Triumph Academy [1] IIT–JEE-11 / Paper I

CHEMISTRY
Part I
Section–I
Straight Objective Type
This section contains 7 multiple choice questions numbered 1 to 7. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

1. Geometrical shapes of the complexes formed by the reaction of Ni2 with Cl  , CN  and H 2 O,
respectively, are
(A) octahedral, tetrahedral and square (B) tetrahedral, sqaure planar and octahedral
(C) square planar, tetrahedral and octahedral (D) octahedral, square planar and octahedral

Ans. (B)
2
Sol. NiCl 4  Tetrahedral

b g
Ni CN 4
2
 Square planar

Nib H Og
2
2 6
 Octahedral

2. AgNO3 (aq.) was added to an aqueous KCI solution gradually and the conductivity of the solution was
measured. the plot of conductance (  ) versus the volume of AgNO3 is

(A) (P) (B) (Q) (C) (R) (D) (S)

Ans. (D)
Triumph Academy [2] IIT–JEE-11 / Paper I

CHEMISTRY
3. Bombardment of aluminum by   particle leads to its artificial disintegration in two ways, (i) and (ii) as
shwon. Products X, Y and Z respectively are

(A) proton, neutron, positron (B) neutron, positron, proton

(C) proton, positron, neutron (D) positron, proton, neutron
Ans. (A)

Sol.
4
2 He  27
13 Al 
 30
15 P 0 n1
b Y g  neutron

4
2 He  27
13 Al 
 30
15 Si  1 P1
b X g proton
4
He  27
Al 
 30
Si  e 
2 13 14
b positron g

4. Extra pure N2 can be obtained by heating

(A) NH3 with CuO (B) NH4NO3
(C) (NH4)2Cr2O7 (D) Ba(N3)2

Ans. (D)

Sol. b g
Ba N 3 2


 Ba  3N 2

5. Among the following compounds, the most acidic is

(A) p-nitrophenol (B) p-hydroxybenzoic acid
(C) o-hydroxybenzoic aicd (D) p-toluic acid
Ans. (C)
Triumph Academy [3] IIT–JEE-11 / Paper I

CHEMISTRY
O–H
OH O
COOH C
Sol. because its carboxylate ion is stabilised due to intramolecular hydrogen bonding O

and due to ortho effect.

6. The major product of the following reaction is

(A) (B)

(C) (D)

Ans. (A)
O O
C
(i) KOH
Sol. NH
(ii) Br CH2 Cl
N – CH2 Br
C
O O

7. Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solutino of density 1.15 g/mL. The
momlarity of the solution is
(A) 1.78 M (B) 2.00 M (C) 2.05 M (D) 2.22 M
Triumph Academy [4] IIT–JEE-11 / Paper I

CHEMISTRY
Ans. (C)

Sol. Total mass of the solution = 1000 + 120 = 1120 g

1120
V  0.973 L
115
.
120
n urea   2 mol
60
2
M  2.05 M
0.973
Section–II
Multiple Correct Answer Type
This section contains 5 multiple choice questions numbered 8 to 14. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE THAN ONE is / are correct.

8. Extraction of metal from the ore casiterite involves

(A) carbon reduction of an oxide ore (B) self-reduction of a sulphide ore
(C) removal of copper (D) removal of iron impurity
Ans. (A, D)
Sol. Cassiterite contains impurity of FeWO4
bSnO g2

SnO 2  2C 
 Sn  2CO

9. Amongst the given options, the compound(s) in which all the atoms are in one plane in all the possible
conformations (if any), is (are)

(A) (B) (C) H 2 C  C  O (D) H 2 C  C  CH 2

Ans. (B, C)

10. The correct statement (s) pertaining to the adsorption of a gas on a solid surface is (are)
(A) Adsorption is always exothermic
(B) Physisorption may transform into chemisorption at high
(C) Physisorption increases with increasing temperature but chemisorption decreases with increasing
temperature
(D) Chemisorption is more exothermic than physisorption, however it is very slow due to higher energy of
activation.
Triumph Academy [5] IIT–JEE-11 / Paper I

CHEMISTRY

Ans. (A, B, D)

11. According to kinetic theory of gases

(A) collision are always elastic
(B) heavier molecules transfer more momentum to the wall of the container
(C) only a small number of molecules have very high velocity
(D) between collision, the mmolecules mvoe in straight lines with constnat velocities.

