ ~ if \ .

14. Complete the following chemical reaction equations:

(i) I2 + HN03 ~

(conc.)

(ii) HgCl2 + PH3 -+

R"."If'Mfuw 'l;IHllJRCfl ,m~ fl41Cfl{o.fi :cit "TJ ~

(i) I2 + HNDs --+

(~)

(ii) HgCl2 + PH3 --+

2

15.' Draw the structural formulae of the following compounds :

(i) H4P205

(ii) XeF 4

Rki-R1f@d ~ ~ ~ W ~

2

(i)

(ii) XeF 4

16. Give the chemical tests to distinguish between the following pairs of

compounds: 2

(i) Ethylamine and Aniline

(ii) Aniline and. Benzylamine

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F"p·..,Fc'1Rsld ~ :rm -# atcn: Cfi8. ~ _ ful:t: (lfllllf.:1Q; ~ ~ :

CD 1!j'ilMQrJ7i'i am Qf.:1M1'i -#

(ii) QF .. wil'i am ~Pis1(1Q!jl'i -#

17. Identify A and B in each of the following processes:

N aCN reduction

------+A B

2

(i)

NaN02/ Hel . C6HSNH2

C6HSNH2 A B

OH-

f'iyfc'1Rsli1 ~ >mill if A,31R B tt ~ ~:

(ii)

(i)

(ii)

B

18. Draw the molecular structures of the monomers of

2

(i) PVC

(ii) Teflon

19. The density of copper metal is 8·95 g cm-3. If the radius of copper atom be 127·8 pm, is the copper unit cell simple cubic, body-centred cubic or face-centred cubic?

(Given: atomic mass of Cu = '63·54 g marl and NA = 6·02 x 1023 mol-I) 3

W, 'EffTI q;r ~ 8·9,5 g. cm--3 ~ I ~ ~ ~ Cfit~ 127·8 pm m, "i1T w ~ ~ ~ it ~ >r$R q;y irn ~-m'ClRUT m, ~-~ m 3:r2lm ~-~"ERPI ?

(Rm7fm ~: Cu q)[ ~ t;O!1!!H = 63·54 g mol-13m NA = 6·02 x 1023 marl)

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20. What mass of NaCl (molar mass = -58·5 g mol-i) must be dissolved in 65 g of water to lower the freezing point by 7.50 C ? The freezing point depression constant, Kf, for water is 1·86 K_ kg mori. Assume

van't Boff factor for NaCI is 1·87. 3

NaCI (~ :S::ClJ1=JH = 58"5 g mol ") qij ~ lIT5IT 65 g, ~ if ,~ .;srro: f%:Rffi ~ if 7.50 C <tI flmcR: sn ;srro:? ~ ~ ftrtr: WWt ~ ~) Kf ~

1·86 K kg mol-i. ~ -~ ~ fcp NaCI -~ ftrtr: qy;c tfq:; ~ 1·87 ~ l

21. Describe the role of the following:

(i) NaCN in the _extraction of silver from a silver are

(ii) Iodine in the refining of titanium

(iii) _ Cryolite in the metallurgy of aluminium OR

3

Describe the principle involved in each of the following processes of

metallurgy: 3

(i) Froth floatation - method

(ii) Electrolytic refining of metals

(iii) Zone refining of metals Ryf~Md qij ~ CfiT CfUH ~

(i) ft:rc;:cn: ~ it ~ ~ Rtiht1UI if N~CN ctt

(ii) 21~2Rljq _~ qRtih(uj if dil~gl., ctt

(iii) ~ijfi:lRlj4 itl ~ if 9h1<A1(1,I$c cn1

a:re:rcrr

~ it RqFC'lf{9d ~_ mfill iff1r~f%d ffl:?l.fii" CfiT quf-;,' ~

(i) -ifr1 ~ fcrf'El

(ii) m-gaff CfiT ~-31q'6l2;:ft qRti!l(UI

(iii) mgalf' ~ ~ q Rtih(u I

- 22. Explain the follo:wing cases giving appropriate reasons :

(i) Nickel does not form low spin octahedral complexes.

(ii) The IT-complexes are known for the transition metals only ..

(iii) Co'2+ is easily oxidised to C03+ in the presence of a strong ligand.

.3

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~ CfiRUl ~ ~ f.i kir~R9d q:;:r O!U@TI ~ :

(i) ~ ~-%'fiUT- 31@lfiMChlll ~ ~ GFlTffi ~

(ii) n-ChTu:8Cf8 ~ ~ "ffii:lT t ~ ~ % I

(iii) 5filR1 ~ q:;:r '3Qfftffu ~. C02+ ~ it C03+ if 3114<81$(1 it \lIl"ffi ~

23. How would you differentiate between SN1 - and SN2 mechanisms of substitution reactions? Give one example of each.

3

~ ~3TI q:;:r SN1 afR SN2 Rhlj-IFqr~ t Gftq :mq til' attn: ~ ? ~ WilR CfiT ~- t!,Cfl 3eJ Q {Ol cftfm!: I

24. How would you convert the following :

(i) Phenol to benzoquinone

(ii) Propanone to 2-methylpropan-2-01

(iii) Propene to propan-z-ol -

f.,kiF«If{9.d CfiT ~ ~ ~ :

(i) ~ q)T ~<=:&i1~<il<i if

(ii). ~ CfiT 2_itfiH.1siiQ+2-3lfc;:r ~ (iii) mifR CfiT mt.:r-2-3lT\.1" if.

