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07a1bs08-physical-chemistry

07a1bs08-physical-chemistry

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Published by: SRINIVASA RAO GANTA on Aug 28, 2008
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Code No: 07A1BS08
Set No. 1
I B.Tech Regular Examinations, May/Jun 2008
PHYSICAL CHEMISTRY
(Chemical Engineering)
Time: 3 hours
Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
\u22c6 \u22c6 \u22c6 \u22c6 \u22c6
1. State Nernst distribution law. Derive the expression and state its limitations. [16]
2. Draw the phase diagram of a two component system. Explain the behaviour and
special feature of such systems.
[16]
3. What is the experimental basis for the existence of activated complex ? How will
you determine energy of activation.
[16]
4. (a) Explain in detail the coagulating e\ufb00ect of electrolytes.
(b) Explain in detail the sedimentation potential of electrolytes.
[8+8]
5. (a) Classify the Electrolytes
(b) Explain Electrolysis process.
[8+8]
6. Describe a method for measuring e.m.f\u2019s of a Galvanic cell. How can this method
be used for measuring potentials of single electrodes?
[16]
7. Discuss and explain the mechanism and kinetics of enzyme catalyzed reactions.
[16]
8. Explain with neat diagram of voltammograms and their industrial applications.
[16]
\u22c6 \u22c6 \u22c6 \u22c6 \u22c6
1 of 1
Code No: 07A1BS08
Set No. 2
I B.Tech Regular Examinations, May/Jun 2008
PHYSICAL CHEMISTRY
(Chemical Engineering)
Time: 3 hours
Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
\u22c6 \u22c6 \u22c6 \u22c6 \u22c6

1. Explain how with the help of distribution law you can show whether it is more economical to extract with all the solvent available in one operation or to use it in several portions separating each time.

[16]
2. (a) With the help of Clapeyron-Clausius equation explain the e\ufb00ect of pressure
on the melting point of sulphur.
(b) Discuss the application of eutectics.
[8+8]
3. Distingush between
(a) Collision theory and Transition state theory.
(b) Molecularity and order of reaction.
[8+8]
4. (a) Explain the preparation of lyophilic sols.
(b) Explain the preparation of lyophobic sols.
[8+8]
5. Answer each in about 5 lines (give reasons)
(a) In the electrolysis of Aq.KOH, H2 gas is evolved at cathode and K is not
deposited
(b) In the determination of conductance of KCl, A.C is used in place of D.C
(c) Conductance of a solution of an Electrolyte increases, if the Electrical \ufb01eld
strength is increased from 25 vcm\u22121 to 106 vcm\u22121.
[5+5+6]
6. Discuss in detail about the fuel cell with neat diagram.
[16]
7. (a) Describe the di\ufb00erent type of catalysis
(b) Write short notes on Enzyme catalysis.
[8+8]
8. Discuss the advantages and disadvantages of the dropping mercury electrode com-
pared with platinum or carbon micro electrodes.
[16]
\u22c6 \u22c6 \u22c6 \u22c6 \u22c6
1 of 1
Code No: 07A1BS08
Set No. 3
I B.Tech Regular Examinations, May/Jun 2008
PHYSICAL CHEMISTRY
(Chemical Engineering)
Time: 3 hours
Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
\u22c6 \u22c6 \u22c6 \u22c6 \u22c6
1. How is the equilibrium constant determined from distribution coe\ufb03cient.
[16]
2. (a) State the phase rule and discuss the derivation of the phase rule.
(b) Apply phase rule to a one component system having more than one triple
point.
[8+8]
3. Explain the in\ufb02uence of solvent on reaction rates.
[16]
4. (a) Explain in detail the mechanism of electro-osmosis with a neat sketch.
(b) Colligative properties of colloids.
[8+8]
5. (a) Describe the measurement of Transport numbers by Hittrof\u2019s method.
(b) by moving Boundary method.
[8+8]
6. (a) Describe the process of measurement of e.m.f. by potentiometer with neat
diagram.

(b) For the cell reaction Zn+ + Fe+2\u2194 Zn2+ + Fe, Calculate the relative concen- tration of Zn2+ + and Fe+2 at which the overall cell e.m.f. becomes zero. E0 Fe2+, Fe = -0.0440V and E0 Zn2+, Zn = -0.760V.

[8+8]
7. (a) Discuss the types of reactions in catalytic reactor.
(b) List out the representative catalysts.
[8+8]
8. Explain the following :
(a) Linear scan polarography
(b) Pulse polarography.
[8+8]
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1 of 1

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