Ans. (A, B, C, D)

Section–III
Paragraph Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be answered.
Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Question Nos. 12 to 14

When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution
turns light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous
NH3 dissolves O and gives an intesne blue solution.
12. The metal rod M is
(A) Fe (B) Cu (C) Ni (D) CO

Ans. (B)

13. The compound N is

(A) AgNO3 (B) Zn(NO3)2 (C) Al(NO3)3 (D) Pb(NO3)2

Ans. (A)

14. The final solution contains

b g
(A) Pb NH 3 4
2
and CoCl 4
2
b g
(B) Al NH 3 4
3
b g
and Cu NH 3 4
2

Agb NH g b g Agb NH g Nib NH g

 2  2
(C) 3 2 and Cu NH 3 4
(D) 3 2 and 3 6

Ans. (C)
Triumph Academy [6] IIT–JEE-11 / Paper I

CHEMISTRY
Sol. 2 AgNO 3  Cu 
N M
b g
 Cu NO 3 2  2 Ag
Light blue

AgNO3  NaCl 
 AgCl  NaNO3
White ppt
O

Cu 2   4 NH 3  b g
 Cu NH 3 4
2

 AgbNH g

AgCl  2 NH 3  3 2 Cl 

Paragraph for Question Nos. 15 to 16

An acyclic hydrocrbon P, having molecular formula C6H10 gave acetone as the only organic product through the
following sequence of reactions, in which Q is an intermediate organo compoud.

15 The structure of compound P is

(A) CH 3CH 2 CH 2  C  C  H (B) H 3CH 2 C  C  C  C  CH 2 CH 3

(C) (D)

16. The structure of the compound Q is

(A) S (B)

(C) (D)

Ans. (D, B)
Triumph Academy [7] IIT–JEE-11 / Paper I

CHEMISTRY
CH 3 CH 3
(1) H2 SO4|HgSO4
CH 3 C–C CH CH 3– C – C – CH 3
Sol.
CH 3 (D) CH 3 O

CH 3 CH 3
| |

NaBH
 4 / C 2 H 5OH
 CH 3  C  CH  CH 3 
H
 CH 3  C  CH  CH 3 

dil . acid
| | | |
CH 3 OH CH 3 OH 2


CH3 CH3 CH3 CH3

| | | |
(i) O
CH 3  C  CH  CH3 
 CH 3  C  CH  CH 3 
 CH3  C  C  CH 3  3  CH 3COCH 3
a ii f Zu/ H O
2
|   |
CH3 CH 3

Section – IV
Integer Answer Type
This section contains 8 questions. The answer to each of the questions is a single-digit integer, ranging from
0 to 9. The appropriate bubbles below the respective question numbers in the SORS have to be darkened.

17. Reaction of Br2 with Na 2 CO 3 in aqueous solution gives sodium bromide and sodium bromate with evolution
of CO2 gas. The number of sodium bromide molecules involved in the balanced chemical euqation is
Ans. (5)

Sol. 3Br2  3CO23  

 5Br   BrO3  3CO2

18. The difference in the oxidation numbers of the two types of sulphur atoms in Na 2S 4 O 6 is

Ans. (5 )

O O
+–  
Sol. NaO – S – S – S – S – O Na
+5 0 0 +5
O O
Triumph Academy [8] IIT–JEE-11 / Paper I

CHEMISTRY
19. The maximum number of electrons that can have principal quantum number, n = 3, and spin quantum
1
number, ms   , is
2

Ans. (9)

Sol. Number of orbital for n = 3 is = n2 = 9

1
Number of electron n = 3 and ms   =9
2

20. A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and phenylanine.
Glycine contributes 47.0% to the total weight of the hydrolysed prdoucts. The number of glycine units
present in the decapeptide is

Ans. (6)
Sol. Let number of glycine units = n
mass of decapeptide = 796
mass of H2O needed = 162 g
Total mass = 958 g
47
958   75  n
100

958  47
 n 6
100  75

21. To an evacuated vessel with movable piston under external pressure of 1 atm, 0.1 mol of He and 1.0 mol.
of an unknown compound (vapour pressure 0.68 atm. at 00C) are introduced. Considering the ideal gas
behaviour, the total volume (in litre) of the gases at 00C is close to
Ans. (7)

Sol. Let unknown is X.

b g
p He  p total  p x  1  0.68 atm
 0.32 atm
RT
Now p He  n He
V
RT 010 .  0.082  273
 v 
p He 0.32
7
Triumph Academy [9] IIT–JEE-11 / Paper I

CHEMISTRY

22. The total number of alkenes possible by dehydromination of 3-bromo-3-cyclopentylhexane using alcoholic
KOH is
Ans. (5)

Sol.

(Cis + trans) (Cis + trans)

23. bg
The work function  of some metals is listed below. The number of metals which will show photoelectric
effec when light of 300 nm wavelength falls on the metal is

Metal Li Na K Mg Cu Ag Fe Pt W

b g
 eV 2.4 2.3 22 3.7 4.8 4.3 4.7 6.3 4.75

Ans. (4)

Sol. For photoelectric effect to lapper.

E      4.14 eV

 Li, Na, Ka, Mg will show photoelectronic effect when light g 300 nm wavelength falls on the metal is (4).
 [10] IIT 2011 / Paper I

PHYSICS
Part II
Section – I (Total Marks : 21)
Single Correct Answer Type
This section contains 7 multiple choice questions numbered 24 to 30. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.