3

25. How would you account for the following :

(i) NC1S is an endothermic compound while NFg is an exothermic one.

3

(ii) XeF 2 is a linear molecule without a bend.

(iii) The electron gain enthalpy with negative sign for - fluorine is less than that for chlorine, still fluorine is a stronger oxidising agent than chlorine.

F'"lkifMf{9d _q;l ~ ~ ~ :mq tit {11if?ll~~ ;

0) Nels 1!:Ch 3;a!l~j)i5fJ ~ ~ ~ NFs ~ ~

(ii) XeF 2 ¥.T g3TI -;r ~ t!,Cfl mm ~ 3lTChf{ CITC1T 31UJ t

(iii) 1:RjamR t fc;m:~c1,*?I"i m q:;:r ;fi0u,l:!Cfi ~ ~ ~ <tt ~ CflB ~)ftM ~ tRjamR ~ <tt ~ afftrCfi 5filR1 31T'f8l<fil(Efi _~ I

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26. Amino acids maybe acidic, alkaline or neutral. How does this happen? What are essential and non-essential amino acids? Name one

of each type. ' 3

~ ~ ~ ~, ~ 312fCn ~ ~ ~ I ~ fctitl >mlT\ mm ~ '.?

- dllCl ~ tlCfl am: 3FlI q ~ ~ Cfl ~ ~ cp::rr mit ~ ? ~ - >mlT\ "CflT" ~- ~ ;m:r

~I

27. Explain the following terms with one example in each case: 3

(i) Food preservatives

(ii) - Enzymes

(iii) Detergents

~ w.m=r if 1l:Cfl-~3G(Q{O I ~ RkJFC"1fuJd .~ tt "a:rr&IT ~ :

(i) ~~

(H) (iii)

Explain the following terms:

(i) Rate of a reaction

(ii) Activation energy of a reaction

The decomposition of phosphine, _ PH3, proceeds according to the following equation:

4 PH3 (g) --+ P4_ (g) + 6 H2 (g) ,

It is found that the reaction follows the following rate ~quation :

Rate = k [PH).

The half-life of PH3 is 37·9 s at 1200 C.

(i) H~w much time is required for 3/4thof PH3 to decompose ?

(ii) What fraction of the original sample of PH3 remains behind

after 1 minute? 5

OR

(a) Explain the following terms:

(1) Order of a reaction

28. (a)

(b)

(ii) Molecularity of a reaction

(b) The rate- of a reaction increases four times when the temperature changes from 300 K to 320 K. Calculate the energy of activation ofihe . reaction, assuming that it does not change with

temperature. (R = 8·314 J K-I moCI) 5

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(a) f.:tYr~r~('1 ~ cit ~ ~ :

(i) 3TI~ ct'r G\

(ii) 3TI~ ct'r l;1Rt;;qol "i;sTI

(b) q;IWI<i, PH3, q}f ~ f.:tyrC'lR9('1 H~ICfl{OI ~ ~ ~ ~ :

4 PH3 (g) ---'t P 4 (g) + 6 H2 (g)

~ 1WIT ~ ~ fcfi ~ f.:tYr~fuJ.(4 ?J H41Cfl{o.1 ~ ~ ~. ~ :

.cr.: = k [PH3].

1200 C lR PH3 ct'r ;wJ-3il1 37·9 s ~ I

(i) - PH3 ~ 3/4 'BPI t 31ql':JF2:('1 if.t ~ ~ fcflcfo:IT ~ ~ ?

(ii) 1 11Rz it ~ PH3 it +wf ~ cnr ~ ~ -ir:T ~ ~ ?

....... . C'>..

3lWU

(a) f.ri::l ~ cit ~ ~ :

(0 ~ .. an~.<tr c€tf2" .

(ii) ~ ~ <tT3ilfUEjCfl('11

(0) ~ 300 K ~ ~ 320 K ~ ~ 1:R ~ ~ Cf>T ~ "qT{ :fIT m ~ ~ I ~ Cf>T Hr~;qol mT cnr qRq;{i1<i ~, ~ ~ SQ: fcp (1fq11R ~ ~ m2I ~ 11R qRqR4d ~ ~ ~. I (R = 8·314J K-I mol-I)

29. (a) . Complet~ the following chemical eq~ation~-:

(i) Cr20~- (aq) + H2S (g) + H+ (aq) -7

(ii) Cu2+(aq) + I" (aq) -7

(b) How would you account for the following:

(i) . The oxidising power of oxoamons are In the order . VO; < Cr20~'- < MnO:.

