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senyawa-fenilpropana

senyawa-fenilpropana

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Published by Fino Yoharde

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categoriesTypes, School Work
Published by: Fino Yoharde on Mar 28, 2011
Copyright:Attribution Non-commercial

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07/01/2013

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FENIL PROPANOIDFENIL PROPANOID
‡ Transformasi L-fenilalanina dan L-tirosin dalamtumbuhan dapat berlangsung sbb.‡ Kedua asam amino ini seimbang dengan asamfenilpiruvat / asam p-hidroksi fenilpiruvat‡ Fenilalanina terlibat transformasi menjadi transasam sinamat, tirosin terlibat proses lain‡ Rantai samping gugus karboksilat terlepas,
F
±
feniletilamina dan
F
±
fenilasetaldehida, biasadisertai dengan gugus hidroksil pada aromatis‡ Metabolit fenilalanina (dan tirosin) denganasam amino tetap utuh dikenalFenilpropanoid
 
‡ Merupakan senyawa Fenol umum padatumbuhan tinggi‡ Dibiosintesis lewat jalur shikimat‡ Ciri satu cincin benzena tersubtitusi denganrantai karbon propil‡ Pola oksidasi teratur, maksimum sebagaitrihidroksi, bisa 3,4-dihidroksi, 4-hidroksiatau sama sekali tidak
CCC
 
COOHOCOOHNH
2
PALatauTAL
COOHRNH
2
(
O
)
CHO
(
O
)(
O
)(
O
)
ASAM SHIKIMATASAM FENILPIRUVAT
F
-
FENILETILAMINA
F
-
FENILASETALDEHIDAASAM
trans
SINAMAT
R
(2)
FENILPROPANOIDALKALOIDAR = H = L
-
FENILALANINAR = OH = L
-
TIROSINA
JALUR METABOLIT L
-
FENILALANINA DAN L
-
TIROSINA DALAM TUMBUHAN

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