24. A ball of mass (m) 0.5 kg is attached to the end of a string having length (L) 0.5 m. The ball is rotated on
a horizontal circular path about vertical axis. The maximum tension that the string can bear is 324 N. The
maximum possible vlaue of angular velocity of ball (in radian/s) is

(A) 9 (B) 18 (C) 27 (D) 36

Sol.: (D) m max 2 r  Tmax

Tmax 324
  max    1296  36 rad / s
mr 0.5  0.5

25. A meter bridge is set-up as shown, to determine an unknown resistance 'X' using a standard 10 ohm
resistor. The galvanometer shows null point when tapping-key is at 52 cm mark. The end-corrections are
1 cm and 2 cm respectively for the ends A and B. The determined value of 'X' is

(A) 10.2 ohm (B) 10.6 ohm (C) 10.8 ohm (D) 11.1 ohm
 [11] IIT 2011 / Paper I

PHYSICS

X 53 53
Sol.: (B)  X  10  10.6  (include the end corrections as well in the calculated length)
10 50 50

26. A 2 F capacitor is charged as shown in figure. The percentage of its stored energy dissipated after the
switch S is turned to position 2 is

(A) 0% (B) 20% (C) 75% (D) 80%

1
Sol.: (D) U i   2 V 2
2
bg
U loss  
bg bg
1 2  8
V 2
2 10
U loss 4
 lost    80%
Ui 5

27. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km / hr towards a tall
building which reflects the sound waves. The speed of sound in air is 320 m / s. The frequency of the siren
heard by the car driver is
(A) 8.50 kHz (B) 8.25 kHz (C) 7.75 kHz (D) 7.50 kHz

Sol.: (A) f final  8 

LM 320  10 OP  8  33  8.5 kHz
N 320  10 Q 31
28. 5.6 liter of helium gas at STP is adiabatically compressed to 0.7 liter. Taking the intial temperature to be
T1 , the work done in the prcess is

9 3 15 9
(A) R T1 (B) R T1 (C) R T1 (D) R T1
8 2 8 2

Sol.: (A) TV  1  constant

b g
T1 5.6
2/3
 T2 0.7
2/3
 T2  T1 8
2/3
 4T1

1
Wad   U  nCv T   
3R
3T1  
 RT1FG IJ
 4 2 8 H K
 [12] IIT 2011 / Paper I

PHYSICS

29. Consider an electric field E  E0 x , where E0 is a constant. The flux through the shaded area (as shown
in the figure) due to this field is

E 0a 2
(A) 2 E0a 2 (B) 2 E0a 2
(C) E0a 2 (D)
2

Sol.: (C) e j d i
A  ai  ak  aj  a 2 k  a 2i
 
  E  A  E 0i  a 2 k  a 2i  E0 a 2

30. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 Å. The wavelength
of the second spectral line in the Balmer series of singly-ionized helum atom is
(A) 1215 Å (B) 1640 Å (C) 2430 Å (D) 4687 Å

1 1 1
R  
LM5
R
OP
Sol.: (A) 1 4 9 N
36 Q
1 1 1
 4R 
3
 R
LM OP
2 4 9 4 N Q
2 5 4 5 5
    2   6561  1215 Å
 1 36  3 27 27
 [13] IIT 2011 / Paper I

PHYSICS
Section–II (Total Marks : 16)
Multiple Correct Answer Type
This section contains 4 multiple choice questions numbered 31 to 34. Each question has 4 choices (A), (B),
(C) and (D), out of which ONE OR MORE THAN ONE is / are correct.

31. b g
A spherical metal shell A of radius R A and a solid metal sphere B of radius R B  R A are kept far apart
and each is given charge '+Q'. Now they are connected by a thin metal wire. Then
 A RB
(A) E Ainside  0 (B) QA  QB (C)   R (D) E Aon surface  E Bon surface
B A

Sol.: (A, B, C, D) On connecting V A  VB

kQ A kQB
 
RA RB .
also R  constant
 A RB
 
 B RA

32. An electron and a proton are moving on straight parallel paths with same velocity. They enter a semi-
infinite region of uniform magnetic field perpendicular to the velocity. Which of the following statement(s0
is/are true?
(A) They will never come out of the magnetic field region.
(B) They will come out travelling along parallel paths.
(C) They will come out at the same time.
(D) They will come out at different times.
Sol.: (B, D) As shown in the figure they will come out after describing a semicircle along parallel paths.

m
Also time taken t  which will be different for both.
qB
 [14] IIT 2011 / Paper I

PHYSICS

33. A metal rod of length 'L'and mass 'm' is pivoted at one end. A thin disk of mass 'M'and radius 'R'(< L) is
attached at its center to the free end of the rod. Consider two ways the disck is attached: (case A). The
disc is not free to rotate about its center and (case B) the disck is free to rotate about its center. The rod-
disc system performs SHM in vertical plane after being released from the same displaced position. Which
of the following statement(s) is/are true?

(A) Restoring torque in case A = Restoring torque in case B

(B) Restoring torque in case A < Restoring torque in case B
(C) Angular frequency for case A > Angular frequency for case B
(D) Angular frequency for case A < Angular frequency for case B
Sol.: (A, D) In both the situations, net restoring torque is same. In first case when the disk is not free to rotate about its
mR 2
centre its moment of inertia is  mL2 about the axis where as in second case its moment of inertia is mL2 .
2
So from   I 2 , the angular frequency in case A is lesser than that in B.

