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IIT-JEE-2011-PAPER1-SOLUTIONS -ENGLISH(1.1)

IIT-JEE-2011-PAPER1-SOLUTIONS -ENGLISH(1.1)

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Published by: Resonance Kota on Apr 10, 2011
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09/28/2012

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Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
Date : 11-04-2011 Duration : 3 HoursMax. Marks : 240
PAPER - 1
QUESTIONS AND SOLUTIONS OF IIT-JEE 2011
INSTRUCTIONS
A. General :1.
The
question paper CODE
is printed on the right hand top corner of this sheet and on the backpage of this booklet.
2.
No additional sheets will be provided for rough work.
3.
Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers andelectronic gadgets are NOT allowed.
4.
Write your name and registration number in the space provided on the back page of this booklet.
5.
The answer sheet, a machine-gradable Optical Response Sheet (ORS), is provided separately.
6.
DO NOT TAMPER WITH/MUTILATE THE ORS OR THE BOOKLET.
7.
Do not break the seals of the question-paper booklet before being instructed to do so by theinvigilators.
8.
This Question Paper contains having 69 questions.
9.
On breaking the seals, please check that all the questions are legible.
B. Filling the Right Part of the ORS:10.
The ORS also has a CODE printed on its Left and Right parts.
11.
Make sure the CODE on the ORS is the same as that on this booklet.
If the codes do notmatch, ask for a change of the booklet.12.
Write your Name, Registration No. and the name of centre and sign
with pen
in the boxesprovided.
Do not write them anywhere else
. Darken the appropriate bubble UNDER each digitof your Registration No. with a
good quality HB pencil.C. Question paper format and Marking Scheme:13.
The question paper consists of
3 parts
(Chemistry, Physics and Mathematics). Each partconsists of
four sections
.
14.
In
Section I
(Total Marks: 21), for each question you will be awarded 3 marks if you darken
ONLY
the bubble corresponding to the correct answer and
zero marks
if no bubble is darkened.In all other cases,
minus one (-1) mark
will be awarded.
15.
In
Section Il
(Total Marks: 16), for each question you will be awarded
4 marks
if you darken
ALL
the bubble(s) corresponding to the correct answer(s)
ONLY
and
zero marks
otherwise. Thereare no negative marks in this section.
16.
In
Section III
(Total Marks: 15), for each question you will be awarded
3 marks
if you darken
ONLY
the bubble corresponding to the correct answer and
zero marks
if nobubble is darkened. In all other cases,
minus one (-1) mark
will be awarded.
17.
In
Section IV
(Total Marks: 28), for each question you will be awarded
4 marks
if you darken
ONLY
the bubble corresponding to the correct answer and
zero marks
otherwise. There are
nonegative marks
in this section.
Write your Name registration number and sign in the space provided on the backpage of this booklet.
   D   O   N   O   T   B   R   E   A   K   T   H   E   S   E   A   L   S   W   I   T   H   O   U   T   B   E   I   N   G   I   N   S   T   R   U   C   T   E   D   T   O   D   O   S   O   B   Y   T   H   E   I   N   V   I   G   I   L   A   T   O   R
 
J10411Page # 2Useful Data :
R = 8.314 JK
 –
1
mol
 –
1
or 8.206
× 10
 –
2
L atm K
 –
1
mol
 –
1
1 F = 96500 C mol
 –
1
h = 6.626
× 10
 –
34
Js1 eV = 1.602
× 10
 –
19
Jc = 3.0
× 10
8
m s
 –
1
N
A
= 6.022
× 10
23
 
J10411Page # 3
SECTION - I (Total Marks : 21)
(Single Correct Answer Type)
This section
contains 7 multiple choice questions
, Each question has four choices, (A), (B), (C) and (D)out of which
ONLY ONE
is correct.
1.
Extra pure N
2
can be obtained by heating(A) NH
3
with CuO(B) NH
4
NO
3
(C) (NH
4
)
2
Cr
2
O
7
(D) Ba(N
3
)
2
Ans.
(D)
Sol.
Ba (N
3
)
2
   
Ba + 3N
2
2.
Geometrical shapes of the complexes formed by the reaction of Ni
2+
with Cl
 –
, CN
 –
and H
2
O, respectively, are(A) octahedral, tetrahedral and square planar(B) tetrahedral, square planar and octahedral(C) square planar, tetrahedral and octahedral(D) octahedral, square planar and octahedral
Ans.
(B)
Sol.
Ni
+2
+ 4Cl
 –
 
   
[NiCl
4
]
2
 –
SP
3
[NiCl
4
]
2
 –
= 3d
8
confiuration with Nickel in + 2 Oxidation state. Cl
 –
 
being weak field ligand does not compelfor pairing of electrons.So,Hence, complex has tetrahedral geometryNi
+2
+ 4CN
 –
 
 
[Ni(CN)
4
]
2
 –
[Ni(CN)
4
]
2
 –
= 3d
8
configuration with nickel in + 2 oxidation state. CN
 –
being strong field ligand which compelsfor pairing of electrons.So,Hence, complex has square planar gemetry.
CHEMISTRY

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