Electrochemistry in Historical and Archaeological Conservation
Workshop January 11 -15 2010, Leiden, The Netherlands
EIS measurements for theperformance evaluation of organo-silane in the protection of outdoormonumental bronzes
P. Letardi
CNR - ISMAR, Genoa, Italy
E.Joseph, S.Prati, R.Mazzeo
University of Bologna, M2ADL Laboratory, Ravenna,Italy
Eu
-
ARTECH
Access, Research and Technology for theconservation of the European Cultural Heritage
EC Integrated Infrastructure initiatives 6
th
Framework Program
–
Structuring the European Research Area
Electrochemistry in Historical and Archaeological Conservation
Workshop January 11 -15 2010, Leiden, The Netherlands
Eu
-
ARTECH
Access, Research and Technology for theconservation of the European Cultural Heritage
EC Integrated Infrastructure initiatives 6
th
Framework Program
–
Structuring the European Research Area
JOINT RESEARCH ACTIVITY 1Development and evaluation of new treatments for the conservation-restoration of outdoor bronze monuments
Task 1:
IDENTIFICATION, SELECTION ANDCHARACTERIZATION OF BRONZE SAMPLESFOR TESTING
Task 2:
LABORATORY STUDIES ON NEWTREATMENTS
Task 3:
AGEING PROCEDURES ANDCHARACTERISTICS OF SAMPLES PROPERLYAGED BEFORE TREATMENTS
Task 4:
TREATED SAMPLES, EXPOSURESITES AND AGEING PROCEDURES
Task 5:
PERFORMANCE OF THETREATMENTS DURING NATURAL ANDARTIFICIAL AGEING PROCEDURES
Task 6:
IN SITU TESTS OF TREATMENTS ONOLD ARTIFACTS (DEMO ACTIVITY)
Eddy current thicknessmeasurementsColour measurements
EIS measurements
FTIR microspectroscopyX-ray diffraction
Electrochemistry in Historical and Archaeological Conservation
Workshop January 11 -15 2010, Leiden, The Netherlands
TYPOLOGIES OF TREATMENTS SELECTED
treatment
name
Type of functionalgroup
R
f
T1 dynasylanF8263- (CF
2
)
5
CF
3
T2 SIVO clear
®
(?)T3 protectosil SC
®
(?)T4 dynasylan
BSM40
-CH(CH
3
)OCH
3
Acrylic lacquers (Incralac), various waxes (wax R21, TeCe Wachs 3534F) and organiccorrosion inhibitors (benzotriazole) are the most frequently used treatments for outdoor bronze protection. In order to response to the pressing need voiced by art conservators, thisproject aimed at evaluating new approaches based on alternative materials for the protectionof outdoor bronze monuments as well as new inhibition treatments for active corrosion.Different typologies of treatments were selected:1. New generation of silanes, which arecommonly applied to protect stonemonument, were chosen for their abilityto produce, after hydrolysis, chemicalbonds with copper hydroxysulphates or hydroxychlorides.
2.
formation of artificial copper oxalate patinas
3.
formation of artificial copper oxalate by fungi
4.
formation of a thicker cuprite layer
5.
limewater as corrosion inhibitor
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Letardi, P. Et Al. Evaluation Organo-silane Protection Bronzes Outdoor. 2010
Letardi, P. Et Al. Evaluation Organo-silane Protection Bronzes Outdoor. 2010
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