34. A composite block is made of slabs A, B, C, D and E of different thermal conductivities (givenin terms of
a constant K) and sizes (given in terms of length, L) as shown in the figure. All slabs are of same width.
HJeat 'Q'flows only from left to right through the blocks. Then in steady state

(A) heat flow through A and E slabs are same.

(B) heat flow through slab E is maximum.
(C) temperature difference across slab E is smallest.
(D) heat flow through C = heat flow through B + heat flow through D.
Sol.: (A, B, C, D) Slabs A and E are in series and thus heat flow through them is same and maximum. Treating slabs B, C,
D as a joint block and since it is in series with A and E temperature difference across slab E is smallest as it has the least
kA
resistance. Also for slabs B, C, D heat current H  and thus H C  H B  H D .
L
 [15] IIT 2011 / Paper I

PHYSICS
Section–III (Total Marks : 15)
Paragraph Type
This section contains 2 paragraphs. Based upon the first paragraph, 3 multiple choice questions and based
upon the second paragraph 2 multiple choice questions have to be answered. Each of these question has four
choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Question Nos. 35 to 37

Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. They are especially useful in
studying the changes in motion as intial position and momentum are changed. Here we consider some simple
dynamical systems in one-dimension. For such systems, phase space is a planein which positionis plotted along
bg bg
horizontal axis and momentumis plotted along vertical axis. The phase space diagram is x t vs. p t curve in
this plane. The arrow on the curve indicates the time flow. For example, the phase space diagram for a particle
moving with constant velocity is a straight line as shown in the figure. We use the sign conventionin which position
or momentum upwards (or to right) is positive and downwards (or to left) is negative.

35. The sphase space diagram for a ball thrown vertically up from ground is

(A) (B)
 [16] IIT 2011 / Paper I

PHYSICS

(C) (D)

36. The phase space diagram for simple harmonic motion is a circle centered atthe origin. In the figure, the two
circles represent the same oscillator but for different initial conditions, E1 and E2 are the total mechanical
energies respectively. Then

(A) E1  2 E 2 (B) E1  2 E 2 (C) E1  4 E 2 (D) E1  16 E 2

 [17] IIT 2011 / Paper I

PHYSICS
37. Consider the spring-mass system, with the mass submerged in water, as showin in the figure. The phase
space diagram for one cycle of this system is

(A) (B)

(C) (D)

Sol.: (D, C, B) For a ball thrown upward, the magnitude of position first increases and then decreases. The magnitude of
momentum for upward flight decreases and then for downward flight increases so correct option is B.
The amplitude of SHM for second case is double that of first and other factors (mass frequency) are same so from
1
E m 2 a 2 , E 2  4 E1
2
During the downward motion (from upper extreme to lower extreme) of block, the momentum is negative and its
magnitude first increases then decreases. For upward motion (from lower extreme to upper extreme), the magni-
tude of momentum first increases and then decreases, the sign is +ve here.
Further due to the damping the upper extreme for the upward phase is lower from previous one.
So correct option is B.
 [18] IIT 2011 / Paper I

PHYSICS
Paragraph for Question Nos. 38 to 39

A dense collection of equal number of electrons and positive ions is called neutral plasma. Certain solids contain-
ing fixed positive ions surrounded by free electrons can be treated as neutral plasma. Let 'N'be the number
density of free electrons, each of mass 'm'. When the electrons are subjected to an electric field, they are
displaced relatively away from the heavy positive ions. If the electric field becomes zero, the electrons being to
oscillate about the positive ions with a natural angular frequency '  p ', which is called the plasma frequency. To
sustain the oscillations, a time varying electric field needs to be applied that has an angular frequency  , ap-
proaches  p , all the free electrons are set to resonance together and all the energy is reflected. This is the
explanation of high reflectivity of metals.

38. Taking the electronic charge as é'and the permittivity as '  0 ' , use dimensional analysis to determine the
correct expression for  p .

Ne m 0 Ne 2 m 0
(A) m 0 (B) (C) (D)
Ne m 0 Ne2

39. Estimate the wavelength atwhich plasma reflection will occur for a metal having the density of electrons
N  4  1027 m 3 . Take  0  1011 and m  10 30 , where these quantities are in proper SI units.
(A) 800 nm (B) 600 nm (C) 300 nm (D) 200 nm

Sol.: (C, B) By checking dimension of each option, the correct option is

LM Ne 2 OP
p 
MN m 0 PQ
P
The frequency of light reflected is so wavelength is
2

c 10 30  10 11
  2  3  108   600 nm
 P/ 2 .  10 38
4  10 27  1.6  16
 [19] IIT 2011 / Paper I

PHYSICS

Section – IV
Integer Answer Type
This section contains 7 questions. The answer to each of the questions is a single-digit integer, ranging from
0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be darkened.