(ii) The third ionization enthalpy of manganese (Z = 25) 1.8 exceptionally high.

(iii) Cr2+ is a stronger reducing .agent than Fe2+. 5

OR

(a) Complete the following chemical equations:

(i) MnO~ (aq) + S20~- (aq) + H20 (l) -7 '

(ii) Cr20;- (aq) + Fe2+ (aq) + H+ (aq) -7

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(b) Explain the following observations .:

(i) La3+ (Z ;:;:: 57) and Lu3+(Z ;:;:: 71) do not show any colour in solutions.

(ii) Among the divalent cations in the first series of transition

elements, manganese exhibits the maximum

paramagnetism.

(iii) Cu+ ion is not known in aqueous solutions.

5

(a) F·::p::rtFc1M(l {IBlllRCh ll~lCh{Un cit ~ ~ :

(i) CrzO;- (aq) + H2S (g) + H+ (aq) ---+

(ii) Cu2+ (aq) + r (aq) ---+

(b) F"il""1FtiM(l cit i'.fi"RUT fc1@Cfj{ ~ .~. :

(i) 3ilCR"i~;ao II "-'!.-i'i qiT 3lTCR"1lCh{U I 8;11TIIT Vo; < CrzO;- < MnO~ ~ iB if ~ ~ t

(ii) ~. (2 "". 25) qiT ~ ~ q:4lMI ~~a;Rr: ~ mID ~

(iii) Cr2+ ~ Fe2+ it 31fmn "5foif0 3lqT.lI"-'!Ch ~ ·1 .

3t~

(a) RklfAPSl('1 {IBlllf-iCfl B41Ch{Un en) lU ~ :

(i) MnO~ (aq) + S20~- (aq) + H20 (l) --+

(ii) Cr20~- (aq) + Fe.2+ (aq) + H+ (aq) ---+

(b) Ryfc1Md d"jClff1Cfl ... il qiT ~ ~ :

(i) La 3+ (Z= 57) am L u3+ (Z = 71) fCl ('ill '·11' if ~ trT -;ffiT f~@ M 18

(ii) >P-11i 4tuft $ ~ ~ $ f~4~~JjCh ~ if ~ -wmmn 3i 11k! Cfl(q ~ Cfi""{(1l ~I

(iii) ~ fCl('ilj .. ii· if Cu" ,'3w:R q;r ~ ~ 'Jl"RT.~ i

30. {a) Illustrate the following name reactions giving a chemical eq~ation in each case :

(i) Clemmensen reaction

(ii) Cannizzaro's reaction

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(b) Describe how the following conversions can be brought about:

(i). Cyclohexanol to eyclohexan-Lone

(ii) Ethylbenzene to benzoic acid

(iii) . Bromobenzene to benzoic acid .

5

OR

(a) Illustrate the following name reactions :

(i) Hell ~ Volhard ~ Zelinsky' reaction

(ii) W olff - Kishner reduction reaction

(b) How are the following conversions carried out ,:

(i) Ethylcyanide to ethanoie acid

(ii) Butan-Lol to butanoic acid

(Ill) Methylbenzene to benzoic acid

Write chemical equations for the involved reactions. 5

(a) A ~'-If"&l Rg (1 -;::yp:f cn--ffi an~3lf <it >rfflq; ~ ft;rQ: {I € III A CfI € ~l CfI{O I ~ ~:

CD cR'fl~'i1'i ~

(ii) .:tRiS11 ~ q;r a:rf~

(b) quf;r ~ fcr; AYr~f@("1 ¥Qi("1{ol --%it ~. ~ ~ :

CD BI~<"R11~c.Ht'i1M CfiT fll~'R1)8ct=B+ I-aiR it

(ii) "QjiiM~<:Jil<1 CfiT ~<=MI~CfI ~- if

(iii) ffijl~I~;;:411<1 CfiT ~;::;J1l~CfI 31R?f-if

3l~-

(a) AyfdM("1 -;n-q) q;r ~3if qj) 3<1~{UI t trm ~ :

(i) ~ ~ ~ - JiR1f:h1 ~

(ii) ~~~~~

(b) f.:p::;f¥qid{UI ~_ ~_ 'Jff ~ % :

(i) ~Qifllll<1I~S CfiT t?:~.n~(fl ~ if

(ii) ~ -1-a1'fc1 CfiT ~ 2 ·11 ~ q; ~ it

'" '"

(iii) itf~(1~~l,<1, CfiT ~~l~Cb ~ if

flF"1ffi("1 31f~an ~ fc;n:; -{lflll1ACfi Hl=!lCfi{OI fc1furQ:

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