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r050210802 Organic Chemistry

r050210802 Organic Chemistry

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Code No: R050210802
Set No. 1
II B.Tech I Semester Regular Examinations, November 2007
ORGANIC CHEMISTRY
(Chemical Engineering)
Time: 3 hours
Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
\u22c6 \u22c6 \u22c6 \u22c6 \u22c6
1. (a) Discuss the concept of resonance with examples.
(b) Distinguish between mesomeric and inductive e\ufb00ects.
[8+8]
2. (a) Discuss the mechanism of reaction involving benzene and acyl chlorides in the
presence ofAlCl3.
(b) Explain, how phenol can be converted into Salicyaldehyde and write the mech-
anism involved in it?
[8+8]
3. Write the steps involved in the following conversions.
(a) 2CH3COCH3OH\u2296
\u2212\u2212 \u2212\u2192Product
(b)CH3 COCH3 +CH3CHOOH\u2296
\u2212\u2212 \u2212\u2192Product
[8+8]
4. (a) Describe the acid catalyzed addition of water to propylene.
(b) Discuss the reaction between ethane gas and chlorine in the presence of UV
light.
[8+8]
5. Write a note on conformational analysis of cyclohexane.
[16]
6. (a) Describe the preparation of natural rubber from latex.
(b) What are bakelite resins and how are they made.
[8+8]
7. (a) What happens when pyrrole is heated with bromine?
(b) How is quinoline obtained by Skraup?s synthesis?
[8+8]
8. Outline the synthesis of the following:

(a) Malachite Green
(b) para-rosaniline
(c) Magenta red.

[6+5+5]
\u22c6 \u22c6 \u22c6 \u22c6 \u22c6
1 of 1
Code No: R050210802
Set No. 2
II B.Tech I Semester Regular Examinations, November 2007
ORGANIC CHEMISTRY
(Chemical Engineering)
Time: 3 hours
Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
\u22c6 \u22c6 \u22c6 \u22c6 \u22c6
1. (a) Using inductive e\ufb00ect, explain why chloro acetic acid stronger then acetic acid.
(b) Explain why aniline is less basic in comparison with methyl amine.
[8+8]
2. Write the mechanism for the following \ufb01gure 2 & \ufb01gure 2
[16]
Figure 2
Figure 2
3. Write the reaction mechanism of the following conversions.
(a) p - methoxy BenzaldehydeEtOH/KCN/
\u2212\u2212\u2212\u2212\u2212\u2212\u2212\u2192
H eat
Anisoin
(b)BenzaldehydeAcetic anhydride
\u2212\u2212\u2212\u2212\u2212\u2212\u2212\u2212\u2212\u2192
Sodiumacetate
C innamic acid
[8+8]

4. (a) What is a free-radical?
(b) How do you get bromine free radicals?
(c) Describe the free-radical mediated addition of HBr to alkenes.

[4+8+4]
5. Write short note on optical isomerism and explain it with reference to tartaric acid.
How does it give two optically active forms?
[16]
6. (a) What is natural wool? How is it obtained?
(b) Explain the di\ufb00erence between natural and arti\ufb01cial silk. How are they dis-
tinguished?
[8+8]
1 of 2
Code No: R050210802
Set No. 2
7. (a) Give any two methods for the preparation of the following:
i. Pyrole
ii. Pyridine.
(b) How will you explain the grater basicity of pyridine as compared to that of
pyrrole?
[4+4+8]
8. (a) What are dyes?
(b) Explain the classi\ufb01cation of dyes based on their chemical structure. [6+10]
\u22c6 \u22c6 \u22c6 \u22c6 \u22c6
2 of 2

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