40. The activity of a freshly prepared radioacitve sample is 1010 disintegrations per second, whosemean life is
109 s. The mass of an atom of this radioisotope is 10–25 kg. The mass (in mg) of the radioactive sample is
Sol.: (1) A  N
A
N  A

so M  mN  mA  1025  1010  109  106 kg  1 mg

41. Four point charges, each of +q, are rigidly fixed atthe four corners of a square planar soap film of side 'a'.
The surface tension of the soap film is . The systemof charges and planar film are in equilibrium, and

Lq O
a  kM P
2 1/ N

N Q , where 'k' is a constant. Then N is

Sol.: (3) b g
The force due to surface tension on any side is  2 and the force electrostatic force on any side is
2 kq 2
a2
. For

equlibrium,

q q

q q

F kq I  2b ga
2
2GH a JK2

LF q I O
a  k MG J P
2
1/ 3

MNH  K PQ
42. Steel wire of length 'L' at 40 oC is suspended from the ceiling and then a mass 'm' is hung from its free end.
The wire is colled down from 40 oC to 30 oC to regain its original length 'L'. The coefficient of linear
thermal expansion of the steel is 10–5 / oC, Young's modulus of steel is 1011 N / m2 and radius of the wire
is 1 mm. Assume that L >> diameter of the wire. Then the value of 'm' in kg is nearly

mgL
Sol.: (3)  L T
AY
AY T   10 6  1011  10 5  10
m  
g 10
 [20] IIT 2011 / Paper I

PHYSICS

43. Four solid spheres each of diameter 5 cm and mass 0.5 kg are placed with their centers atthe corners
of a square of side 4 cm. The moment of inertia of the system about the diagonal of the square is
N  10 4 kg m2 , then N is

2 2 LM
T  2  mr 2  2 mr 2 
mR 2 OP
Sol.: (9) 5 5 MN 2 PQ

8 2 1 8 5 LM OP
mr  mR 2     16  10 4  9  10 4
5 2 5 4 N Q
44. A long circular tube of length 10 m radius 0.3 m carries a current I along its curved surface as shown. A
wrie-loop of resistance 0.005 ohm and of radius 0.1 m is placed inside the tube with its axis coinciding with
b g
the axis of the tube. The current varies as I  I 0 cos 300t where I 0 is constant. If the magnetic moment
b g
of the loop is N 0 I 0 sin 300t , then 'N' is

I
Sol.: (6) The given tube is equivalent to a solenoid. The current per unit length of the solenoid is . So field produced
L
I
is B   0 . The flux through the coil is   Br 2 so current induced is
L

i
 1 d
  Br 2 
1 d 0I FG IJ
  r 2 dI
r 2  0
R R dt R dt L H KRL dt
So magnetic moment of coil is
 0 2 r 4 dI  0  10  10 4
M  r 2i 
RL dt

5  10 3  10
b g
 300 I 0 sin 300t  6 0 I 0 sin 300t
 [21] IIT 2011 / Paper I

PHYSICS

45. A boy is pushing a ring of mass 2 kg and radius 0.5 m with a stick as shown in the figure. The stick applies
a force of 2 N on the ring and rolls it without slipping with an acceleration of 0.3 m / s2. The coefficient of
friction between the ground and the ring is large enough that rolling always occurs and the coefficient of
coefficient of friction between the stick and the ring is (P / 10). The value of P is

Sol.: (4) Writing torque about instantaneous axis of rotation

a = 0.3 m / s2

2N

f
(2)P/10

2R  2
FG P IJ R  I 
H 10 K IAOR

or
P
2 R  R  e2mR j
5
a
2
R
b g
or 2  2  2  0.3 
P
5
or P  4

46. A block is moving on an inclined plane making and angle 45o with the horizontal and the coefficient of
friction is . The force required to just push it up the inclined plane is 3 times the force required to just
prevent it from slding down. If we defined N = 10 , then N is

Sol.: (5) bmg sin  mg cos g  3 mg sin  mg cos

2mg sin   4 mg cos
1 1
 tan  
2 2
1
N  10  10  5
2
Triumph Academy [22] IIT–JEE-11 / Paper I

MATHEMATICS
PART III
Section–I
Straight Objective Type
This section contains 7 multiple choice questions numbered 47 to 53. Each question has 4 choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.

47. Let  and  be the roots of 6x 2  6x  2  0 , with    . If a n   n   n for n  1 , then the value of
a 10  2a 8
is
2a 9
(A) 1 (B) 2 (C) 3 (D) 4

Sol: (C)  is a roots of of equation  2  6  2  0 ;  2  6B  2  0

 2  6  2  0   2  2  6

a 10  2a 8

e
 10  10  2  8  8j e j
2a 9 2  9  9 e j

e j e
 8  2  2  8  2  2 j 
b g b g
 8  6  8 6
2 e   j 9 9 2 e   j
9 9

6 e   j
9 9

 3
2(  9   9 )

48. A Straight line L through the point (3,  2) is inclined at an angle 60o to the line 3x  y  1 . If L also
intersects the x  axis , then the equation of L is

