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[1]
IIT JEE-2010 Paper-2 (Chemistry)Useful data
Atomic Numbers: B = 5; C = 6; N = 7; O = 8; F = 9 ; Na = 11; Si = 14; P =15; S = 16; Cl = 17;Ti = 22; V = 23; Cr = 24; Ni = 28; Cu = 29; Br = 35; Rh = 45; Sn = 50;Xe = 54; Tl = 811 amu=1.66
× 10
 – 
27
kge=1.6
× 10
 – 
19
CR=0.082 L-atm K
 – 
1
mol
 – 
1
c=3.0
× 10
8
m s
 – 
1
h=6.626
× 10
 – 
34
J sF=96500 C mol
 – 
1
N
A
=6.022
× 10
23
R
H
=2.18
× 10
 – 
18
Jm
e
=9.1
× 10
 – 
31
kg4

0
=1.11
× 10
 – 
10
J
 – 
1
C
2
m
 – 
1
PART-ISECTION-I
Single Correct Choice Type
This section contains
6 multiple choice questions
. Each question has 4 choices (A), (B), (C) and (D),out of which
ONLY ONE
is correct.Q.1The packing efficiency of the two-dimensional square unit cell shown below is
 L
(A) 39.27 %(B) 68.02 %(C) 74.05 %(D) 78.54 %
Ans.[D]
Q.2Assuming that Hund
’
s rule is violated, the bond order and magnetic nature of the diatomic molecule B
2
is(A) 1 and diamagnetic(B) 0 and diamagnetic(C) 1 and paramagnetic(D) 0 and paramagnetic
Ans.[A]
 
[2]
Q.3The compounds P, Q and S
HOCOOH
P
H C
3
OCH
3
QS
CO
were separately subjected to nitration using HNO
3
/ H
2
SO
4
mixture. The major product formed in eachcase respectively, is(A)
HO H C
3
COONO
2
NO
2
COOH OCH
3
O
2
N
(B)
HO H C
3
COONO
2
NO
2
NO
2
COOH OCH
3
(C)
HOH C
3
COONO
2
NO
2
NO
2
COOHOCH
3
(D)
HOH C
3
COONO
2
NO
2
NO
2
COOHOCH
3
Ans.[C]
 
[3]
Q.4In the reaction
C
C
O
O
NH
2
Cl
H C
3
(1) NaOH/Br
2
(2)
 
T
the structure of the Product T is(A)
COOO
 – 
C
H C
3
(B)
NHOCCH
3
(C)
NHOCH C
3
(D)
COONH
 – 
C
H C
3
Ans.[C]
Q.5The complex showing a spin-only magnetic moment of 2.82 B.M.is(A) Ni(CO)
4
(B) [NiCl
4
]
2
 – 
(C) Ni(PPh
3
)
4
(D) [Ni(CN)
4
]
2
 – 
Ans.[B]
Q.6The species having pyramidal shape is(A) SO
3
(B) BrF
3
(C) SiO
32
 – 
(D) OSF
2
Ans.[D]
SECTION-II
(Integer Type)
This Section contains a group of 
5 questions
. The answer to each questions is a
single digit integer
ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.Q.7One mole of an ideal gas is taken from
a
to
b
along two paths denoted by the solid and the dashed linesas shown in the graph below. If the work done along the solid line path is w
s
and that along the dotted linepath is w
d
, then the integer closet to the ratio w
d
/ w
s
is
0.00.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.00.51.01.52.02.53.03.54.04.5
PV(atm)(lit.)
ab
Ans.[2]
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