Extruded activated carbon (EAC)
Extruded activated carbon combines powdered activated carbon with a binder, which are fused together and extrudedinto a cylindrical shaped activated carbon block with diameters from 0.8 to 130 mm. These are mainly used for gasphase applications because of their low pressure drop, high mechanical strength and low dust content.
Porous carbons containing several types of inorganic impregnant such as iodine, silver, cations such as Al, Mn, Zn,Fe, Li, Ca have also been prepared for specific application in air pollution control especially in museums andgalleries. Due to antimicrobial/antiseptic properties, silver loaded activated carbon is used as an adsorbent forpurification of domestic water. Drinking water can be obtained from natural water by treating the natural water witha mixture of activated carbon and Al(OH)
, a flocculating agent. Impregnated carbons are also used for theadsorption of H
S and thiols. Adsorption rates for H
S as high as 50% by weight have been reported.
Polymer coated carbon
This is a process by which a porous carbon can be coated with a biocompatible polymer to give a smooth andpermeable coat without blocking the pores. The resulting carbon is useful for hemoperfusion. Hemoperfusion is atreatment technique in which large volumes of the patient's blood are passed over an adsorbent substance in order toremove toxic substances from the blood.
Activated carbon is also available in special forms such as cloths and fibres. The "carbon cloth" for instance is usedin personnel protection for the military.
A gram of activated carbon can have a surface area in excess of 500 m
, with 1500 m
being readily achievable.
Carbon aerogels, while more expensive, have even higher surface areas, and are used in special applications.
Activated carbon, as viewed by an electron microscope
Under an electron microscope, the high surface-areastructures of activated carbon are revealed. Individualparticles are intensely convoluted and display variouskinds of porosity; there may be many areas where flatsurfaces of graphite-like material run parallel to eachother, separated by only a few nanometers or so. Thesemicropores provide superb conditions for adsorption tooccur, since adsorbing material can interact with manysurfaces simultaneously. Tests of adsorption behaviourare usually done with nitrogen gas at 77 K under highvacuum, but in everyday terms activated carbon isperfectly capable of producing the equivalent, byadsorption from its environment, liquid water fromsteam at 100 °C and a pressure of 1/10,000 of anatmosphere.James Dewar, the scientist after whom the Dewar (vacuum flask) is named, spent much time studying activatedcarbon and published a paper regarding its absorption capacity with regard to gases.
In this paper, he discoveredthat cooling the carbon to liquid nitrogen temperatures allowed it to absorb significant quantities of numerous airgases, among others, that could then be recollected by simply allowing the carbon to warm again and that coconut