(A) y  3x  2  3 3  0 (B) y  3x  2  3 3  0

(C) 3y  x  3  2 3  0 (D) 3y  x  3  2 3  0
Sol: (C) Inclination of line 3x  y  1 is 150o
Inclination of line L = 150o  60o
 210o , 90o
1
Slope of line L = tan 210 o  tan 30 o 
3
Equation of = Line L

y2 
1
3
bx  3g
 3y  x  3  2 3  0
Triumph Academy [23] IIT–JEE-11 / Paper I

MATHEMATICS

49. Let ( x 0 , y 0 ) be the solution of the following equations

b g
(2 x) ln 2  3y
ln 3

3ln x  2 ln y
Then x 0 is

1 1 1
(A) (B) (C) (D) 6
6 3 2

Sol: (C) Let ln x  p, ln y  q

ln 2  a, ln 3  b
Now, (2 x) ln 2  (3y) ln 3
 a (a  p)  b( b  q ) . . . (1)

3ln x  2 ln y  (ln x) (ln 3)  (ln y) (ln 2)

 pb  qa . . . (2)
From (1) a 2  b 2  bq  pa
pb
 b.  pa
a
p 2

a
e
b  a2 j
 p  a
1
 ln x   ln 2  x 
2

z
ln 3
x sin x 2
50. The value of dx is
ln 2
sin x 2
 sin(ln 6  x 2
)

1 3 1 3 3 1 3
(A) ln (B) ln (C) ln (D) ln
4 2 2 2 2 6 2

z
ln 3
x sin x 2
Ans: (A) I dx
sin x 2  sin(ln 6  x 2 )
ln 2

z
ln 3
sin t dt
 I Put x 2  t
sin t  sin(ln 6  t ) 2
ln 2

z
ln 3
 1 sin(ln 6  t )
I dt
2 sin(ln 6  t )  sin t
ln 2
Triumph Academy [24] IIT–JEE-11 / Paper I

MATHEMATICS

z
ln 3
1 1 3
Adding 2I  dt  ln
2 2 2
ln 2

1 3
  I ln
4 2

r r r r r r
51. Let a  $
i  $j  k$ , b  $
i  $j  k$ and c  $
i  $j  k$ be three vectors. A vector v in the plane of a and b ,
1
whose projection on cr is , is given by
3

(A) $
i  3$j  3k$ (B) 3$
i  3$j  k$ (C) 3$
i  $j  3k$ (D) $
i  $j  3k$

r r r
Sol: (C) v  a  b
r r
vc 1 r r r 1 r
r   ( a  b ) . c  c
c 3 3
r r r
r r c
 a . c   ( b . c) 
3

1 r r r
c  a. c
3 r 1  ( 1)
  r  2
b.c 1
r r r
 v  a  2b  2$
i  $j  3$
i

52. o t o t
Let P   : sin   cos   2 cos  and Q   : sin   cos   2 sin  be two sets. Then

(A) P  Q and Q  P   (B) Q  P

(C) P  Q (D) P  Q

Ans: (D) sin   cos   2 cos 

 sin   ( 2  1) cos 
1
 tan    2 1
2 1

 sin   cos   2 sin 

 ( 2  1) sin   cos 
 tan   2  1
Triumph Academy [25] IIT–JEE-11 / Paper I

MATHEMATICS
53. Let the straight line x  b divide the area enclosed by y  (1  x) , y  0 and x  0 into two parts
2

1
R1 (0  x  b) and R 2 ( b  x  1) such that R 1  R 2  . Then b equals
4
3 1 1 1
(A) (B) (C) (D)
4 2 3 4

1
Ans: (B) R1  R 2 
4

z z
b 1
1
 (1  x) 2 dx  (1  x) 2 dx 
4
0 b

z z
b 1
1
 2 (1  x) 2 dx  (1  x) 2 dx 
4
0 0

b 1
(1  x ) 3 (1  x) 3 1
 2  
3 3 4
0 0

 
2
3
e
(1  b) 3  1  0 
1
3
j FGH

1
4
IJ
K
2 2 1 1 1 1 1
 (1  b) 3      
3 3 3 4 3 4 12

1 1 1
 (1  b) 3   1 b   b 
8 2 2
Triumph Academy [26] IIT–JEE-11 / Paper I

MATHEMATICS

Section–II
Straight Objective Type
This section contains 4 multiple choice questions numbered 54 to 57. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE THAN ONE is / are correct.

54. Let M and N be two 3  3 non-singular skew-symmetric matrices such that MN  NM . If p T denotes
the transpose of P, then M 2 N 2 ( M T N ) 1 ( MN 1 ) T is equal to
(A) M 2 (B) N 2 (C) M 2 (D) MN

Ans: (C) M 2 N 2 ( M T N ) 1 ( MN 1 ) T

 e
M 2 N 2 ( N 1 ( M T ) 1 ) ( N 1 ) T M T j
2 2 1 T T 1
 M N N (  M ) ( N ) (  M)

 M 2 N ( N N 1 ) (  M) 1 (  N ) 1 (  M)

 b
M 2 N ( I) (  N ) (  M ) g 1
(  M)

 M 2 N ( NM) 1 (  M)

 M ( MN) ( MN) 1 (  M)
 M (I) (  M)

  M2

55. The vectors(s) which is/are coplanar with vectors $

i  $j  2 k$ and $
i  2 $j  k$ , and perpendicular to the
vecotrs $
i  $j  k$ is/are
(A) $j  k$ (B)  $
i  $j (C) $
i  $j (D)  $j  k$
r
SOL: ( ) a$
i  $j  2 k$
r
b$
i  2 $j  k$
r
c$
i  $j  k$
r r r
vector coplanar with a and b and perpendicular to c is given by
r r r
c  ( a  b)
r r r r r r
 ( c . b) a  ( c . a ) b
r r
 4 a  4b
r r r r
 4( a  b)  4(  j  k )
Triumph Academy [27] IIT–JEE-11 / Paper I

MATHEMATICS
x2 y2
56. Let the eccentricity of the hyperbola 2  2  1 be reciprocal to that of the ellipse x 2  4 y 2  4 . If the
a b
hyperbola passes through a focus to the ellipse, then
x2 y2
(A) the equation of the hyperbola  1 (B) a focus of the hyperbola is (2, 0)
3 2

5
(C) the eccentricity of the hyperbola is (D) the equation of the hyperbola is x 2  3y 2  3
3
SOL: ( B, D) Equation of ellipse
x2 y2
 1
4 1

1 3
eccentricity of ellipse  1  
4 2
2
eccentricity of hyperbola 
3
Foci of ellipse (  3 , 0) .
3 0
 2
 1
a b2
3
  1  a2  3
a2

a2
 b2  1
3

x2 y2
Equation of Hyperbola :  1
3 1
 x 2  3y 2  3
Foci of hyperbola : (  2, 0)
Triumph Academy [28] IIT–JEE-11 / Paper I

MATHEMATICS
57. Let f : R  R be a function such that
f ( x  y)  f ( x)  f ( y), x, y  R
If f ( x) is differentiable at x  0 , then
(A) f ( x) is differentiable only in a finite interval containing zero
(B) f ( x) is continuous x  R
(C) f ( x) is constant x  R
(D) f ( x) is differentiable except at finitely many points
f ( x  h)  f ( x) f ( x)  f ( h)  f ( x)
Ans: (B, C ) f ( x)  lim  lim
h0 h h0 h

f ( x  0)
f ( h) f ( h)  f (0)
 lim  lim  f ( x)  f (0)
h 0 h h0 h
 f (0)  0

 f  (0) = A const = k (say)

 f ( 0)  kx  c but f (0)  0  k  0  f ( x)  kx
Triumph Academy [29] IIT–JEE-11 / Paper I

MATHEMATICS

Section–III
Linked Comprehension Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Question Nos. 58 to 59

Let U1 and U 2 be two urns such that U1 contains 3 white and 2 red balls, and U 2 contains only 1 white ball.
A fair coin is tossed. If head appears then 1 ball is dawn at random from U1 and put into U 2 . However , if tail
appears then 2 balls are drawn at random from U1 and put into U 2 . Now 1 ball is drawn at random from U 2 .

58. The probability of the drawn ball from U 2 being white is

13 23 19 11
(A) (B) (C) (D)
30 30 30 30

W (2 W) W
1
3/ 5

H
2/5
1/ 2 1/ 2
R (1W 1R) W
2W (3W) 1
3/10 W
SOL: ( B) Coin
1/ 2 6 /10 2/ 3
T 2(1W 1R) (2W, 1R)
W,1R W
1/10 1/ 3
2R (1W, 2R) W

1 3 1 2 1 1 3 1 6 2 1 1 1
P(W)             
2 5 2 5 2 2 10 2 10 3 2 10 3


1LM 9
9  3   6
1 OP  23
30 N 2 2 Q 30
Triumph Academy [30] IIT–JEE-11 / Paper I

MATHEMATICS

59. Given that the drawn ball from U 2 is white, the probability that head appeared on the coin is
17 11 15 12
(A) (B) (C) (D)
23 23 23 23

SOL: ( D)

1 3 1 2 1
F Head appear on coin I
PG
    12 FG IJ
H ball drawn from U is white JK
2 5 2 5 2 
2
= 1 3 1 6 2 1 1 1
      
23 H K
2 10 2 10 3 2 10 3

Paragraph for Question Nos. 60 to 62

Let a, b and c be three numbers satisfying

LM1 9 OP
7
7  0
a b c 8
MN7 2
3 7
PQ 0 0 . . . (E)

60. If the point P (a , b, c) , with reference to (E), lies on the plane 2 x  y  z  1 , then the value of 7a  b  c
is
(A) 0 (B) 12 (C) 7 (D) 6

a  8b  7c  0
SOL: ( D) 9a  2 b  3c  0 . . . (E)
UV
W
7a  7 b  7c  0

1 8 7
Now, D  9 2 3 0
7 7 7

 system (E) has infinite solutions

a b c
   k (say)
1 6 7
 2a  b  c  1
 2 k  6k  7 k  1
 k 1
 7a  b  c  7 k  6k  7 k  6k  6
Triumph Academy [31] IIT–JEE-11 / Paper I

MATHEMATICS

61. Let  be a solution of x 3  1  0 with Im( )  0 . If a  2 with b and c satisfying (E), then the value of
3 1 3
 b c
 a
 
is equal to
(A) 2 (B) 2 (C) 3 (D) 3

Sol: (A) a  2, k  2 , b  12, c  14

3 1 3
    3  1  3 2
2  12  4
 3 (   2 )  1
 3( 1)  1  2

62. Let b  6 , with a and c satisfying (E). If  and  are the roots of the quadratic equaiton ax 2  bx  c  0 ,
then
6
(A) 6 (B) 7 (C) (D) 
7
Sol: (B) b  6  k  1  a  1, c  7
quadratic Equation is x 2  6x  7  0  ( x  7) ( x  1)  0  x  7, 1
F 1 1I F 1 1 I
 n  n

 GH    JK  GH 1  (7) JK
n0 n0

F 6I 1  7

 G J 
n

H 7K 1 6
n0
7
Triumph Academy [32] IIT–JEE-11 / Paper I

MATHEMATICS
Section – IV
Integer Answer Type
This section contains 10 questions. The answer to each of the questions is a single-digit integer, ranging from
0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be darkened.

63. The minimum value of the sum of real numbers a 5 , a 4 , 3a 3 , 1, a 8 and a10 with a  0 is

Sol : [8]
e j
a 5  a 4  3 a 3  1  a 8  a 10 F e j b1gea jea jIK
 a 5 a 4 a 3
3 1/ 8

H
8 10
1 (using AM  GM )
1 1 3  1 1 1

 a 5  a 4  3a 3  1  a 8  a 10  8

bg
Let f   sin tan
1 FG FG sin  IJ IJ ,where       . Then the value of
64.
H H cos 2 KK 4 4

d
db tan g
b f ( ) g
is

bg 1 FG sin  IJ  sinFG sin 1 sin  I

J
Sol: [1] f   sin tan H cos 2 K H sin 2   cos 2 K

sin  sin  sin 

    tan 
e
sin 2   cos2   sin 2  j cos  cos 

d
b g
f  
b g
d tan 
1
b g
d tan  b g
d tan 

65. If z is any complex number satisfying z  3  2i  2 , then the minimum value of 2 z  6  5i is

FG 5 IJ
Sol: [5] 2 z  6  5i  2 z  3  H 2 K
 2 3 3
FG 5 IJ
H 2
i
K (corresponding Pt A)

FG 5 IJ  5
=2
H 2K
Triumph Academy [33] IIT–JEE-11 / Paper I

MATHEMATICS
66. g g
Let f : 1,   2,  be a differentiable function such that f (1)  2 . If

z
x
6 f ( t )dt  3x f ( x)  x 2
1

for all x  1 , then the value of f (2) is

z bg
x

SOL [6] 6 f t dt  3  f x  x bg
3

1
differenciating both sides

bg bg bg
6f x  3f x  3xf ' x  3x 2

 xf ' b xg  f b xg  x
2

F 1I
f ' b xg  f b xgG  J  x
 H xK
integration factor
1
bg
f x e
 dx
x 
1
x
solution is given by
1
x
f x  x z
b g FGH IJK
1
x
dx  c  x  c

 f b xg  x  cx
2

Now f b1g  2  c  1

 f b xg  x  x
2

f b2g  6

67. The positive integer value of n  3 satisfying the equation

1 1 1
 
FG  IJ FG IJ
2 3FG IJ
sin
H nK sin
H Kn
sin
n H K
is
Triumph Academy [34] IIT–JEE-11 / Paper I

MATHEMATICS

1 1 1 
SoL [7]   (Let  )
 2 3 n
sin sin sin
n n n
1 1 1 1 1 1 sin 3  sin 
      
sin  sin 2 sin 3 sin 2 sin  sin 3 sin .sin 3
sin   sin 3 sin   sin 3
 sin 3  sin    2 cos 2  sin   sin   0
sin 2 sin 2
 7 7
 sin 4  sin 3  2 sin cos 0  cos 0
2 2 2
7  
  
2 2 7

68. Let a1 , a 2 , a 3 , ..., a100 be an arithmetic progression with a1  3 and sp   a i , 1  p  100 . For any
i 1

Sm
integer n with 1  n  20 , let m  5n . If S does not depend on n, then a 2 is
n

Sm
m
2a 1  m  1 d b g
m 6  md  d b g
5n 6  5nd  d b
5 6  d  5nd g b g
 2   
SoL [9] S n n
2a 1  n  1 d b g
n 6  nd  d b n 6  ndg d b g b
6  d  nd is free from n g
2
 6d  0 d6
 a 2  a1  d  3  6  9

69. Consider the parabola y 2  8x . Let 1 be the area of the triangle formed by the end points of its latus

FG 1 , 2IJ on the parabola, and 

rectum and the point P
H2 K 2 be the area of the triangle formed by drawning

1
tangents at P and at the end points of the latus rectum. Then is
2
SoL [2] Area of  formed by three pts to to parabola is twice the area of  formed by tangents at these pts.